Chapter 13: Problem 34
What is one benefit of understanding a reaction's mechanism?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 13: Problem 34
What is one benefit of understanding a reaction's mechanism?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeTrue or false? (a) The orders \(x\) and \(y\) in a rate law are written directly from the balancing coefficients from the balanced equation for a reaction. (b) The overall order of a reaction is the sum of the individual orders of the reactants. (c) If you start a reaction with just reactants (no product present), then the rate of the reaction will remain constant with time. (d) If you start a reaction with just reactants (no product present), then the rate of the reaction will decrease with time.
For a particular reaction, the reactants are at \(30 \mathrm{~kJ}\), the products are at \(60 \mathrm{~kJ}\), and the transition state is at \(100 \mathrm{~kJ} .\) Sketch a reactionenergy profile showing both \(\Delta E_{\mathrm{rxn}}\) and \(E_{\mathrm{a}}\). Also, calculate the value of \(\Delta E_{\mathrm{rxn}}\) and \(E_{\mathrm{a}}\), and state whether this reaction is endothermic or exothermic.
Reactions go faster when heated. Astudent claims this is because as temperature increases, the activation energy \(E_{\mathrm{a}}\) for a reaction decreases. Is this student correct or incorrect? If incorrect, then explain what happens to \(E_{\mathrm{a}}\) upon heating a reaction.
Does the rate constant \(k\) increase, decrease, or stay the same when: (a) You increase the temperature (explain your choice fully). (b) You add a catalyst (explain your choice fully).
What is meant by the term rate-determining step?
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