Arsonic and nitric acids react to form nitrogen monoxide, arsenic acid and water according to the equation shown below. Is this an example of a redox reaction? \(2 \mathrm{HNO}_{3}(a q)+3 \mathrm{H}_{3} \mathrm{AsO}_{3}(a q) \rightarrow 2 \mathrm{NO}(g)+3 \mathrm{H}_{3} \mathrm{AsO}_{4}(a q)+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})\)

Short Answer

Expert verified
Yes, this is a redox reaction, as nitrogen is being reduced from +5 to +2, and arsenic is being oxidized from +3 to +5.

Step by step solution

01

- Identify the Oxidation States of Elements

To determine if a reaction is a redox reaction, identify the oxidation states of elements in the reactants and products. In each compound, assign the oxidation numbers based on the known oxidation states of common elements and the rules of determining oxidation states.
02

- Determine Changes in Oxidation States

Compare the oxidation numbers from reactants to products for each element to see if any element's oxidation number has changed. A change in the oxidation number indicates that a redox reaction has occurred.
03

- Analyze the Oxidation State Changes

Nitrogen in HNO_3 goes from +5 to +2 in NO, losing 3 electrons therefore being reduced, while Arsenic in H3AsO3 goes from +3 to +5 in H3AsO4, gaining 2 electrons thus being oxidized. Since both oxidation and reduction are taking place, this reaction is a redox reaction.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation States
Understanding oxidation states is crucial when analyzing redox reactions, which involve the transfer of electrons between chemical species. An oxidation state, often referred to as an oxidation number, is a theoretical charge that an atom would have if all bonds to atoms of different elements were completely ionic.

The rules for assigning oxidation states include considering known values, such as the fact that oxygen usually carries a -2 charge (except in peroxides or when bonded to fluorine), hydrogen has a +1 when bonded to non-metals, and metals typically have positive values corresponding to their group number in the Periodic Table.

Accurately determining oxidation states is the key first step in identifying redox processes. Once these states are known, changes in them between reactants and products reveal which atoms are oxidized and which are reduced.
Chemical Reactions
Chemical reactions are processes that transform one set of chemical substances into another. They are the foundation of chemistry and involve the making and breaking of chemical bonds.

Reactions can be categorized into many types, with redox reactions being one such type. A redox reaction consists of two concurrent processes: oxidation, where a substance loses electrons, and reduction, where a substance gains electrons. These reactions are ubiquitous in both nature and technology, contributing to processes such as metabolism and battery operation.
Balancing Chemical Equations
Balancing chemical equations is necessary to satisfy the law of conservation of mass, which states that matter cannot be created nor destroyed in a chemical reaction. Thus, the quantity of each element must be the same in both the reactants and products.

To balance a chemical equation, one should adjust the coefficients in front of compounds until the number of atoms for each element is the same on both sides of the reaction. For redox reactions, it's often helpful to balance the equations by ensuring that the number of electrons lost in oxidation equals the number of electrons gained in reduction.
Reduction and Oxidation
Reduction and oxidation are the two key processes that comprise redox reactions. Oxidation is the loss of electrons, which increases an atom's oxidation state, while reduction is the gain of electrons, decreasing an atom's oxidation state.

These processes are interconnected: whenever one substance is oxidized, another is reduced. This reciprocity is known as the oxidation-reduction pairing and is represented in an equation where the oxidizing agent gets reduced, and the reducing agent gets oxidized.

An easy way to remember this is the mnemonic 'OIL RIG'—which stands for 'Oxidation Is Loss, Reduction Is Gain' of electrons. In the exercise example, arsenic is oxidized (it becomes more positive), and nitrogen is reduced (it becomes more negative), demonstrating a classic redox reaction.

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Most popular questions from this chapter

Write a balanced chemical equation for the reactions given below: a. When hydrogen gas reacts is combined with oxygen gas and the mixture ignited with a spark, water is formed in a violent reaction. b. Lead (IV) oxide reacts with HCl to give lead (II) chloride, chlorine gas and water. c. Solid potassium chlorate decomposes on heating to form solid KCl and oxygen gas.

For each of the reactions given below, calculate the oxidation number of each of the elements in the reactants and the products and determine if the reaction involves oxidation-reduction. If it is a redox reaction, identify the elements that have been oxidized and reduced. a. \(\mathrm{Cu}_{2} \mathrm{~S} \rightarrow 2 \mathrm{Cu}+\mathrm{S}\) Reactants: Cu ___________ \(\mathrm{S}\) ___________ Products: Cu ___________ \(\mathrm{S}\) ___________ Element oxidized: ___________ Element Reduced ___________ b. \(\mathrm{CaCO}_{3} \rightarrow \mathrm{CaO}+\mathrm{CO}_{2}\) Reactants: Ca ___________ C ___________ O ___________ Products: \(\mathrm{Ca}\) ___________ \(C\) ___________ O ___________ Element oxidized: ___________ Element Reduced ___________ c. \(\mathrm{Fe}_{2} \mathrm{O}_{3}+3 \mathrm{H}_{2} \rightarrow 2 \mathrm{Fe}+3 \mathrm{H}_{2} \mathrm{O}\) Reactants: Fe ___________ O ___________ \(\mathrm{H}\) ___________ Products: Fe ___________ O ___________ \(\mathrm{H}\) ___________ Element oxidized: ___________ Element Reduced ___________ \(\mathrm{d} . \mathrm{AgNO}_{3}+\mathrm{NaCl} \rightarrow \mathrm{AgCl}(\mathrm{s})+\mathrm{NaNO}_{3}\) Reactants: Ag ___________ \(\mathrm{N}\) ___________ \(\mathrm{O}\) ___________ \(\mathrm{Na}\) ___________ \(\mathrm{Cl}\) ___________ Products: \(\mathrm{Ag} \) ___________ \( \mathrm{N}\) ___________ \( \mathrm{O}\) ___________ \( \mathrm{Na}\) ___________ Element oxidized: ___________ Element Reduced ___________

a. Write a chemical equation for the reaction of solid iron with solid sulfur to form solid iron(II) sulfide. b. Write a chemical equation for the reaction of solid carbon with solid magnesium oxide to form carbon monoxide gas and magnesium metal.

Mixing each of the following salt solutions results in the formation of a precipate. In each case, identify the insoluble salt. a. \(\mathrm{NaCl}+\mathrm{Pb}\left(\mathrm{NO}_{3}\right) 2\) b. \(\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\right) 3+\mathrm{KOH}\) c. \(\mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2}+\mathrm{K}_{2} \mathrm{SO}_{4}\) d. \(\mathrm{Li}_{2} \mathrm{~S}+\mathrm{CuSO}_{4}\) e. \(\mathrm{Co}\left(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\right)_{2}+\mathrm{LiOH}\)

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