Calculate the mass percent composition of each element in each compound. (a) \(\mathrm{FeCl}_{3}\) (b) \(\mathrm{TiO}_{2}\) (c) \(\mathrm{H}_{3} \mathrm{PO}_{4}\) (d) \(\mathrm{HNO}_{3}\)

Short Answer

Expert verified
FeCl3: 34.43% Fe, 65.57% Cl; TiO2: 59.94% Ti, 40.06% O; H3PO4: 3.06% H, 31.61% P, 65.33% O; HNO3: 1.58% H, 22.23% N, 76.19% O.

Step by step solution

01

Calculate Molar Mass of FeCl3

Find the atomic mass of each element from the periodic table: Iron (Fe) has an atomic mass of about 55.85 g/mol, and Chlorine (Cl) has an atomic mass of about 35.45 g/mol. Since there are three Chlorine atoms, multiply the atomic mass of Chlorine by 3. The molar mass of FeCl3 is the sum: Molar mass of FeCl3 = (1 * 55.85) + (3 * 35.45) g/mol.
02

Determine Mass Percent of Each Element in FeCl3

Calculate the mass percent of Iron (Fe) by dividing the atomic mass of Iron by the molar mass of FeCl3, then multiply by 100%. Similarly, for Chlorine, divide the total atomic mass of Chlorine by the molar mass of FeCl3 and multiply by 100%.
03

Calculate Molar Mass of TiO2

Find the atomic mass of Titanium (Ti) and Oxygen (O) from the periodic table: Titanium (Ti) has an atomic mass of about 47.87 g/mol, and Oxygen (O) has an atomic mass of about 16.00 g/mol. Since there are two Oxygen atoms, multiply the atomic mass of Oxygen by 2. The molar mass of TiO2 is the sum: Molar mass of TiO2 = (1 * 47.87) + (2 * 16) g/mol.
04

Determine Mass Percent of Each Element in TiO2

Calculate the mass percent of Titanium (Ti) by dividing the atomic mass of Titanium by the molar mass of TiO2, then multiply by 100%. For Oxygen, divide the total atomic mass of Oxygen by the molar mass of TiO2 and multiply by 100%.
05

Calculate Molar Mass of H3PO4

Find the atomic mass of Hydrogen (H), Phosphorus (P), and Oxygen (O): Hydrogen (H) has an atomic mass of about 1.01 g/mol, Phosphorus (P) has an atomic mass of about 30.97 g/mol, and Oxygen (O) has 16.00 g/mol. The molar mass of H3PO4 is the sum: Molar mass of H3PO4 = (3 * 1.01) + (1 * 30.97) + (4 * 16) g/mol.
06

Determine Mass Percent of Each Element in H3PO4

Calculate the mass percent of Hydrogen (H) by dividing the total atomic mass of Hydrogen by the molar mass of H3PO4, then multiply by 100%. Do the same for Phosphorus (P) and Oxygen (O), dividing their atomic masses by the molar mass of H3PO4 and multiplying by 100%.
07

Calculate Molar Mass of HNO3

Find the atomic mass of Hydrogen (H), Nitrogen (N), and Oxygen (O): Hydrogen (H) has an atomic mass of about 1.01 g/mol, Nitrogen (N) has an atomic mass of about 14.01 g/mol, and Oxygen (O) has 16.00 g/mol. The molar mass of HNO3 is the sum: Molar mass of HNO3 = (1 * 1.01) + (1 * 14.01) + (3 * 16) g/mol.
08

Determine Mass Percent of Each Element in HNO3

Calculate the mass percent of Hydrogen (H) by dividing the atomic mass of Hydrogen by the molar mass of HNO3, then multiply by 100%. Do the same for Nitrogen (N) and Oxygen (O), dividing their atomic masses by the molar mass of HNO3 and multiplying by 100%.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
Understanding the molar mass of a compound is crucial for a plethora of chemical calculations, from reacting quantities to concentration and beyond. To calculate the molar mass, one must first look up the atomic masses of each element in the compound from the periodic table. The atomic mass is the weight of a single mole of an element and is measured in grams per mole (g/mol).

Then, these values are combined according to the compound's chemical formula. For example, for water (H2O), you would take the atomic mass of Hydrogen (approximately 1.01 g/mol), multiply it by two for the two Hydrogen atoms, and then add the atomic mass of Oxygen (approximately 16.00 g/mol).

One common mistake is to overlook that the subscript in the chemical formula indicates the number of atoms in that compound. Always multiply the atomic mass of each element by the number of atoms of that element present in the compound before summing them up.
Percent Composition by Mass
Percent composition by mass shows the proportion each element contributes to the total mass of the compound. It is a fundamental concept for those studying stoichiometry and other areas of chemistry. After calculating the molar mass of the compound, determine the mass percent for each individual element by dividing the total atomic mass of that element (as represented in one mole of the compound) by the molar mass of the compound, then multiply the result by 100%.

For instance, in methane (CH4), Carbon's mass percent is calculated by dividing the atomic mass of a single Carbon atom by the molar mass of methane and multiplying by 100%. The same process is then repeated for Hydrogen. These calculations are fundamental in finding out the empirical and molecular formulas of unknown compounds based on their mass percent composition.
Chemical Compound Analysis
Chemical compound analysis involves determining the composition and proportions of a chemical compound. Methods range from simple, like the percent composition calculations discussed earlier, to advanced instrumental techniques like mass spectrometry and nuclear magnetic resonance (NMR).

In academic settings, learning to calculate the mass percent composition of each element lays the groundwork for more complex analyses. This essential skill aids in predicting the physical properties and chemical behavior of substances. Moreover, an accurate analysis affects the outcome of chemical reactions, product purity in pharmaceuticals, and the suitability of materials for specific applications in industry.

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