Chapter 9: Problem 101
Based on periodic trends, which one of these elements would you expect to be most easily oxidized: Ge, K, S, or N?
Short Answer
Expert verified
Potassium (K) would be expected to be most easily oxidized based on its position in the periodic table.
Step by step solution
01
- Understand the concept of oxidation
Oxidation is the loss of electrons by an atom or ion. Elements that lose electrons more easily are said to be more easily oxidized. Generally, elements with low ionization energy and a larger atomic radius are oxidized more easily because it's less energetically costly for them to lose an outer electron.
02
- Apply periodic trends
Knowing that ionization energy decreases as we move down a group and increases as we move across a period from left to right, we look for an element with low ionization energy. Among the provided elements, potassium (K) is farthest to the left and lowest in the periodic table, which means it should have the lowest ionization energy.
03
- Compare the positions in the periodic table
Ge (germanium) is a metalloid which tends to have intermediate ionization energy. K (potassium) is an alkali metal with very low ionization energy, making it very reactive. S (sulfur) is a non-metal with higher ionization energy than metals. N (nitrogen) has a very high ionization energy due to its small size and high electronegativity. Among these, K is lowest on the periodic table and farthest to the left, indicating it should be most easily oxidized.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionization Energy
Ionization energy refers to the amount of energy required to remove an electron from an isolated atom or ion in its gaseous state. It's a critical indicator of an element's reactivity, particularly when discussing oxidation, as elements with lower ionization energies tend to lose electrons more readily and undergo oxidation.
Ionization energy generally increases from left to right across a period in the periodic table due to the increasing nuclear charge. This increase in nuclear charge means that electrons are held more tightly to the nucleus, thus requiring more energy to be ionized. Down a group, ionization energy decreases because the outer electrons are further from the nucleus and thus more easily removed. In summary, the lower the ionization energy, the easier it is for an element to be oxidized.
Ionization energy generally increases from left to right across a period in the periodic table due to the increasing nuclear charge. This increase in nuclear charge means that electrons are held more tightly to the nucleus, thus requiring more energy to be ionized. Down a group, ionization energy decreases because the outer electrons are further from the nucleus and thus more easily removed. In summary, the lower the ionization energy, the easier it is for an element to be oxidized.
Atomic Radius
The atomic radius of an element is the average distance from its nucleus to the outermost electrons orbiting it. When considering oxidation, a larger atomic radius often signifies an increased ease of losing electrons, since these valence electrons are further from the attractive force of the nucleus.
Within the periodic table, the atomic radius increases down a group as additional electron shells are added, making atoms larger. Conversely, atomic radius decreases across a period, as electrons are added to the same energy level while the nuclear charge increases, pulling electrons closer to the nucleus. This concept helps us understand why some elements are more easily oxidized than others; those with larger atomic radii tend to give up their outer electrons with less resistance.
Within the periodic table, the atomic radius increases down a group as additional electron shells are added, making atoms larger. Conversely, atomic radius decreases across a period, as electrons are added to the same energy level while the nuclear charge increases, pulling electrons closer to the nucleus. This concept helps us understand why some elements are more easily oxidized than others; those with larger atomic radii tend to give up their outer electrons with less resistance.
Periodic Table Trends
The periodic table is organized in a way that showcases the periodic trends, or recurring variations in element properties with increasing atomic number. Two trends, in particular, ionization energy and atomic radius, play key roles in determining an element's propensity to undergo oxidation.
Elements that are lower and to the left on the periodic table are generally more easily oxidized, a trend consistent with their lower ionization energy and larger atomic radius. Beyond these, other trends, such as electronegativity and electron affinity, also impact reactivity and oxidation tendencies. Understanding these trends is crucial for making predictions about the behavior of elements in chemical reactions.
Elements that are lower and to the left on the periodic table are generally more easily oxidized, a trend consistent with their lower ionization energy and larger atomic radius. Beyond these, other trends, such as electronegativity and electron affinity, also impact reactivity and oxidation tendencies. Understanding these trends is crucial for making predictions about the behavior of elements in chemical reactions.
Alkali Metals
Alkali metals, located in Group 1 of the periodic table, are known for their high reactivity, especially with regard to oxidation. This group includes elements such as lithium, sodium, and potassium, which are characterized by their single electron in their outermost shell.
Due to their low ionization energy and large atomic radius compared to other elements, alkali metals readily lose their single valence electron to form a +1 ion. This makes them extremely reactive and easily oxidized. For example, potassium (K) easily loses its one outer electron, explaining why it's more likely to be oxidized than the other elements listed in the exercise. Alkali metals' distinctive properties make them a textbook example of periodic trends in action.
Due to their low ionization energy and large atomic radius compared to other elements, alkali metals readily lose their single valence electron to form a +1 ion. This makes them extremely reactive and easily oxidized. For example, potassium (K) easily loses its one outer electron, explaining why it's more likely to be oxidized than the other elements listed in the exercise. Alkali metals' distinctive properties make them a textbook example of periodic trends in action.