Chapter 13: Problem 69
What is the general name given to biological catalysts?
Short Answer
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 13: Problem 69
What is the general name given to biological catalysts?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeIndicate whether each statement is true or false. Rewrite each false statement to make it true. (a) The exponents in the rate law for a reaction that has a one-step mechanism can be determined from the balanced equation for the reaction. (b) A rate law can be used to prove that a proposed mechanism is correct. (c) The step \(\mathrm{A}+\mathrm{X}+\mathrm{Y} \rightarrow \mathrm{AX}+\mathrm{Y}\) in a reaction mechanism is plausible. (d) A reaction intermediate appears first as a reactant and then as a product in a reaction mechanism.
Consider the basic hydrolysis (reaction with aqueous base) of \(\left(\mathrm{CH}_{3}\right){ }_{3} \mathrm{CBr}\). \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CBr}(a q)+\mathrm{OH}^{-}(a q) \rightarrow\) $$\left(\mathrm{CH}_{3}\right){ }_{3} \mathrm{COH}(a q)+\mathrm{Br}^{-}(a q)$$ The rate law is first order with respect to \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CBr}\) and zero order with respect to \(\mathrm{OH}^{-}\). What does this imply about the mechanism of this reaction?
For a particular reaction, the reactants are at \(30 \mathrm{~kJ}\), the products are at \(60 \mathrm{~kJ}\), and the transition state is at \(100 \mathrm{~kJ} .\) Sketch a reactionenergy profile showing both \(\Delta E_{\mathrm{rxn}}\) and \(E_{\mathrm{a}}\). Also, calculate the value of \(\Delta E_{\mathrm{rxn}}\) and \(E_{\mathrm{a}}\), and state whether this reaction is endothermic or exothermic.
In the substitution reaction of \(\mathrm{Cl}^{-}\) for \(\mathrm{OH}^{-}\) in 2-propanol, explain how \(\mathrm{Zn}^{2+}\) acts as a catalyst to increase the reaction rate.
Which of the following will slow down a chemical reaction? (a) Increase concentration of reactants. (b) Add catalyst. (c) Decrease temperature. (d) All of the above.
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