Chapter 10: Problem 13
Indicate whether each reaction is a redox reaction. If it is, which atom gets oxidized and which atom gets reduced? Consult the shortcut rules. \(\mathrm{Ca}+2 \mathrm{H}^{+} \rightarrow \mathrm{Ca}^{2+}+\mathrm{H}_{2}\)
Chapter 10: Problem 13
Indicate whether each reaction is a redox reaction. If it is, which atom gets oxidized and which atom gets reduced? Consult the shortcut rules. \(\mathrm{Ca}+2 \mathrm{H}^{+} \rightarrow \mathrm{Ca}^{2+}+\mathrm{H}_{2}\)
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Get started for free(a) Use the following results to arrange the four metals, \(\mathrm{W}, \mathrm{X}, \mathrm{Y}, \mathrm{Z}\) in the vertical column on the right from the most active (at the top) to least active (on the bottom). \(\mathrm{W}+\mathrm{X}^{+} \rightarrow \mathrm{W}^{+}+\mathrm{X}\) most active \(\mathrm{X}+\mathrm{Z}^{+} \rightarrow \mathrm{X}^{+}+\mathrm{Z}\) \(\mathrm{Y}^{+}+\mathrm{Z} \rightarrow\) no reaction \(\mathrm{X}+\mathrm{Y}^{+} \rightarrow \mathrm{X}^{+}+\mathrm{Y}\) least active (b) Based on your series in part a, circle ALL the reactions below that you would expect to occur spontaneously as written. Explain. \(\mathrm{W}^{+}+\mathrm{Y} \rightarrow \mathrm{W}+\mathrm{Y}^{+} \quad \mathrm{W}^{+}+\mathrm{Z} \rightarrow \mathrm{W}+\mathrm{Z}^{+}\)
In a nickel-cadmium battery, the relevant redox reaction is: \(2 \mathrm{NiO}(\mathrm{OH})+\mathrm{Cd}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow\) \(2 \mathrm{Ni}(\mathrm{OH})_{2}+\mathrm{Cd}(\mathrm{OH})_{2}\) Does this agree with the EMF series? What are the oxidation states of nickel before and after the reaction?
Which of the following are electron-transfer reactions? For those that are, indicate which reactant is the reducing agent and which reactant is the oxidizing agent. (a) \(\mathrm{PF}_{3}+3 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{H}_{3} \mathrm{PO}_{3}+3 \mathrm{HF}\) (b) \(\mathrm{H}_{2}+\mathrm{Cl}_{2} \rightarrow 2 \mathrm{HCl}\) (c) \(2 \mathrm{Cr}_{2} \mathrm{O}_{3}+3 \mathrm{Si} \rightarrow 4 \mathrm{Cr}+3 \mathrm{SiO}_{2}\) (d) \(\mathrm{HCl}+\mathrm{NaOH} \rightarrow \mathrm{NaCl}+\mathrm{H}_{2} \mathrm{O}\)
What is the range of oxidation states possible for carbon? (Hint: Consider that carbon bonds first to atoms that are all higher in electronegativity and then to atoms all lower in electronegativity.)
Under what circumstances does fluorine not have an oxidation state of \(-1 ?\)
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