How will you prepare the following compounds? (a) Paladium (II) chloride (b) Sodium titanate (c) \(\left[\mathrm{Cd}\left(\mathrm{NH}_{3}\right)_{4}\right](\mathrm{OH})_{2}\)

Short Answer

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(a) Palladium (II) chloride is synthesized by reacting palladium metal with chlorine gas at elevated temperatures. (b) Sodium titanate is prepared by reacting titanium dioxide with sodium hydroxide, followed by calcination. (c) \(\left[\mathrm{Cd}\left(\mathrm{NH}_{3}\right)_{4}\right](\mathrm{OH})_{2}\) is synthesized in a two-step process involving the formation of an ammonia complex with cadmium, then reaction with hydroxide ions.

Step by step solution

01

Preparation of Paladium (II) Chloride

Palladium (II) chloride can be prepared by the reaction of palladium metal with chlorine gas. The reaction can be represented as follows: \(2 Pd (s) + Cl_{2} (g) \rightarrow 2 PdCl_{2} (s)\). This reaction typically takes place at elevated temperatures.
02

Preparation of Sodium Titanate

Sodium titanate can be prepared by the reaction of titanium dioxide with sodium hydroxide, followed by calcination. The reaction may be represented as follows: \(TiO_{2} (s) + 2NaOH (aq) \rightarrow Na_{2}TiO_{3} (s) + H_{2}O (l)\). The calcination is the heating process used to drive off water.
03

Preparation of \(\left[\mathrm{Cd}\left(\mathrm{NH}_{3}\right)_{4}\right](\mathrm{OH})_{2}\)

This complex compound can be prepared in two steps. First, cadmium reacts with ammonia to form an ammonia complex: \(Cd(s) + 4 NH_{3}(aq) \rightarrow [Cd(NH_{3})_{4}]^{2+}\). Next, this complex reacts with hydroxide ions to form the final product: \([Cd(NH_{3})_{4}]^{2+} + 2 OH^- \rightarrow [Cd(NH_{3})_{4}](OH)_{2}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Palladium (II) Chloride Synthesis
Palladium (II) chloride, often represented as PdCl2, is a vital inorganic compound in various industrial and laboratory applications. The synthesis of palladium (II) chloride can be achieved through a reaction that involves heating palladium metal in the presence of chlorine gas. During this process, the palladium metal is oxidized and chlorine is reduced, forming the ionic compound PdCl2.

This reaction is exothermic and generally requires a controlled environment to safely manage the release of heat. Safety precautions are necessary because chlorine gas is both toxic and corrosive. The product, palladium (II) chloride, is a solid powder that has significant use in catalysis and as a precursor to other palladium compounds.
  • Direct combination of elements: Palladium metal reacts with chlorine.
  • High temperature is critical for reaction progression.
  • Industrial safety standards are vital.
Sodium Titanate Preparation
In the world of inorganic chemistry, the preparation of sodium titanate showcases an interesting reaction between a metal oxide and a strong base. The synthesis starts with titanium dioxide (TiO2), a white powder, reacting with sodium hydroxide (NaOH). The process includes a calcination step where the reaction product is heated to a high temperature to remove any water that was formed.

This procedure not only forms sodium titanate but also illustrates the transformation of raw inorganic materials to more complex structures. Sodium titanate, outlined by its formula Na2TiO3, has applications in waste treatment and photocatalysis due to its adsorptive and light-absorbing properties.
  • Reaction between metal oxide and strong base.
  • Calcination to remove excess water and solidify the product.
  • Relevance in environmental and photocatalytic applications.
Ammonia Complex Formation
Complexes play an essential role in fields ranging from coordination chemistry to bioinorganic processes. When forming an ammonia complex, we start by introducing a metal ion, in this case cadmium, to an ammonia solution. Upon this interaction, the cadmium ion forms coordinate bonds with the surrounding ammonia molecules, constructing what’s known as an ammonia complex ion.

The formation of such complexes demonstrates the concept of coordination chemistry, where metal ions bind with ligands—in this case, ammonia—to form a new entity. In this process, ammonia acts as a ligand, donating a pair of electrons to the metal ion to form a stable complex. This action exhibits the Lewis acid-base interaction fundamental to the formation of coordination compounds.
  • Formation involves coordinate bond creation.
  • Ammonia acts a ligand in the complex.
  • Relevant in understanding Lewis acid-base theory.
Inorganic Synthesis Reactions
Diving into the realm of inorganic synthesis reactions opens up an array of procedures to create inorganic compounds. Fundamentally, these reactions involve the interaction of various substances, typically involving metals and non-metals, to create products with new chemical structures and properties. In the instances of PdCl2, sodium titanate, and cadmium ammonia complexes, we see a blend of direct combination, reaction with bases, and complex formation.

From the production of catalysts to the development of materials with unique properties, mastering inorganic synthesis reactions enables us to tailor-make compounds for specific applications. These reactions require precision and an understanding of the elemental properties.
  • Involves creating new compounds with diverse methods.
  • Varies from direct synthesis to complexation.
  • Crucial for tailored applications ranging from catalysis to materials science.
Coordination Compounds
Coordination compounds are distinctive molecules where metal atoms or ions are surrounded by various ligands (neutral molecules or anions that donate electrons). This unique configuration gives rise to remarkable properties that are exploited in many areas of chemistry and technology, such as catalysis, biological systems, and material science.

The ammonia complex of cadmium, \(\left[\mathrm{Cd}\left(\mathrm{NH}_{3}\right)_{4}\right](\mathrm{OH})_{2}\), is a classic example of a coordination compound. These entities highlight the principles of coordination chemistry, including charge balance, coordination number, and geometric structure. Understanding these principles is critical for chemists to manipulate and utilize the potential of coordination compounds in various applications.
  • Consist of a central metal ion and surrounding ligands.
  • Ligands donate electron pairs to the metal ion.
  • Important in myriad chemical applications and industries.

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