1\. For each of the following, write a balanced neutralization equation: a. The reaction of calcium hydroxide with hydrochloric acid. b. The reaction of sodium hydroxide with sulfuric acid (both ionizations). c. The reaction of barium hydroxide with nitric acid. 2\. Write a balanced neutralization equation for the reaction of calcium hydroxide with sulfuric acid

Short Answer

Expert verified
The balanced neutralization equations are: a) \( Ca(OH)_2 + 2HCl \rightarrow CaCl_2 + 2H_2O \), b) \( 2NaOH + H_2SO_4 \rightarrow Na_2SO_4 + 2H_2O \), c) \( Ba(OH)_2 + 2HNO_3 \rightarrow Ba(NO_3)_2 + 2H_2O \), and the reaction of calcium hydroxide with sulfuric acid is \( Ca(OH)_2 + H_2SO_4 \rightarrow CaSO_4 + 2H_2O \)

Step by step solution

01

Write the Formula for Calcium Hydroxide and Hydrochloric Acid

The first step is to write down the chemical formulas for calcium hydroxide and hydrochloric acid, which are \( Ca(OH)_2 \) and \( HCl \), respectively.
02

Write the Unbalanced Equation for Reaction (a)

Write out the reactants and the expected products. For this reaction, calcium chloride and water are the products. The unbalanced chemical equation is: \( Ca(OH)_2 + HCl \rightarrow CaCl_2 + H_2O \).
03

Balance the Equation for Reaction (a)

Balance the equation by ensuring there are equal numbers of each atom on both sides. The balanced equation is: \( Ca(OH)_2 + 2HCl \rightarrow CaCl_2 + 2H_2O \).
04

Write the Formulas for Sodium Hydroxide and Sulfuric Acid

For reaction (b), write down the chemical formulas for sodium hydroxide and sulfuric acid, which are \( NaOH \) and \( H_2SO_4 \) respectively.
05

Write the Unbalanced Equation for Reaction (b)

Write out the reactants and the expected products for both ionizations of sulfuric acid. Products include sodium sulfate and water. The unbalanced chemical equation is: \( 2NaOH + H_2SO_4 \rightarrow Na_2SO_4 + H_2O \).
06

Balance the Equation for Reaction (b)

Balance the equation by ensuring there are equal numbers of each type of atom on both sides. The balanced equation is: \( 2NaOH + H_2SO_4 \rightarrow Na_2SO_4 + 2H_2O \).
07

Write the Formulas for Barium Hydroxide and Nitric Acid

For reaction (c), write down the chemical formulas for barium hydroxide and nitric acid, which are \( Ba(OH)_2 \) and \( HNO_3 \) respectively.
08

Write the Unbalanced Equation for Reaction (c)

List out the reactants and products, including barium nitrate and water. The unbalanced chemical equation is: \( Ba(OH)_2 + HNO_3 \rightarrow Ba(NO_3)_2 + H_2O \).
09

Balance the Equation for Reaction (c)

To balance the equation, adjust the coefficients to get equal numbers of each type of atom on both sides. The balanced equation is: \( Ba(OH)_2 + 2HNO_3 \rightarrow Ba(NO_3)_2 + 2H_2O \).
10

Write the Formulas for Calcium Hydroxide and Sulfuric Acid

For the reaction of calcium hydroxide with sulfuric acid, write down the chemical formulas, which are \( Ca(OH)_2 \) and \( H_2SO_4 \) respectively.
11

Write the Unbalanced Equations for Reaction of Calcium Hydroxide with Sulfuric Acid

Write out the reactants and products, including calcium sulfate and water. The unbalanced equation is: \( Ca(OH)_2 + H_2SO_4 \rightarrow CaSO_4 + H_2O \).
12

Balance the Equation for Reaction with Calcium Hydroxide and Sulfuric Acid

Balance the equation so that there are the same numbers of each atom on both sides. The balanced equation is: \( Ca(OH)_2 + H_2SO_4 \rightarrow CaSO_4 + 2H_2O \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Formulas
Understanding chemical formulas is the first pivotal step in chemistry, as they serve as a shorthand to indicate the types and numbers of atoms present in a molecule or compound. For example, the formula for calcium hydroxide is represented as \( Ca(OH)_2 \), indicating one calcium atom bonded to two hydroxyl groups (each with one oxygen and one hydrogen atom).

Similarly, for hydrochloric acid, the formula \( HCl \) shows one hydrogen atom bonded to one chlorine atom. Aligning the theory with practice, when you write down these formulas, you lay the foundation to comprehend how substances will interact during a reaction—such as in neutralization, where an acid like \( HCl \) reacts with a base like \( Ca(OH)_2 \) to form salt and water.
Balancing Chemical Equations
To follow the law of conservation of mass, balancing chemical equations is necessary, meaning the number of each type of atom must be equal on both sides of the equation. The process involves adjusting coefficients, the numbers before each chemical formula, to attain this balance.

Without this critical step, the equation would not correctly reflect reality. When the equation \( Ca(OH)_2 + HCl \rightarrow CaCl_2 + H_2O \) is adjusted to \( Ca(OH)_2 + 2HCl \rightarrow CaCl_2 + 2H_2O \), it shows that two moles of hydrochloric acid react with one mole of calcium hydroxide to produce one mole of calcium chloride and two moles of water, abiding by the balanced equation rule.
Acid-Base Reactions
At the heart of a neutralization equation lies an acid-base reaction, a process where an acid reacts with a base to form a salt and typically water. Acids are substances that can donate protons (\( H^+ \) ions), while bases can accept them. Neutralization typically results in a pH closer to 7, which is neutral on the pH scale.

This describes what's occurring in our textbook exercises: hydrochloric acid (an acid) reacts with calcium hydroxide (a base) in a 2:1 molar ratio to yield calcium chloride and water. Using acid-base reactions to solve real-world problems extends beyond the classroom—it's involved in areas like medicine, environmental science, and industrial chemistry.
Stoichiometry
Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It relies on the balanced equations for calculating the amount of reactants needed or products formed. In the context of our neutralization reactions such as \( Ca(OH)_2 + 2HCl \rightarrow CaCl_2 + 2H_2O \), stoichiometry would allow us to predict how much calcium chloride and water would result from a given amount of calcium hydroxide and hydrochloric acid.

It is a critical concept when scaling up reactions for industrial purposes or assessing the yield from a chemical procedure. Accurate stoichiometry is important not only for academic exercises but for the safe and efficient production of chemical products.

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Most popular questions from this chapter

1\. You are given a solution containing an unknown concentration of HCl. You carefully measure \(50.0 \mathrm{~mL}\) of this solution into a flask and then add a few drops of phenolphthalein solution. You prepare a buret containing \(0.055 \mathrm{M} \mathrm{NaOH}\) and note that the initial level of the solution in the buret is \(12.6 \mathrm{~mL}\). You slowly add the \(\mathrm{NaOH}\) solution to the acid until the color change just occurs (as evidence of the color change becomes visible, you carefully stir the solution after each drop has been added). When the acid solution turns (and remains) pink, you note that the volume in the buret is now \(28.9 \mathrm{~mL}\). What is the concentration of the unknown acid solution? 2\. If \(25.00 \mathrm{~mL}\) of \(\mathrm{HCl}\) solution with a concentration of \(0.1234 \mathrm{M}\) is neutralized by \(23.45 \mathrm{~mL}\) of \(\mathrm{NaOH}\), what is the concentration of the base?

1\. A solution is known to have a hydronium ion concentration of \(4.5 \times 10^{-5} \mathrm{M}\); what is the \(p \mathrm{H}\) this solution? 2\. A solution is known to have a \(p \mathrm{H}\) of \(9.553\); what is the concentration of hydronium ion in this solution? 3\. A solution is known to have a hydronium ion concentration of \(9.5 \times 10^{-8} \mathrm{M}\); what is the \(p \mathrm{H}\) this solution? 4\. A solution is known to have a pH of \(4.57\); what is the hydronium ion concentration of this solution?

Calculating \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]\) and \(\left[\mathrm{HO}^{-}\right]\) using \(\mathrm{K} \mathrm{W}\) 1\. A solution at \(25^{\circ} \mathrm{C}\), is known to have a hydronium ion concentration of \(4.5 \times 10^{-5} \mathrm{M}\); what is the concentration of hydroxide ion in this solution? 2\. A solution at \(25^{\circ} \mathrm{C}\), is known to have a hydroxide ion concentration of \(7.5 \times 10^{-2} \mathrm{M}\); what is the concentration of hydronium ion in this solution? 3\. A solution is known to have a hydronium ion concentration of \(9.5 \times 10^{-8} \mathrm{M}\); what is the concentration of hydroxide ion in this solution?

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