What are the colour changes observed during titration of a solution of sodium carbonate with hydrochloric acid using two drops each of phenolphthalein and methyl orange? What is the reason behind these colour changes?

Short Answer

Expert verified
The colour changes observed during titration are: from pink (phenolphthalein) and yellow (methyl orange) to colorless (phenolphthalein) and red (methyl orange). They occur due to the change in pH of the solution – when it becomes less than 8.2, phenolphthalein turns colorless and when it becomes less than 4.4, methyl orange turns red.

Step by step solution

01

Describe Initial Conditions

Initially, the sodium carbonate solution is alkaline in nature. When we add phenolphthalein, it turns pink because the pH is above 8.2. Similarly, methyl orange turns yellow as the initial pH is above 4.4.
02

Explain Color Change 1

As we start adding hydrochloric acid to the solution, it will react with sodium carbonate to neutralize it. When the pH drops below 8.2, phenolphthalein changes color from pink to colorless, indicating the completion of the reaction between hydrochloric acid and sodium carbonate.
03

Explain Color Change 2

Continuing to add more acid, when the pH drops below 4.4, methyl orange will change from yellow to red. This signifies that all the carbonate ions have been neutralized and the solution is now acidic.
04

Understand the Occurrence

The color changes occur due to the properties of the indicators used. Phenolphthalein changes color in the pH range of 8.0 to 10.0, and methyl orange changes color in the pH range of 3.1 to 4.4. These indicators detect the change in pH of the solution due to the acid-base neutralization reaction.

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