Chapter 13: Problem 121
Explain why this statement is false: A reaction in which weak bonds are broken and strong bonds are formed is an endothermic reaction.
Chapter 13: Problem 121
Explain why this statement is false: A reaction in which weak bonds are broken and strong bonds are formed is an endothermic reaction.
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Get started for freeThe rate of a reaction depends both on inherent factors and on concentration. The rate constant \(k\) is associated with the inherent factors. What are they?
Indicate whether each statement is true or false. Rewrite each false statement to make it true. (a) The exponents in the rate law for a reaction that has a one-step mechanism can be determined from the balanced equation for the reaction. (b) A rate law can be used to prove that a proposed mechanism is correct. (c) The step \(\mathrm{A}+\mathrm{X}+\mathrm{Y} \rightarrow \mathrm{AX}+\mathrm{Y}\) in a reaction mechanism is plausible. (d) A reaction intermediate appears first as a reactant and then as a product in a reaction mechanism.
In a kinetic study of the reaction \(2 \mathrm{ClO}_{2}(a q)+2 \mathrm{OH}^{-}(a q) \rightarrow\) \(\mathrm{ClO}_{3}^{-}(a q)+\mathrm{ClO}_{2}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l)\) the following rate data were obtained. Write a rate law complete with proper values for the orders. What is the overall order of the reaction? $$\begin{array}{cccc} \text { Experiment } & {\left[\mathrm{ClO}_{2}\right]} & {\left[\mathrm{OH}^{-}\right]} & \text {Rate }(\mathbf{M} / \mathrm{s}) \\ \hline 1 & 0.060 \mathrm{M} & 0.030 \mathrm{M} & 0.02484 \\ 2 & 0.020 \mathrm{M} & 0.030 \mathrm{M} & 0.00276 \\ 3 & 0.020 \mathrm{M} & 0.090 \mathrm{M} & 0.00828 \end{array}$$
\(\Delta\) (Any quantity) is always defined as (final value of quantity) - (initial value of quantity). Now consider the quantity \(\Delta E_{\mathrm{rxn}}\). (a) For the forward reaction \(\mathrm{R} \rightarrow \mathrm{P}\), is \(\Delta E_{\mathrm{rxn}}=E_{\text {Reactants }}-E_{\text {Products }} ?\) Explain your answer. (b) According to your answer to (a), what does it mean when \(\Delta E_{\mathrm{rxn}}\) for a reaction is negative?
Consider the transition state for a chemical reaction. (a) What is it (define it). (b) Can there be only imminent bond breaking in a transition state? Explain.
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