Chapter 4: Problem 49
IUPAC name of allyl chloride is (a) 2 -chloropropene (b) 3 -chloropropene (c) 1 -chloropropene (d) 1 -(chloromethyl)ethane
Chapter 4: Problem 49
IUPAC name of allyl chloride is (a) 2 -chloropropene (b) 3 -chloropropene (c) 1 -chloropropene (d) 1 -(chloromethyl)ethane
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Get started for freeWhich of the following reactions will give benzyl chloride? (a) \(\mathrm{C}_{6} \mathrm{H}_{6}+\mathrm{HCHO}+\mathrm{HCl} \stackrel{\mathrm{ZnCl}_{3}}{\longrightarrow}\) (b) \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{3}+\mathrm{Cl}_{2} \stackrel{\mathrm{hv}}{\Delta}\) (c) \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{3}+\mathrm{SO}_{2} \mathrm{Cl}_{2} \stackrel{\text { peroxide }}{\longrightarrow}\) (d) \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{3}+\mathrm{SOCl}_{2} \rightarrow\)
Vapours of isomeric butyl alcohols are passed over copper at \(573 \mathrm{~K}\). The products obtained from normal, sec, iso and tertiary butyl alcohols respectively are (a) aldehyde, ketone, aldehyde and ketone, (b) aldehyde, ketone, ketone and aldehyde (c) aldehyde, ketone, aldehyde and alkene (d) ketone, aldehyde, aldehyde and alkene
Preparation and reactions of alcohols Alcohols can by prepared from alkyl halides, epoxides, alkenes, etc. When treated with acid, \(\mathrm{C}-\mathrm{OH}\) bond is cleaved heterolytically to form a carbocation which could then undergo substitution, elimination or rearrangement depending on the conditions and stability of the carbocation. When 1,2 -dimethyl cyclohexene is treated with cold dilute alkaline \(\mathrm{KMnO}_{4}\), the product obtained is
Which of the following reactions can be used to distinguish between chlorobenzene and benzyl chloride? (a) Heating with an alcoholic solution of silver nitrate. (b) Boiling with aqueous KOH solution followed by acidification with dilute \(\mathrm{HNO}_{3}\) and addition of \(\mathrm{AgNO}_{3}\) solution. (c) Fusion with sodium metal followed by acidification with dilute \(\mathrm{HNO}_{3}\) and addition of \(\mathrm{AgNO}_{2}\) solution. (d) Refluxing with alkaline \(\mathrm{KMnO}_{4}\) followed by acidification with \(\mathrm{HCl}\).
When 3,3-dimethyl-2-butanol is treated with dilute acid, the most stable carbocation formed is (a) 3,3-dimethyl-2-butyl cation (b) 3,3 -dimethyl-1-butyl cation (c) 2,3-dimethyl-2-butyl cation (d) 2-methyl-2-pentyl cation
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