Chapter 7: Problem 10
Explain what happens to an ionic substance when it dissolves in water.
Short Answer
Expert verified
An ionic substance dissolves in water as it interacts with water molecules, which separate and solvate the ions, eventually leading to an even distribution of ions in the solution.
Step by step solution
01
Understanding Dissolution
When an ionic substance dissolves in water, the polar water molecules interact with the positive and negative ions of the substance.
02
Ion-Water Interactions
The partially positive hydrogen atoms of water molecules are attracted to the negative ions (anions), and the partially negative oxygen atoms of water molecules are attracted to the positive ions (cations).
03
Separation of Ions
This interaction between water molecules and ions causes the ions to become solvated (surrounded by a layer of water molecules) and separates them from the ionic solid, resulting in the ions dispersing throughout the solution.
04
Formation of an Aqueous Solution
As more ions are solvated, the ionic compound becomes fully dissolved, forming an aqueous solution where the ions are evenly distributed throughout the water.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with Vaia!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Dissolution Process
When you drop an ionic compound into water, you're witnessing the dissolution process—a fascinating dance at the molecular level. Think of it as a 'molecular meet-and-greet': the ionic substance, made up of oppositely charged ions, ventures into a space dominated by water molecules. These water molecules aren't just any crowd; they're polar, meaning each one has a positive side and a negative side.
Imagine the negative chloride ion (Cl-) in table salt (NaCl) getting surrounded by the positive 'faces' of water molecules. Simultaneously, the positive sodium ion (Na+) is embraced by the water’s negative ends. It's like every ion finds its perfect match in polarity. This entire interaction is what prises the ions away from their solid network, distributing them throughout the water, resulting in what we observe as the substance dissolving.
Imagine the negative chloride ion (Cl-) in table salt (NaCl) getting surrounded by the positive 'faces' of water molecules. Simultaneously, the positive sodium ion (Na+) is embraced by the water’s negative ends. It's like every ion finds its perfect match in polarity. This entire interaction is what prises the ions away from their solid network, distributing them throughout the water, resulting in what we observe as the substance dissolving.
Ion-Water Interactions
The magic of ion-water interactions lies within the water's polar nature. On the molecular level, water behaves like a tiny magnet. The oxygen atom holds a slight negative charge, while the hydrogen atoms possess slight positive charges. When ionic substances encounter water, these micro-magnets spring into action.
Here's what happens: water molecules align themselves according to their charge affinity, with hydrogen atoms pointing towards negative ions (anions), and the oxygen atom facing towards positive ions (cations). This specialized arrangement is not random—it's a key part of the solvation process. These one-on-one interactions are crucial for the next step: breaking the bonds that hold the ionic substance together.
Here's what happens: water molecules align themselves according to their charge affinity, with hydrogen atoms pointing towards negative ions (anions), and the oxygen atom facing towards positive ions (cations). This specialized arrangement is not random—it's a key part of the solvation process. These one-on-one interactions are crucial for the next step: breaking the bonds that hold the ionic substance together.
Solvation
The solvation process, sometimes called hydration when it involves water, can be thought of as the 'welcome party' for ions into the liquid phase. After the initial meet-up between ions and water molecules, solvation involves wrapping the incoming ions in cozy blankets of water molecules—a process termed as forming a hydration shell or sphere.
During solvation, the ionic compound gets a full molecular embrace. Each ion, now surrounded by oppositely charged ends of water molecules, finds a new home in the liquid. This rearrangement diminishes the ionic bonds and disperses the previously solid ionic compound throughout the solution. The result? The ions are now solvated—they essentially wear a shield of water molecules that allows them to drift freely within the solution.
During solvation, the ionic compound gets a full molecular embrace. Each ion, now surrounded by oppositely charged ends of water molecules, finds a new home in the liquid. This rearrangement diminishes the ionic bonds and disperses the previously solid ionic compound throughout the solution. The result? The ions are now solvated—they essentially wear a shield of water molecules that allows them to drift freely within the solution.
Aqueous Solutions
When all said and done—when each ion has been tenderly encased in its watery shell—we are left with what is called an aqueous solution. The term 'aqueous' comes from 'aqua,' meaning water in Latin. In an aqueous solution, ions are dispersed homogeneously throughout the water, creating a uniform mixture where no visible trace of the original solid can be found.
These solutions are not just a feature of a laboratory—they're part of our daily lives. From the salt dissolved in ocean water to minerals in our drinking water, understanding aqueous solutions is key to grasping how substances behave and interact in various environments, including biological systems. So every time you dissolve salt in water to cook pasta or rice, remember, you're creating an aqueous solution and witnessing a remarkable natural phenomenon.
These solutions are not just a feature of a laboratory—they're part of our daily lives. From the salt dissolved in ocean water to minerals in our drinking water, understanding aqueous solutions is key to grasping how substances behave and interact in various environments, including biological systems. So every time you dissolve salt in water to cook pasta or rice, remember, you're creating an aqueous solution and witnessing a remarkable natural phenomenon.