Chapter 14: Problem 26
What does the "equi" portion of the word equilibrium refer to?
Chapter 14: Problem 26
What does the "equi" portion of the word equilibrium refer to?
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Get started for freePhosphorus pentachloride gas decomposes to \(\mathrm{PCl}_{3}(\mathrm{~g})\) and \(\mathrm{Cl}_{2}(\mathrm{~g}) .\) At equilibrium, the concentrations of the decomposition products are \(5.50 \times 10^{-3} \mathrm{M}\) for \(\mathrm{PCl}_{3}(\mathrm{~g})\) and \(0.125 \mathrm{M}\) for \(\mathrm{Cl}_{2}(g)\). What is the equilibrium concentration of \(\mathrm{PCl}_{5}\) ? The equilibrium constant for this reaction is \(7.50 \times 10^{-2}\).
Suppose a reaction has a \(K_{\text {eq }}\) value of \(2.05\). When we write the reaction, can we use a single arrow to the right instead of a double set of equilibrium arrows? Explain your answer.
Sparingly soluble aluminum hydroxide dissolves in water to yield an equilibrium hydroxide ion concentration of \(8.58 \times 10^{-9} \mathrm{M}\). (a) Write the balanced equilibrium equation for aluminum hydroxide dissolving in water. (b) Write the \(K_{\mathrm{sp}}\) expression for aluminum hydroxide. (c) What is the equilibrium concentration of aluminum ion? (d) Calculate the value of \(K_{\mathrm{sp}}\) for aluminum hydroxide (show your calculation).
On the basis of \(K_{\text {eq }}\) values, which reaction goes essentially to completion? How would you describe the other reaction? (a) \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \leftrightarrows 2 \mathrm{H}_{2} \mathrm{O}(g)\); \(K_{\mathrm{eq}}=3 \times 10^{81}\) (b) \(2 \mathrm{HF}(g) \rightleftarrows \mathrm{H}_{2}(g)+\mathrm{F}_{2}(g)\) \(K_{\mathrm{eq}}=1 \times 10^{-95}\)
What symbol and name are used to replace the ratio \(k_{\mathrm{f}} / k_{\mathrm{r}}\) for a reaction?
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