Calculate the molality of each solution. (a) \(0.25 \mathrm{~mol}\) solute; \(0.250 \mathrm{~kg}\) solvent (b) \(0.882 \mathrm{~mol}\) solute; \(0.225 \mathrm{~kg}\) solvent (c) \(0.012 \mathrm{~mol}\) solute; \(23.1 \mathrm{~g}\) solvent

Short Answer

Expert verified
(a) 1 m, (b) 3.92 m, (c) 0.519 m

Step by step solution

01

Understanding Molality

Molality (m) is a measure of the concentration of a solute in a solution. It is defined as the number of moles of solute per kilogram of solvent. Molality is calculated using the formula: molality = moles of solute / kilograms of solvent.
02

Calculating Molality for (a)

Using the formula above, divide the given moles of solute by the given kilograms of solvent for solution (a): molality (m) = 0.25 mol / 0.250 kg.
03

Calculating Molality for (b)

Similarly, calculate the molality for solution (b) by dividing the moles of solute by the kilograms of solvent: molality (m) = 0.882 mol / 0.225 kg.
04

Converting Grams to Kilograms for (c)

Before calculating the molality for (c), convert the mass of the solvent from grams to kilograms by dividing by 1000: mass in kilograms = 23.1 g / 1000.
05

Calculating Molality for (c)

Now, calculate the molality for solution (c) using the converted kilograms of solvent: molality (m) = 0.012 mol / (23.1 g / 1000 kg).
06

Performing the Calculations

Carry out the divisions to obtain the molalities for each solution. (a) 0.25 mol / 0.250 kg = 1 m, (b) 0.882 mol / 0.225 kg = 3.92 m, and (c) 0.012 mol / (23.1 g / 1000 kg) = 0.519 m.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molality
Molality is a vital concept in chemistry, particularly when discussing solution concentration. It is a measure that represents the amount of solute dissolved in a given mass of solvent. Unlike molarity, which depends on the volume of the solution, molality is based exclusively on the mass of the solvent, making it temperature-independent since mass doesn't change with temperature.

Understanding molality is crucial for processes where temperature varies, such as in chemical reactions that involve heating or cooling. When calculating molality, you use the formula: \[ \text{molality} (m) = \frac{\text{moles of solute}}{\text{kilograms of solvent}} \].

This unit of concentration is particularly helpful because it remains constant under different temperature and pressure conditions, making it a more precise measure for experiments requiring high accuracy.
Moles of Solute
The concept of 'moles of solute' refers to the quantity of solute in a chemical equation and is fundamental to chemistry education. A mole is a unit that measures the amount of substance. It is one of the seven base SI units and is defined as containing exactly 6.02214076 × 10²³ particles of the given substance (Avogadro's number).

These particles could be atoms, molecules, ions, or electrons, depending on the context. Knowing the moles of solute allows chemists to predict how substances in solution will react with one another, how much product will form, and to determine the concentration of the solution. Molecular weight and mass calculations often precede the determination of moles of solute in a given solution.
Kilograms of Solvent
In every solution, there's a solvent - the substance that dissolves the other substance(s) called the solute. In molality calculations, we specifically look at the mass of the solvent in kilograms. This is because molality is defined in terms of kilograms to avoid the complications that arise from volume measurements, which can change with temperature or pressure.

By using kilograms of solvent, we standardize the unit for solutions, making comparisons and calculations more straightforward and accurate. Always ensure you convert the solvent's mass to kilograms if given in any other unit, like grams or pounds. This is essential for achieving the correct molality. For example, to convert grams to kilograms, you divide the mass in grams by 1000.
Solution Concentration
Solution concentration is an overall term that encompasses various methods of quantifying the proportion of solute in a solution. It can be expressed in several ways, including molality, molarity, mole fraction, and percent composition, among others.

Each type of concentration measurement is useful for different applications. Molality is particularly useful for calculations involving temperature changes. In teaching chemistry, it’s important to highlight the relevance and application of each concentration type, ensuring students can choose the most suitable measure for a given scenario. Clear, practical examples can strengthen comprehension, such as how the concentration of an antifreeze solution in a car radiator might be best expressed using molality due to temperature fluctuations.
Chemistry Education
The field of chemistry education revolves around how students learn chemistry, how educators teach it, and the ways to improve the learning and teaching processes. It is essential to simplify complex subjects, such as solution concentration, and make them as accessible as possible for learners at all levels.

Teaching the concept of molality should involve not just equations and definitions but also demonstrations and laboratory exercises where students can measure and mix solutions themselves. By promoting active learning, students can better understand the practical implications of these concepts in real-world scenarios, enhancing their overall chemistry comprehension.

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