Chapter 7: Problem 1
. What type of linkage is known as glycosidic linkage?
Chapter 7: Problem 1
. What type of linkage is known as glycosidic linkage?
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Get started for freeWhich of the following statements are not correct? (a) Hydrolysis of lactose gives D-glucose and D-galactose. (b) In sucrose, glucose is present in the furanose form while fructose is present in the pyranose form. (c) Gun cotton is cellulose triacetate. (d) On heating with dilute \(\mathrm{H}_{2} \mathrm{SO}_{4}\) under pressure, cellulose undergoes hydrolysis to give D-glucose.
Synthetic polymers are classified by their sequence of synthesis as chain growth or step growth polymers. Chain growth polymers are produced by chain reaction polymerization in which an initiator adds to a carbon-carbon double bond of a vinyl monomer to yield a reactive intermediate. The intermediate reacts with a second monomer to yield a new intermediate which reacts with a third unit and so on. The initiator may be a radical or an acid or an anion. Acid catalysed polymerization is effective in case of vinyl monomers having electron donating groups. Anionic polymerization requires the presence of electron withdrawing groups. One of the important catalysts used in polymerization is Ziegler-Natta catalyst (triethyl aluminium and titanium tetrachloride). One of the important aspects of Zeiglar-Natta catalysed polymers is that they are stereo-chemically controllable. Three forms (i) isotactic (ii) syndiotactic and (iii) atactic can be produced Vinylidene chloride \(\mathrm{H}_{2} \mathrm{C}=\mathrm{CCl}_{2}\) does not polymerize in isotactic, syndiotactic or atactic forms because (a) it contains electronegative chlorine atoms. (b) it has sp \(^{2}\) hybridized carbon. (c) it is a planar molecule. (d) the polymer formed has no chiral centre
This section contains multiple choice questions. Each question has 4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct. Interconversion of glucose, fructose and mannose when warmed with dilute alkali or amine is called (a) Fries rearrangement (b) Lobry de Bruyn-van Ekenstein rearrangement (c) Beckman's rearrangement (d) Hoffmann's rearrangement
Polyvinyl chloride is a/an (a) chain growth polymer (b) thermoplastic polymer (c) cross linked polymer (d) elastomer
This section contains multiple choice questions. Each question has 4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct. An organic compound was fused with sodium and the water extract was treated with silver nitrate solution when a black precipitate was obtained. The test suggests (a) absence of halogen (b) presence of sulphur (c) presence of nitrogen (d) presence of halogen
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