Give reasons for the following: (a) size of a Cation is smaller than its parent atom. (b) Size of an anion is larger than its parent atom. (c) Radius of argon is greater than that of chlorine. (d) Be and Al show similar properties. (e) The first electron affinity of oxygen is positive but the second electron affinity is negative. (f) The difference of atomic size between lithium and beryllum is much greater than between sodium and magnesium.

Short Answer

Expert verified
The sizes of ions compared to their parent atoms are influenced by changes in fundamental properties such as electron shielding and effective nuclear charge when an electron is either added or removed to form the ions. The atomic radius comparison between Argon and Chlorine, as well as the atomic size difference of Lithium and Beryllium versus Sodium and Magnesium, can be understood in light of their positions in the periodic table and the variation in nuclear charge and shielding effect. Elements in the same group of the periodic table like Beryllium and Aluminum exhibit similarity in properties due to comparable electron configurations. The variance in oxygen's first and second electron affinities is because of electron-electron repulsion that increases energy requirement.

Step by step solution

01

Size of Cation vs. its Parent Atom

A cation is formed when a neutral atom loses an electron. The loss of negatively charged electrons slightly reduces electrostatic repulsion in the electron cloud and allows the positively charged nucleus to pull the remaining electrons closer. This makes the size of the cation smaller than its parent atom.
02

Size of Anion vs. its Parent Atom

An anion is formed when a neutral atom gains an electron. This extra electron increases electrostatic repulsion in the electron cloud, causing the electrons to spread out more and consequently, the anion is larger than its parent atom.
03

Radius of Argon and Chlorine

Argon and Chlorine are found in the same period in the periodic table, but Argon is located to the right of Chlorine. Whenever you move right across a period, there's a general increase in nuclear charge without much increase in shielding effect. So, the electron cloud is drawn closer to the nucleus resulting in larger atomic radius for Argon than Chlorine.
04

Similar Properties of Be and Al

Be (Beryllium) and Al (Aluminium) both belong to group 2A in the periodic table (Aluminium usually behaves like a group 3A element, but it can sometimes show similar properties as group 2A elements). This means they have similar electron configurations and thus, similar chemical properties.
05

First and Second Electron Affinity of Oxygen

Electron affinity is the energy change that occurs when an electron is added to a neutral atom. The first electron affinity of Oxygen is positive because energy is released when an electron is added to a neutral Oxygen atom. However, the second electron affinity is negative because energy is required to overcome the electron-electron repulsion to add another electron to the already negative O^- ion.
06

Atomic Size Between Lithium and Beryllium vs. Sodium and Magnesium

The atomic size difference between lithium and beryllium is greater than between sodium and magnesium. This can be explained by the fact that lithium and beryllium are in period 2, close to the top of the periodic table where the atomic sizes vary greatly within periods due to significant increase in effective nuclear charge. Sodium and Magnesium are in period 3 where atomic sizes do not vary as much within the same period.

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