How many atoms of nitrogen are there in a \(230.0-\mathrm{mL}\) sample of \(\mathrm{N}_{2} \mathrm{O}_{4}\) gas that has a pressure of \(745.0 \mathrm{~mm} \mathrm{Hg}\) at \(34.0^{\circ} \mathrm{C}\) ?

Short Answer

Expert verified
In a 230.0 mL sample of N₂O₄ gas with a pressure of 745.0 mmHg at 34.0°C, there are approximately \(1.105 \times 10^{23}\) atoms of nitrogen.

Step by step solution

01

Convert pressure from mmHg to atm

First, we need to convert the given pressure from mmHg to atm using the following conversion factor: 1 atm = 760 mmHg. Given pressure = 745.0 mmHg To convert to atm: Pressure (atm) = (745.0 mmHg) / (760 mmHg/atm) Pressure (atm) = 0.98026 atm
02

Convert temperature from Celsius to Kelvin

Next, let's convert the given temperature from Celsius to Kelvin using the formula: Temperature (K) = Temperature (°C) + 273.15 Temperature (K) = 34.0° C + 273.15 Temperature (K) = 307.15 K
03

Use Ideal Gas Law to determine moles of N₂O₄

Now, we will use the Ideal Gas Law equation (PV = nRT) to find the number of moles (n) of N₂O₄: P = 0.98026 atm (pressure) V = 230.0 mL (volume) = 0.230 L (convert to liters) R = 0.0821 L atm / (mol K) (the ideal gas constant) T = 307.15 K (temperature) n = PV / (RT) n = (0.98026 atm * 0.230 L) / (0.0821 L atm/mol K * 307.15 K) n = 0.00918 mol
04

Calculate the number of nitrogen atoms

Now that we have the number of moles of N₂O₄, we can find the number of nitrogen atoms (each molecule of N₂O₄ contains 2 nitrogen atoms) using Avogadro's number, 6.022 x 10²³ atoms/mol. Total moles of nitrogen atoms = 0.00918 mol of N₂O₄ * 2 = 0.01836 mol of nitrogen atoms Number of nitrogen atoms = 0.01836 mol of nitrogen atoms * 6.022 x 10²³ atoms/mol Number of nitrogen atoms = 1.105 x 10²³ atoms In conclusion, there are approximately 1.105 x 10²³ atoms of nitrogen in the 230.0 mL sample of N₂O₄ gas.

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