Chapter 18: Problem 8
What is meant by the term macromolecule? Are polymers macromolecules? Explain.
Chapter 18: Problem 8
What is meant by the term macromolecule? Are polymers macromolecules? Explain.
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Get started for freeCarbomer, a polymer used to thicken cosmetic lotions and creams, is a polymer of the monomer known as acrylic acid, shown below. Polymerization occurs due to the \(\mathrm{C}=\mathrm{C}\) double bond as it does for polyethylene. (a) Draw the polymer. (b) When this polymer is exposed to aqueous base, it deprotonates, and the resulting carboxylate anion hydrogen bonds to water very well, causing thickening of the aqueous solution. Draw this polymer in its deprotonated form, and show how water would hydrogen bond to it.
What is an amide bond? Show an amide bond between dimethylamine and acetic acid chloride.
When you burn wood, what are you actually burning? What are the combustion products?
What is a monomer? How does a monomer unit differ from a monomer? Give an example of each.
Amino acids are a sort of self-contradiction because they contain both a basic group (the \(\mathrm{NH}_{2}\) end) and an acidic group (the \(\mathrm{CO}_{2} \mathrm{H}\) end \()\) in the same molecule. Therefore, it should not surprise you that, when dissolved in water, an amino acid can react with itself to form what is known as a zwitterion. Based on this information, (a) Draw the structural formula for the form of the amino acid alanine you would expect to find in a neutral water solution. What is the net electrical charge on this species? (b) Enough concentrated \(\mathrm{HCl}\) is added to the solution of part (a) to make it strongly acidic. Draw the structural formula for the form of alanine you expect to find in this solution. What is the net charge on the alanine? (c) Enough concentrated \(\mathrm{NaOH}\) is added to the solution of part (a) to make it strongly basic. Draw the structural formula for the form of alanine you expect to find in this solution. What is the net charge on the alanine now?
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