Aluminum and chlorine gas react to form aluminum chloride according to the balanced equation shown in below. $$ 2 \mathrm{Al}(s)+3 \mathrm{Cl}_{2}(g) \rightarrow 2 \mathrm{AlCl}_{3}(s) $$ If \(17.467\) grams of chlorine gas are allowed to react with excess \(\mathrm{Al}\), what mass of solid aluminum chloride will be formed?

Short Answer

Expert verified
The mass of solid AlCl3 formed from 17.467 grams of Cl2 with excess Al is calculated by converting the mass of Cl2 to moles, using the stoichiometric ratio to find moles of AlCl3, and then converting back to grams.

Step by step solution

01

Calculate the molar mass of chlorine gas (Cl2)

The molar mass of chlorine is 35.45 grams per mole. Since chlorine gas is diatomic (Cl2), the molar mass of Cl2 is 2 * 35.45 grams per mole, which equals 70.90 grams per mole.
02

Calculate the number of moles of Cl2

Divide the mass of chlorine gas by the molar mass of chlorine gas to get the number of moles. The calculation is as follows: number of moles = 17.467 grams / 70.90 grams per mole.
03

Use the balanced equation to find the mole ratio

According to the balanced chemical equation, 3 moles of Cl2 produce 2 moles of AlCl3. We will use this ratio to convert moles of Cl2 to moles of AlCl3.
04

Calculate the number of moles of AlCl3

The mole ratio from the balanced equation is 3 moles of Cl2 : 2 moles of AlCl3. Using the number of moles of Cl2 from Step 2, calculate the number of moles of AlCl3 produced.
05

Calculate the molar mass of AlCl3

The molar mass of AlCl3 is found by adding the molar mass of aluminum (26.98 grams per mole) to three times the molar mass of chlorine (3 * 35.45 grams per mole). The total is the molar mass of AlCl3.
06

Calculate the mass of aluminum chloride (AlCl3) formed

Multiply the number of moles of AlCl3 by its molar mass to find the mass of aluminum chloride produced.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
Understanding the concept of molar mass is crucial when dealing with chemical reactions and stoichiometry. Molar mass is defined as the mass of one mole of a substance, usually expressed in grams per mole (g/mol). It serves as a bridge between the atomic scale and the macroscopic scale. To calculate the molar mass, you add up the atomic masses of all the atoms in the molecule. For example, in the given exercise, chlorine gas (Cl2) consists of two chlorine atoms. Since the atomic mass of chlorine is 35.45 g/mol, you simply multiply this by two, leading to a molar mass of 70.90 g/mol for Cl2.

This step is essential and it provides baseline information to move forward with the problem. It allows us to convert from grams to moles, which is a fundamental skill for any subsequent stoichiometric calculation.
Chemical Reaction Balancing
Balancing chemical equations is a vital step in solving stoichiometry problems. A balanced equation ensures that the same number of atoms for each element is present on both sides of the reaction, showing the conservation of mass. In our exercise, the chemical equation is already balanced:2 Al(s) + 3 Cl2(g) → 2 AlCl3(s).

This tells us the exact ratio in which reactants combine and products form, which is crucial for the stoichiometry calculations. For every two moles of aluminum reacted, three moles of chlorine are required, and two moles of aluminum chloride are produced. The coefficients in the equation (2, 3, and 2) directly state the mole ratios, which we then use to predict the amount of product formed from a given amount of reactant. It's important to comprehend this concept thoroughly, as stoichiometry hinges on the relationship between these coefficients.
Mole-to-Mass Conversion
Once the chemical equation is balanced and the molar mass of the reactants and products determined, we can perform a mole-to-mass conversion. The goal is to convert moles of one substance to grams of another substance using the balanced equation as the conversion factor. From our exercise, after finding the moles of Cl2, we use the mole ratio of Cl2 to AlCl3 from the equation to determine moles of AlCl3. This is followed by multiplying the moles of AlCl3 by its calculated molar mass to find the mass in grams of AlCl3 produced.

Quick Guide

  • Identify the number of moles of one substance from the mass given in the problem.
  • Use the mole ratio from the balanced equation to find the moles of a product or another reactant.
  • Multiply by the molar mass of the product or reactant of interest to find the mass.
Mastering mole-to-mass conversion is crucial, as it allows one to quantitatively predict the outcomes of chemical reactions.

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Most popular questions from this chapter

Lead (IV) chloride reacts with fluorine gas to give lead (IV) fluoride and \(\mathrm{Cl}_{2}\). If \(0.023\) moles of fluorine gas reacts with \(5.3\) grams of lead (IV) chloride, what mass of lead (IV) fluoride will be formed?

Ammonia is produced industrially from nitrogen and hydrogen according to the equation: $$ \mathrm{N}_{2}+3 \mathrm{H}_{2} \rightarrow 2 \mathrm{NH}_{3} $$ a. If you are given \(6.2\) moles of nitrogen how many mole of ammonia could you produce? b. How many moles of hydrogen would you need to fully react with \(6.2\) moles of nitrogen? C. If you wished to produce 11 moles of ammonia how many moles of nitrogen would you need to start with?

The Harber process is used making ammonia from nitrogen and hydrogen according to the equation shown below. The yield of the reaction, however, is not \(100 \%\). a. Suppose you end up with \(6.2\) moles of ammonia, but the reaction stoichiometry predicts that you should have \(170.0\) grams of ammonia. What is the percent yield for this reaction? b. If you started with \(6.2\) grams of nitrogen and you produce \(6.2\) grams of ammonia what would be the percent yield?

a. Iron (III) oxide reacts with hydrogen gas to form elemental iron and water, according to the balanced equation shown below. How many moles of iron will be formed from the reduction of excess iron (III) oxide by \(0.58\) moles of hydrogen gas? b. When an impure sample containing an unknown amount of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) is reacted with excess hydrogen gas, \(0.16\) moles of solid Fe are formed. How many moles of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) were in the original sample?

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