Chapter 14: Problem 24
How is \(\mathrm{pH}\) defined? A change of \(1.0 \mathrm{pH}\) unit corresponds to how much of a change in \(\left[\mathrm{H}_{3} \mathrm{O}^{+}\right]\)?
Short Answer
Expert verified
pH is the negative base 10 logarithm of the hydronium ion concentration. A pH change of 1 unit corresponds to a tenfold change in the concentration of hydronium ions.
Step by step solution
01
Define pH
pH is defined as the negative logarithm to base 10 of the hydrogen ion concentration. Mathematically, it can be expressed as: \(\text{pH} = -\log_{10}\left[\mathrm{H}_{3}O^{+}\right]\), where \(\left[\mathrm{H}_{3}O^{+}\right]\) represents the concentration of hydronium ions in moles per liter (M).
02
Understand pH scale
The pH scale is a measure of acidity or alkalinity of a solution. A lower pH value indicates a higher concentration of hydronium ions and thus a more acidic solution. Conversely, a higher pH value indicates a lower concentration of hydronium ions and thus a more basic or alkaline solution.
03
Calculate change in hydronium ion concentration
A change of 1.0 pH unit represents a tenfold change in the concentration of hydronium ions. For instance, if the pH changes from 4 to 3, the concentration of hydronium ions \(\left[\mathrm{H}_{3}O^{+}\right]\) increases by a factor of 10. Conversely, if the pH changes from 4 to 5, the concentration of hydronium ions decreases by a factor of 10.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemistry Education
Chemistry education is the foundation for students to understand various scientific concepts, including the fundamental idea of the pH scale. It involves studying the composition, structure, properties, and change of matter.
At the heart of chemistry education lies the need to comprehend the behavior of atoms and molecules, which ultimately govern the properties of substances. Understanding the pH scale is a significant chapter in chemistry education, as it has widespread practical applications ranging from biology to environmental science and industry.
To ensure students fully grasp this concept, it is crucial to emphasize the real-world implications of the pH scale. For instance, explaining how pH affects soil quality and plant growth can create a tangible connection to the topic. Additionally, experiments that demonstrate the pH of common household items, like vinegar and baking soda, can provide hands-on learning opportunities.
At the heart of chemistry education lies the need to comprehend the behavior of atoms and molecules, which ultimately govern the properties of substances. Understanding the pH scale is a significant chapter in chemistry education, as it has widespread practical applications ranging from biology to environmental science and industry.
To ensure students fully grasp this concept, it is crucial to emphasize the real-world implications of the pH scale. For instance, explaining how pH affects soil quality and plant growth can create a tangible connection to the topic. Additionally, experiments that demonstrate the pH of common household items, like vinegar and baking soda, can provide hands-on learning opportunities.
Acidity and Alkalinity
The concepts of acidity and alkalinity are central to many chemical processes and are measured using the pH scale. Acidity refers to the capacity of a substance to donate hydrogen ions (H+), while alkalinity is the ability to accept hydrogen ions.
Substances with a pH value below 7 are considered acidic, while substances with a pH value above 7 are alkaline or basic. A pH of 7, which is the pH of pure water at 25°C, represents a neutral solution, where the concentration of hydrogen ions equals that of hydroxide ions (OH-).
Understanding the pH levels of substances is crucial not only in laboratories but also in everyday life, as it affects phenomena such as cooking, cleaning, and even the proper functioning of our bodies. The human body, for example, maintains a slightly alkaline pH of about 7.4 for optimal health.
Substances with a pH value below 7 are considered acidic, while substances with a pH value above 7 are alkaline or basic. A pH of 7, which is the pH of pure water at 25°C, represents a neutral solution, where the concentration of hydrogen ions equals that of hydroxide ions (OH-).
Understanding the pH levels of substances is crucial not only in laboratories but also in everyday life, as it affects phenomena such as cooking, cleaning, and even the proper functioning of our bodies. The human body, for example, maintains a slightly alkaline pH of about 7.4 for optimal health.
Hydronium Ion Concentration
Hydronium ion concentration is a key factor in determining a solution's pH. The concentration of hydronium ions, denoted as \(\left[\mathrm{H}_{3}O^{+}\right]\), directly influences how acidic or basic a solution is.
In aqueous solutions, the higher the concentration of hydronium ions, the lower the pH and therefore the more acidic the solution. Conversely, a low concentration of hydronium ions correlates with a higher pH and a more alkaline solution. It's important to note that the hydronium ion is the form in which hydrogen ions exist in water, as they are too reactive to exist on their own.
Equipping students with the tools to calculate hydronium ion concentration, as instructed in the textbook solution, empowers them to not only measure the acidity of solutions but also to predict and control chemical reactions in various settings, which is essential in fields like pharmacology and environmental science.
In aqueous solutions, the higher the concentration of hydronium ions, the lower the pH and therefore the more acidic the solution. Conversely, a low concentration of hydronium ions correlates with a higher pH and a more alkaline solution. It's important to note that the hydronium ion is the form in which hydrogen ions exist in water, as they are too reactive to exist on their own.
Equipping students with the tools to calculate hydronium ion concentration, as instructed in the textbook solution, empowers them to not only measure the acidity of solutions but also to predict and control chemical reactions in various settings, which is essential in fields like pharmacology and environmental science.
Logarithmic Scale
The pH scale is an excellent example of a logarithmic scale, which is used to express a wide range of values in a compact format. A logarithmic scale is one in which each unit increase or decrease corresponds to a tenfold increase or decrease in the quantity being measured.
This is important when dealing with hydronium ion concentration because the range of possible concentrations is vast, spanning many orders of magnitude. By using a logarithmic scale, this range is compressed into a more manageable 0 to 14 pH scale, with each increment reflecting a tenfold difference in concentration.
An understanding of logarithms is thus essential to grasp the pH scale concept fully. This is why students learning about pH must also familiarize themselves with logarithms, which are used across sciences to describe phenomena such as earthquake intensity, sound loudness, and even population growth in biology.
This is important when dealing with hydronium ion concentration because the range of possible concentrations is vast, spanning many orders of magnitude. By using a logarithmic scale, this range is compressed into a more manageable 0 to 14 pH scale, with each increment reflecting a tenfold difference in concentration.
An understanding of logarithms is thus essential to grasp the pH scale concept fully. This is why students learning about pH must also familiarize themselves with logarithms, which are used across sciences to describe phenomena such as earthquake intensity, sound loudness, and even population growth in biology.