Chapter 32: Problem 7

What are coordination polymers? Discuss the charateristics of coordination polymers.

Short Answer

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Coordination polymers are polymers with metal atoms or ions linked to a number of anionic or neutral ligands. They are characterized by their diversity in structure, tunable properties, potential for porosity, and responsiveness to various stimuli. An example of these polymers is Metal-organic frameworks (MOFs).

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Definition

Coordination polymers are a series of polymers which have metal atoms or ions that are coordinated, or linked, to a number of anionic or neutral ligands. These structures can vary in complexity from simple chains to three-dimensional networks.

Characteristics of Coordination Polymers

Coordination polymers are characterized by their structure and the various properties that result from it. Some of the main characteristics include: 1. Versatility and diversity in structure, which come from the variety of metals and ligands that can be used. 2. Tunable properties, which mean they can be manipulated for specific applications. 3. Potential for porosity, allowing for applications in areas like gas storage and separation. 4. Responsiveness to various stimuli, such as light, temperature, or pressure, which can lead to changes in the polymer structure.

Examples of Coordination Polymers

Some examples of coordination polymers include metal-organic frameworks (MOFs), which consist of metal ions or clusters coordinated to organic ligands to form one-, two-, or three-dimensional structures.

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What are coordination polymers? Discuss the charateristics of coordination polymers.

Short Answer

Step by step solution

Definition

Characteristics of Coordination Polymers

Examples of Coordination Polymers

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