Chapter 14: Problem 88
What is a heterogeneous chemical reaction? Where does a heterogeneous reaction occur?
Chapter 14: Problem 88
What is a heterogeneous chemical reaction? Where does a heterogeneous reaction occur?
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Get started for freeCooling an exothermic reaction for which \(K_{\text {eq }}\) is very low shifts the reaction to the right, so that more product is formed, but there is a trade-off. What is the downside of cooling such a reaction, as far as forming product is concerned?
Suppose you have a reaction with many reactants. When you write the equilibrium expression for the reaction, do the reactant concentrations all go in the numerator or in the denominator? What mathematical operation(s) should be used for these concentrations?
Diamond and graphite are two forms of elemental carbon. Under the appropriate conditions they will be in equilibrium with each other: \(C_{\text {diamond }} \rightleftarrows C_{\text {graphite }}\) If graphite is subjected to very high pressure and temperature, it will convert into the diamond form. (a) Is the above equilibrium reaction exothermic or endothermic? Explain how you know. (b) Which form, graphite or diamond, has the higher density? (Hint: Think about what increasing the pressure of a gas does to its density. It works the same for the solid and liquid phases as well.)
For an endothermic reaction, will the equilibrium constant increase, decrease, or stay the same as the temperature of the reaction mixture increases? Explain your answer.
What effect does a catalyst have on: (a) The position of equilibrium for a reaction? (b) The value of the equilibrium constant? (c) The ratio of \(k_{\mathrm{f}} / k_{\mathrm{r}} ?\) 14.86 What does a catalyst do to the time it takes for a reaction to reach equilibrium? Explain how it does this.
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