Chapter 5: Problem 35
Write the proper name for \(\mathrm{Ca}(\mathrm{ClO})_{2} .\)
Short Answer
Expert verified
Calcium Hypochlorite
Step by step solution
01
Identify the Elements in the Compound
In the given compound, \(\mathrm{Ca}(\mathrm{ClO})_{2}\), we have two elements: Calcium (Ca) and Chlorine (Cl) combined with Oxygen (O). The subscript 2 outside the parentheses indicates that there are two \(\mathrm{ClO}\) groups in the compound. So, it's a combination of calcium with a polyatomic ion containing chlorine and oxygen.
02
Identify the Polyatomic Ion
In this compound, \(\mathrm{ClO}\) group forms a polyatomic ion called hypochlorite (ClO⁻). The negative charge on the oxygen and the positive charge on the chlorine give it a net -1 charge. Because two of these hypochlorite ions are involved in the compound, as evidenced by the subscript 2, the combined charge for the hypochlorite ions is -2.
03
Determine the Oxidation States of the Elements
In this compound, the oxidation state of Calcium (Ca) is +2 as it is part of group 2 and loses two electrons readily. The two hypochlorite (ClO⁻) ions each have an oxidation state of -1, and since there are two of them in the compound, their cumulative oxidation state is -2. This balances the total charges in the compound, as the +2 charge of Calcium adds up with the -2 charge of the hypochlorite ions to give a neutral compound.
04
Name the Compound
Now that we know the compound consists of Calcium (Ca) and the hypochlorite ion (ClO⁻), we can name it using the proper naming conventions. For ionic compounds, we use the name of the metal (cation) followed by the name of the non-metal or polyatomic ion (anion). In this case, the compound is named as Calcium Hypochlorite.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Nomenclature
Chemical nomenclature is the systematic process of assigning names to chemical compounds. It is a critical part of chemistry that ensures clarity and precision when identifying substances. In the example given, \(\mathrm{Ca}(\mathrm{ClO})_{2}\), we are working with an ionic compound, which is composed of a metal (calcium) and a non-metal (hypochlorite ion). The naming convention for such compounds involves first stating the name of the metal, followed by the name of the non-metal or polyatomic ion.
The key is to use the root name of the non-metal with an appropriate suffix (like '-ide', '-ate', or '-ite') that indicates a specific type of ion. Hypochlorite is a polyatomic ion with a specific charge and composition, so its name is used directly after 'calcium' to complete the nomenclature. Hence, in our case, the name 'Calcium Hypochlorite' correctly represents the compound. Understanding these conventions not only helps in naming compounds but also in deducing the composition of a compound based on its name.
The key is to use the root name of the non-metal with an appropriate suffix (like '-ide', '-ate', or '-ite') that indicates a specific type of ion. Hypochlorite is a polyatomic ion with a specific charge and composition, so its name is used directly after 'calcium' to complete the nomenclature. Hence, in our case, the name 'Calcium Hypochlorite' correctly represents the compound. Understanding these conventions not only helps in naming compounds but also in deducing the composition of a compound based on its name.
Polyatomic Ions
Polyatomic ions are charged species made up of two or more atoms covalently bonded together that function as a single ion. When identifying or naming compounds like \(\mathrm{Ca}(\mathrm{ClO})_{2}\), recognizing the polyatomic ions involved is crucial.
For example, the hypochlorite ion (\(\mathrm{ClO}^-\)) is the component in question here. These ions have characteristic names and oxidation states that need to be known for correct nomenclature and chemical formulations. It's important to note that the oxidation state of oxygen is typically -2, but in polyatomic ions, the combined charges add up differently. In hypochlorite, with one chlorine and one oxygen atom, the overall charge of the ion is -1, which affects how it combines with other ions, such as calcium (\(\mathrm{Ca}^{2+}\)) to form a neutral compound.
For example, the hypochlorite ion (\(\mathrm{ClO}^-\)) is the component in question here. These ions have characteristic names and oxidation states that need to be known for correct nomenclature and chemical formulations. It's important to note that the oxidation state of oxygen is typically -2, but in polyatomic ions, the combined charges add up differently. In hypochlorite, with one chlorine and one oxygen atom, the overall charge of the ion is -1, which affects how it combines with other ions, such as calcium (\(\mathrm{Ca}^{2+}\)) to form a neutral compound.
Oxidation States
Oxidation states, also known as oxidation numbers, represent the degree of oxidation of an atom in a chemical compound. This concept is pivotal when balancing chemical equations and understanding reaction mechanisms. In the Calcium Hypochlorite example, calcium exhibits an oxidation state of +2, indicating it has lost two electrons, which is typical for its group in the periodic table.
The polyatomic ion hypochlorite has an overall -1 charge, meaning each oxygen atom has an assumed oxidation state of -2 and the chlorine is adjusted to balance the charge. When two hypochlorite ions bond with one calcium ion, their charges balance out (+2 from calcium and a total of -2 from the two hypochlorite ions), resulting in a neutrally charged compound. Remember that the sum of oxidation states for all atoms in a neutral compound must equal zero, which is a good check for correctly identifying and naming chemical compounds.
The polyatomic ion hypochlorite has an overall -1 charge, meaning each oxygen atom has an assumed oxidation state of -2 and the chlorine is adjusted to balance the charge. When two hypochlorite ions bond with one calcium ion, their charges balance out (+2 from calcium and a total of -2 from the two hypochlorite ions), resulting in a neutrally charged compound. Remember that the sum of oxidation states for all atoms in a neutral compound must equal zero, which is a good check for correctly identifying and naming chemical compounds.