What kinds of intermolecular forces are present in a mixture of calcium bromide and water?

Short Answer

Expert verified
In a mixture of calcium bromide (CaBr2) and water (H2O), the intermolecular forces include ion-dipole interactions between the ions of CaBr2 and the polar water molecules, hydrogen bonding, and London dispersion forces in water.

Step by step solution

01

Identify the Types of Intermolecular Forces in Calcium Bromide

First, we should identify the types of intermolecular forces in the calcium bromide (CaBr2). Since CaBr2 is an ionic compound, it consists of calcium cations (Ca2+) and bromide anions (Br-). The primary intermolecular force between these ions is the ionic bond, which is a type of electrostatic interaction.
02

Identify the Types of Intermolecular Forces in Water

Next, we focus on water (H2O). Water is a polar molecule due to the difference in electronegativity between the oxygen and hydrogen atoms; this leads to a partial negative charge near the oxygen atom and partial positive charges near the hydrogen atoms. The intermolecular forces present in water include hydrogen bonding (which is a strong type of dipole-dipole attraction), as well as London dispersion forces.
03

Determine Intermolecular Forces in the Mixture

When calcium bromide is mixed with water, the ions from the CaBr2 are surrounded by water molecules. The positive calcium ions will be attracted to the partial negative charges on the oxygen atoms of the water molecules, and the bromide ions will be attracted to the partial positive charges on the hydrogen atoms of the water molecules. These attractions are known as ion-dipole interactions. Therefore, the mixture will exhibit ion-dipole intermolecular forces in addition to the hydrogen bonds and London dispersion forces already present in the water.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Bond
Ionic bonds are the glue that holds together metals and nonmetals in ionic compounds, like sodium chloride or calcium bromide. Think of them as a strong handshake between oppositely charged ions (like calcium cations and bromide anions in calcium bromide). This occurs because one atom (the metal) donates one or more electrons to another (the nonmetal), creating charged particles that stick together due to their opposite charges.

These bonds are among the strongest intermolecular forces and greatly influence the properties of an ionic compound, such as its high melting point and its ability to conduct electricity when melted or dissolved in water. In our textbook exercise, calcium bromide, an ionic compound, dissolves in water, breaking the ionic bonds as the individual ions interact with water molecules.
Hydrogen Bonding
Hydrogen bonding is like the secret handshake of the molecular world; it's a special type of interaction that occurs when a hydrogen atom covalently bonded to a very electronegative atom, like oxygen or nitrogen, gets cozy with a lone pair of electrons on another electronegative atom nearby. These bonds are integral to the unique properties of water, such as its high boiling point and its ability to dissolve many substances.

Hydrogen bonds are particularly noteworthy when it comes to water because they're the reason life can exist – they create water's liquid state under Earth's conditions. As explained in the textbook problem, these bonds form in water due to the polar nature of the water molecule, where the oxygen atom has a partial negative charge and the hydrogen atoms have a partial positive charge.
Ion-Dipole Interactions
Imagine ions and polar molecules like water in a dance, and ion-dipole interactions are the steps they follow to dance together. This dance happens when positively and negatively charged ions from a compound like calcium bromide meet the water's polar molecules, enticing each other into an intricate embrace. The positive end of the polar water molecules (hydrogen side) is attracted to the negative ions (bromide), and the negative end (oxygen side) is fond of the positive ions (calcium).

Ion-dipole interactions are vital when it comes to mixing ionic compounds in polar solvents, like in our exercise. They are largely responsible for the solubility of ionic substances in water and dictate a large part of the mixture's properties. Without these interactions, your table salt wouldn't dissolve in water, and the chemical reactions in your body wouldn't work as smoothly.
London Dispersion Forces
London dispersion forces are like the shy, quieter cousin of the intermolecular forces family. They occur in all molecules, whether polar or nonpolar, including noble gases. They're a bit like invisible threads that only become apparent when molecules come very close together, creating instantaneous and shifting dipoles that lead to attractions between molecules.

Even though they're the weakest of the bunch, they are essential for holding nonpolar molecules together, and they contribute to the properties of all substances to some degree. In the case of water, these forces act in addition to hydrogen bonding, and they become evident when nonpolar molecules like oxygen are present. They are always there, subtly shaping the physical properties of matter.

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