What is a heterogeneous chemical reaction? Where does a heterogeneous reaction occur?

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A heterogeneous chemical reaction is a reaction that involves the interaction of two or more different phases, such as solid, liquid, or gas, and typically occurs at the interface between these phases. Examples include solid-liquid reactions like the dissolution of a salt in water, solid-gas reactions like the reaction between carbon and oxygen, liquid-gas reactions like the reaction between hydrogen and oxygen gases, and liquid-liquid reactions occurring between immiscible liquids. The interface between the different phases plays a crucial role in determining the rate of the heterogeneous reaction.

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01

Definition of a heterogeneous chemical reaction

A heterogeneous chemical reaction is a reaction that involves the interaction of two or more different phases. These phases can be solid, liquid, or gas. It typically occurs at the interface between the different phases, where the reactants are in direct contact with each other. The term "heterogeneous" refers to the fact that the reactants are not uniformly distributed throughout the reaction mixture.
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Examples of Heterogeneous reactions

Heterogeneous reactions can occur in various situations, such as: 1. Solid-liquid reactions: When a solid reacts with a liquid, the reaction occurs at the surface of the solid where it is in contact with the liquid. Examples include the dissolution of a salt in water or the corrosion of metals in the presence of water. 2. Solid-gas reactions: Here, the reaction occurs at the surface of a solid exposed to a gas. An example of this is the reaction between carbon and oxygen to form carbon dioxide (CO2), which occurs at the surface of the solid carbon. 3. Liquid-gas reactions: These reactions involve the interaction between a liquid and a gas, such as the dissolution of a gas in a liquid or the reaction between a gas and a dissolved substance in a liquid. An example would be the reaction between hydrogen gas and oxygen gas, which occurs at the liquid-gas interface when the two gases are bubbled through water. 4. Liquid-liquid reactions: These reactions occur at the interface between two immiscible liquids. An example is the reaction between oil and water when a surfactant is present to facilitate the reaction at the liquid-liquid interface.
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Importance of the interface in heterogeneous reactions

In heterogeneous chemical reactions, the interface between the different phases plays a crucial role in determining the rate of the reaction. This is because the reactants need to come into contact with one another for the reaction to take place. As a result, the rate of a heterogeneous reaction is often limited by the available interfacial area and the transport processes (such as diffusion) that bring the reactants into contact at the interface.

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Most popular questions from this chapter

Cooling an exothermic reaction for which \(K_{\text {eq }}\) is very low shifts the reaction to the right, so that more product is formed, but there is a trade-off. What is the downside of cooling such a reaction, as far as forming product is concerned?

Suppose you have a reaction with many reactants. When you write the equilibrium expression for the reaction, do the reactant concentrations all go in the numerator or in the denominator? What mathematical operation(s) should be used for these concentrations?

Diamond and graphite are two forms of elemental carbon. Under the appropriate conditions they will be in equilibrium with each other: \(C_{\text {diamond }} \rightleftarrows C_{\text {graphite }}\) If graphite is subjected to very high pressure and temperature, it will convert into the diamond form. (a) Is the above equilibrium reaction exothermic or endothermic? Explain how you know. (b) Which form, graphite or diamond, has the higher density? (Hint: Think about what increasing the pressure of a gas does to its density. It works the same for the solid and liquid phases as well.)

For an endothermic reaction, will the equilibrium constant increase, decrease, or stay the same as the temperature of the reaction mixture increases? Explain your answer.

What effect does a catalyst have on: (a) The position of equilibrium for a reaction? (b) The value of the equilibrium constant? (c) The ratio of \(k_{\mathrm{f}} / k_{\mathrm{r}} ?\) 14.86 What does a catalyst do to the time it takes for a reaction to reach equilibrium? Explain how it does this.

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