Chapter 14: Problem 126
Some liquid water is placed in a room-temperature container and sealed. After some time, the level of the liquid drops by a small amount. After that, the water level remains constant.
Chapter 14: Problem 126
Some liquid water is placed in a room-temperature container and sealed. After some time, the level of the liquid drops by a small amount. After that, the water level remains constant.
All the tools & learning materials you need for study success - in one app.
Get started for freeConsider the reaction \(\mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g) \rightleftarrows \mathrm{PCl}_{5}(g)\) Use forward and reverse rate meters to represent the forward and reverse reaction rates for: (a) The initial equilibrium (b) Moments after you disturb the equilibrium by adding \(\mathrm{PCl}_{5}\) (c) The restored equilibrium (d) Which way did the reaction shift to get from the initial equilibrium, part (a), to the restored equilibrium, part (c)?
At \(25^{\circ} \mathrm{C}\), the solubility of calcium oxalate, \(\mathrm{CaC}_{2} \mathrm{O}_{4}\), in water is \(6.1 \mathrm{mg} / \mathrm{L}\). (a) What are the equilibrium molar concentrations of \(\mathrm{Ca}^{2+}(a q)\) and \(\mathrm{C}_{2} \mathrm{O}_{4}^{2-}(a q) ?\) (b) Calculate \(K_{\mathrm{sp}}\) for calcium oxalate.
What symbol and name are used to replace the ratio \(k_{\mathrm{f}} / k_{\mathrm{r}}\) for a reaction?
Write the equilibrium constant expression for (a) \(2 \mathrm{FeCl}_{3}(s)+3 \mathrm{H}_{2} \mathrm{O}(g) \rightleftarrows \mathrm{Fe}_{2} \mathrm{O}_{3}(s)\) \(+6 \mathrm{HCl}(g)\) (b) \(\mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{CO}(g) \rightleftarrows 2 \mathrm{Fe}(l)+3 \mathrm{CO}_{2}(g)\) (c) \(\mathrm{PbSO}_{4}(s) \rightleftarrows \mathrm{Pb}^{2+}(a q)+\mathrm{SO}_{4}^{2-}(a q)\) (d) \(\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftarrows \mathrm{H}_{2} \mathrm{CO}_{3}(a q)\)
Indicate with an arrow the direction of the equilibrium shift and predict what will happen to the amount of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) (increases, decreases, unchanged, need more information) when the following stresses are applied to the following exothermic reaction: \(2 \mathrm{Fe}(s)+3 \mathrm{H}_{2} \mathrm{O}(g) \rightleftarrows \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+3 \mathrm{H}_{2}(g)\) The reaction is cooled. \(\mathrm{H}_{2}\) gas is added. \(\mathrm{H}_{2} \mathrm{O}\) is removed. Volume is reduced. A catalyst is added. Fe is added while the reaction temperature is increased.
What do you think about this solution?
We value your feedback to improve our textbook solutions.