Chapter 11: Problem 12
What is the combined gas law? When is it useful?
Short Answer
Expert verified
The combined gas law (\frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2}) describes the relationship between the pressure, volume, and temperature of a fixed amount of gas. It is useful when calculating the change in a gas's state when two of these properties, pressure, volume, or temperature, vary while the amount of gas remains constant.
Step by step solution
01
Definition of the Combined Gas Law
The combined gas law combines the three gas laws: Boyle's Law, Charles's Law, and Gay-Lussac's Law. It shows the relationship among the pressure, volume, and temperature of a fixed amount of gas. The combined gas law is expressed as \(\frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2}\), where \(P_1\), \(V_1\) and \(T_1\) are the initial pressure, volume and temperature respectively, and \(P_2\), \(V_2\) and \(T_2\) are the final pressure, volume and temperature.
02
Applicability of the Combined Gas Law
The combined gas law is useful for solving problems where at least two states (pressure, volume, temperature) of a gas are changing. It allows you to find unknown values when the amount of gas remains constant but its temperature, volume, or pressure changes. It's commonly used in situations involving gas expansion, compression, and temperature fluctuation, provided the amount of gas does not change.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Boyle's Law
Boyle's Law is a fundamental principle in the realm of gas laws that provides a quantitative relationship between the pressure and volume of a gas. It states that, for a given amount of gas at constant temperature, the pressure of the gas is inversely proportional to its volume. This means that as the volume of the gas increases, its pressure decreases, and vice versa, provided the temperature remains constant. The mathematical representation of Boyle's Law is:
\[ P_1V_1 = P_2V_2 \]
This equation implies that if the volume of gas is halved, the pressure will double, assuming no change in temperature. Boyle's Law is particularly useful in processes where temperature is held steady, such as when a gas is compressed in a piston.
\[ P_1V_1 = P_2V_2 \]
This equation implies that if the volume of gas is halved, the pressure will double, assuming no change in temperature. Boyle's Law is particularly useful in processes where temperature is held steady, such as when a gas is compressed in a piston.
Charles's Law
Charles's Law describes the relationship between the volume and temperature of a gas at constant pressure. According to this law, the volume of a fixed amount of gas is directly proportional to its temperature (measured in Kelvin) if the pressure remains unchanged. In a practical sense, this means that if you heat a gas, its volume will expand if the pressure is not allowed to change. Conversely, cooling the gas will lead to a decrease in volume. The law is captured by the formula:
\[ \frac{V_1}{T_1} = \frac{V_2}{T_2} \]
where \(V_1\) and \(T_1\) are the initial volume and temperature, and \(V_2\) and \(T_2\) are the final volume and temperature. Charles's Law can be observed in everyday life, for example, when a balloon deflates slightly on a cold day due to a decrease in the temperature of the air inside it, leading to a reduction in volume.
\[ \frac{V_1}{T_1} = \frac{V_2}{T_2} \]
where \(V_1\) and \(T_1\) are the initial volume and temperature, and \(V_2\) and \(T_2\) are the final volume and temperature. Charles's Law can be observed in everyday life, for example, when a balloon deflates slightly on a cold day due to a decrease in the temperature of the air inside it, leading to a reduction in volume.
Gay-Lussac's Law
Gay-Lussac's Law explores the proportional relationship between the pressure and temperature of a fixed amount of gas, while the volume is kept constant. The law asserts that the pressure of a gas is directly proportional to its absolute temperature when the amount of gas and its volume are held steady. For students trying to understand this concept, it's useful to think of a pressure cooker where heat increases the temperature and consequently the pressure inside the cooker, without altering the amount of gas. The mathematical expression for Gay-Lussac's Law is as follows:
\[ \frac{P_1}{T_1} = \frac{P_2}{T_2} \]
This relationship is critical when calculating changes in pressure for a gas that is heated or cooled, such as in the case of automobile airbags, which deploy due to a rapid increase in temperature and pressure.
\[ \frac{P_1}{T_1} = \frac{P_2}{T_2} \]
This relationship is critical when calculating changes in pressure for a gas that is heated or cooled, such as in the case of automobile airbags, which deploy due to a rapid increase in temperature and pressure.
Gas Laws
The Gas Laws are a set of fundamental principles which describe the behavior of gases in terms of their pressure (\(P\)), volume (\(V\)), and temperature (\(T\)). These laws include Boyle's Law, Charles's Law, Gay-Lussac's Law, and the combined gas law, among others. They provide the framework for understanding how gases respond to changes in their physical conditions. These relationships are essential in disciplines such as chemistry, physics, engineering, and environmental science. When working with gases, it is crucial to remember that these laws typically apply to ideal gases; real gases may show different behavior under extreme conditions of temperature and pressure.
Thermodynamics
Thermodynamics is a branch of physics that deals with the relationships between heat, work, energy, and temperature. It plays an essential role in understanding the behavior of gases as described by the Gas Laws. The four laws of thermodynamics govern the principles of energy transfer and provide insight into the workings of energy systems in our universe. In the context of gas laws, thermodynamics help in explaining how energy in the form of heat affects gas properties and how gases perform work when they expand or are compressed. This field is vast and intersects with the study of gases, encompassing everything from everyday applications like refrigeration to advanced topics in chemical and mechanical engineering.