Chapter 6: Problem 1
Lead (IV) chloride reacts with fluorine gas to give lead (IV) fluoride and \(\mathrm{Cl}_{2}\). If \(0.023\) moles of fluorine gas reacts with \(5.3\) grams of lead (IV) chloride, what mass of lead (IV) fluoride will be formed?
Short Answer
Expert verified
4.33236 grams of lead (IV) fluoride will be formed.
Step by step solution
01
Write the balanced chemical equation
To solve the problem, we first need to write the balanced chemical equation for the reaction between lead (IV) chloride (PbCl4) and fluorine gas (F2). The reaction produces lead (IV) fluoride (PbF4) and chlorine gas (Cl2). The balanced equation is: PbCl4 + 4F2 -> PbF4 + 2Cl2
02
Calculate moles of PbCl4
We can calculate the moles of lead (IV) chloride used in the reaction by using its molar mass. The molar mass of PbCl4 is Pb + 4 * Cl = 207.2 g/mol + 4 * 35.453 g/mol = 346.012 g/mol. Using the provided mass of PbCl4 (5.3 grams), we calculate the moles of PbCl4 as follows:moles of PbCl4 = mass of PbCl4 / molar mass of PbCl4 = 5.3 g / 346.012 g/mol = 0.0153 moles
03
Compare mole ratio to determine the limiting reactant
The chemical equation shows that 1 mole of PbCl4 reacts with 4 moles of F2 to produce 1 mole of PbF4. We need to compare the mole ratio of PbCl4 to F2 to find the limiting reactant.We have 0.0153 moles of PbCl4 and 0.023 moles of F2. According to the chemical equation, the required ratio of PbCl4 to F2 is 1:4. Because we have more than enough F2 to react with the available PbCl4, PbCl4 is the limiting reactant.
04
Calculate the mass of PbF4 produced
The reaction will produce 1 mole of PbF4 for every mole of PbCl4 that reacts. Since PbCl4 is the limiting reactant, we can use its moles to find the expected moles of PbF4 produced:moles of PbF4 = moles of PbCl4 = 0.0153 molesTo find the mass of PbF4 formed, we multiply the moles by the molar mass of PbF4 (Pb + 4 * F = 207.2 g/mol + 4 * 19 g/mol = 283.2 g/mol):mass of PbF4 = moles of PbF4 * molar mass of PbF4 = 0.0153 moles * 283.2 g/mol = 4.33236 grams.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Stoichiometry
Stoichiometry is like a recipe for chemists. It tells you how much of each reactant you need to react together, and what amount of product you will get out at the end. Think of it as the art of balancing and interpreting chemical recipes.
In our example, stoichiometry tells us how to convert between moles of lead (IV) chloride and fluorine gas to find out the mass of lead (IV) fluoride that forms. It all hinges on the balanced chemical equation, which gives us the exact ratio of reactants to products. This ratio is critical because it ensures that atoms are conserved in the reaction—meaning that the number of atoms going into the reaction equals the number of atoms coming out.
When performing stoichiometric calculations, we have to be precise with our measurements. Here, we convert grams of lead (IV) chloride to moles, compare the available moles of reactants to figure out the limiting reactant, and finally, we calculate the mass of lead (IV) fluoride produced based on the stoichiometry of the balanced equation. This process ensures that our chemical 'recipe' is successful and we aren't left with unreacted ingredients.
In our example, stoichiometry tells us how to convert between moles of lead (IV) chloride and fluorine gas to find out the mass of lead (IV) fluoride that forms. It all hinges on the balanced chemical equation, which gives us the exact ratio of reactants to products. This ratio is critical because it ensures that atoms are conserved in the reaction—meaning that the number of atoms going into the reaction equals the number of atoms coming out.
When performing stoichiometric calculations, we have to be precise with our measurements. Here, we convert grams of lead (IV) chloride to moles, compare the available moles of reactants to figure out the limiting reactant, and finally, we calculate the mass of lead (IV) fluoride produced based on the stoichiometry of the balanced equation. This process ensures that our chemical 'recipe' is successful and we aren't left with unreacted ingredients.
Limiting Reactant
The limiting reactant is the ingredient that runs out first in a chemical reaction, limiting the amount of product that can be formed, much like running out of flour can limit the number of cookies you can bake.
Identifying the Limiting Reactant
To identify the limiting reactant in our problem, we compared the mole ratio of the reactants with what is needed according to the balanced chemical equation. In this case, lead (IV) chloride is the limiting reactant because it runs out before the fluorine gas.Why is Finding the Limiting Reactant Important?
Knowing the limiting reactant is important because it determines the maximum amount of product that can form. Once the limiting reactant is consumed, the reaction stops, and no additional product can be created. Understanding this concept is essential, as it allows us to predict and control the outcome of chemical reactions efficiently.Molar Mass
The molar mass is like the 'weight' of a mole of a substance. It's calculated by adding up the masses of all the atoms in a molecule. In our everyday life, we can compare it to knowing the weight of a bag of rice to determine how many bags we'll need for a meal.
In chemistry, the molar mass is crucial because it bridges the gap between the macroscopic world we can measure and the microscopic world of atoms and molecules. By knowing the molar mass of lead (IV) chloride and fluorine gas, we can convert between the mass of a substance (in grams) and the amount of substance (in moles), which is necessary for carrying out stoichiometric calculations and determining the yield of a reaction.
For the exercise, we found the molar mass of lead (IV) chloride to be 346.012 g/mol and used it to convert the given mass to moles. Similarly, the molar mass of lead (IV) fluoride is 283.2 g/mol, which we used to convert moles back to grams to answer the question. Without understanding of molar mass, we wouldn't be able to make these vital conversions.
In chemistry, the molar mass is crucial because it bridges the gap between the macroscopic world we can measure and the microscopic world of atoms and molecules. By knowing the molar mass of lead (IV) chloride and fluorine gas, we can convert between the mass of a substance (in grams) and the amount of substance (in moles), which is necessary for carrying out stoichiometric calculations and determining the yield of a reaction.
For the exercise, we found the molar mass of lead (IV) chloride to be 346.012 g/mol and used it to convert the given mass to moles. Similarly, the molar mass of lead (IV) fluoride is 283.2 g/mol, which we used to convert moles back to grams to answer the question. Without understanding of molar mass, we wouldn't be able to make these vital conversions.
Balanced Chemical Equation
A balanced chemical equation is the cornerstone of understanding chemical reactions. It's similar to making sure both sides of a seesaw are evenly balanced, but instead of children, we're balancing atoms!
Every balanced chemical equation adheres to the Law of Conservation of Mass, meaning the number of atoms of each element must be the same on both sides of the equation. This balance is important for stoichiometry because it provides the mole ratio of reactants to products, which is used to calculate how much product is made from a given amount of reactant.
In the exercise, we balanced the chemical equation before solving for the mass of lead (IV) fluoride. Without this balanced equation, we would not know how many moles of each reactant are required to produce the desired product, making it impossible to carry out the rest of the stoichiometric calculations. It's the foundation upon which all the subsequent steps are built.
Every balanced chemical equation adheres to the Law of Conservation of Mass, meaning the number of atoms of each element must be the same on both sides of the equation. This balance is important for stoichiometry because it provides the mole ratio of reactants to products, which is used to calculate how much product is made from a given amount of reactant.
In the exercise, we balanced the chemical equation before solving for the mass of lead (IV) fluoride. Without this balanced equation, we would not know how many moles of each reactant are required to produce the desired product, making it impossible to carry out the rest of the stoichiometric calculations. It's the foundation upon which all the subsequent steps are built.