Use the ideal gas law to show that \(28.0 \mathrm{~g}\) of nitrogen gas and \(4.00 \mathrm{~g}\) of helium gas occupy the same volume at any temperature and pressure.

Short Answer

Expert verified
Both 28.0 g of nitrogen gas and 4.00 g of helium gas represent 1 mole of gas, and according to the ideal gas law, they will occupy the same volume at constant temperature and pressure.

Step by step solution

01

Identifying the Molar Masses

Determine the molar masses of nitrogen (N2) and helium (He). Nitrogen is diatomic, so its molecular mass is twice the atomic mass, which is approximately 14 g/mol for a single nitrogen atom. Hence, the molar mass of N2 is 28 g/mol. Helium has a molar mass of approximately 4 g/mol.
02

Calculating Moles of Each Gas

Use the molar mass to find the number of moles for each gas. For nitrogen, divide the given mass by its molar mass: 28.0 g N2 / 28 g/mol = 1 mol N2. Do the same for helium: 4.00 g He / 4 g/mol = 1 mol He. Thus, both samples contain 1 mole of gas.
03

Utilizing the Ideal Gas Law

Apply the ideal gas law, PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature. Since both gases have the same number of moles, and R and T are constants, they will occupy the same volume V when the pressure P is the same for both.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
Understanding how to calculate molar mass is crucial when dealing with chemical substances and gases. It represents the mass of one mole of a substance and is usually expressed in grams per mole (g/mol). For elements, the molar mass can be found directly on the periodic table as the atomic weight. For example, helium (He) has a molar mass of approximately 4 g/mol.

For compounds, such as nitrogen gas (N2), the molar mass is the sum of all the atomic masses of the atoms in the molecule. Since nitrogen is diatomic, we take the atomic mass of a single nitrogen atom (approximately 14 g/mol) and multiply it by two, yielding a molar mass of 28 g/mol for N2.

Calculating the molar mass allows you to convert between the mass of a substance and the number of moles, which is a key step in many chemical problems and essential for utilizing the ideal gas law.
Moles of Gas
The mole is a fundamental unit in chemistry used to quantify the amount of substance. When it comes to gases, the mole concept allows us to compare different volumes of gases under the same conditions of temperature and pressure. This is rooted in Avogadro's hypothesis, which states that equal volumes of gases at the same temperature and pressure contain the same number of molecules.

To find the moles of gas, you simply divide the mass of the gas by its molar mass. For example, with 28.0 g of N2, we divide by its molar mass (28 g/mol) to find that we have 1 mole of N2. Similarly, 4.00 g of He divided by its molar mass (4 g/mol) gives us 1 mole of He.

Understanding moles of gas is vital, as it serves as a bridge between the physical world (mass of a sample) and the chemical world (calculating reaction yields, for instance), and is a central element in the application of the ideal gas law.
PV=nRT Equation
The ideal gas law, represented by the equation PV=nRT, is a cornerstone of gas laws, linking pressure (P), volume (V), moles of gas (n), the ideal gas constant (R), and temperature (T). This equation allows us to predict how a gas will behave under different conditions.

For the gases in question, nitrogen and helium, their behavior under any given set of conditions can be determined using this equation. If we keep the temperature (T) and pressure (P) constant, and since the number of moles (n) of each gas is the same (as we calculated before), the volume (V) occupied by each gas will also be the same. This is because R is a constant value and does not change with the identity of the gas.

The ability to use the ideal gas law hinges on the assumption that the gas behaves ideally, which means the gas particles are considered to have no volume and do not exert attractive or repulsive forces on each other. While this is never completely true for real gases, the ideal gas law provides a good approximation under many conditions.

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