Problem 98

Predict the type of reaction (if any) that occurs between each pair of substances. Write balanced molecular equations for each. If no reaction occurs, write NO REACTION. (a) aqueous hydrochloric acid and aqueous copper(II) nitrate (b) liquid pentanol \(\left(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O}\right)\) and gaseous oxygen (c) aqueous ammonium chloride and aqueous calcium hydroxide (d) aqueous strontium sulfide and aqueous copper(II) sulfate

Problem 100

Classify each reaction in as many ways as possible. (a) \(\mathrm{NaCl}(a q)+\mathrm{AgNO}_{3}(a q) \longrightarrow\) \(\mathrm{AgCl}(s)+\mathrm{NaNO}_{3}(a q)\) (b) \(2 \mathrm{Rb}(s)+\mathrm{Br}_{2}(g) \longrightarrow 2 \mathrm{RbBr}(s)\) (c) \(\mathrm{Zn}(s)+\mathrm{NiBr}_{2}(a q) \longrightarrow \mathrm{Ni}(s)+\mathrm{ZnBr}_{2}(a q)\) (d) \(\mathrm{Ca}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(a q)+\mathrm{H}_{2}(g)\)

Problem 103

What solution can you add to each cation mixture to precipitate one cation while keeping the other cation in solution? Write a net ionic equation for the precipitation reaction that occurs. (a) \(\mathrm{Fe}^{2+}(a q)\) and \(\mathrm{Pb}^{2+}(a q)\) (b) \(\mathrm{K}^{+}(a q)\) and \(\mathrm{Ca}^{2+}(a q)\) (c) \(\mathrm{Ag}^{+}(a q)\) and \(\mathrm{Ba}^{2+}(a q)\) (d) \(\mathrm{Cu}^{2+}(a q)\) and \(\mathrm{Hg}_{2}{ }^{2+}(a q)\)

Problem 104

What solution can you add to each cation mixture to precipitate one cation while keeping the other cation in solution? Write a net ionic equation for the precipitation reaction that occurs. (a) \(\mathrm{Sr}^{2+}(a q)\) and \(\mathrm{Hg}_{2}{ }^{2+}(a q)\) (b) \(\mathrm{NH}_{4}^{+}(a q)\) and \(\mathrm{Ca}^{2+}(a q)\) (c) \(\mathrm{Ba}^{2+}(a q)\) and \(\mathrm{Mg}^{2+}(a q)\) (d) \(\mathrm{Ag}^{+}(a q)\) and \(\mathrm{Zn}^{2+}(a q)\)

Problem 105

A solution contains an unknown amount of dissolved calcium. Addition of \(0.112 \mathrm{~mol}\) of \(\mathrm{K}_{3} \mathrm{PO}_{4}\) causes complete precipitation of all of the calcium. How many moles of calcium were dissolved in the solution? What mass of calcium was dissolved in the solution?

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