Match the elements of Column I to elements of Column II. There can be single or multiple matches. Column I (Test) (a) Hinsberg's test (b) Carbylamine test (c) Azo dye test (d) Liebermann nitroso reaction Column II (Distinguish between) (p) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}\) and \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH} \mathrm{CH}_{3}\) (q) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{2}\) and \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{NH}_{2}\) (r) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\) and \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{NH}_{2}\) (s) \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \mathrm{NH}_{2}\) and \(\mathrm{p}-\mathrm{CH}_{3}-\mathrm{C}_{6} \mathrm{H}_{4}-\mathrm{NH}_{2}\) (t) \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2}\right)_{2} \mathrm{NH}\) and \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2}\right)_{3} \mathrm{~N}\)

Step by step solution

01

Understand the tests

Let's first briefly understand each test mentioned in Column I: (a) Hinsberg's test: Used to distinguish between primary, secondary, and tertiary amines. (b) Carbylamine test: Used to detect primary amines. (c) Azo dye test: Determines the presence of aromatic primary amines. (d) Liebermann nitroso reaction: Helps in distinguishing between phenols and amines. Now, let's match each test with its related substances.

02

Match the tests with the substances

Using the information from Step 1, we can match each test in Column I with its related substances in Column II: (a) Hinsberg's test: Distinguishes between primary, secondary, and tertiary amines. Matches with (t) as it involves a secondary amine and a tertiary amine. (b) Carbylamine test: Detects primary amines. Matches with (p) which compares an aniline (aromatic primary amine) with an aryl secondary amine, and (s) as it compares a primary aliphatic amine with an aromatic primary amine. (c) Azo dye test: Determines the presence of aromatic primary amines. Matches (q) which compares an aniline (aromatic primary amine) with an aromatic secondary amine. (d) Liebermann nitroso reaction: distinguishing between phenols and amines. Matches with (r) which compares an aryl tertiary amine with an aromatic secondary amine. The proper matches are: (a) → (t) (b) → (p), (s) (c) → (q) (d) → (r)

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