Determine the empirical formula of the compound that is \(26.4 \%\) by mass \(\mathrm{Na}, 36.8 \%\) by mass \(\mathrm{S}\), and also contains oxygen.

Short Answer

Expert verified
The empirical formula of the compound is NaSO₂.

Step by step solution

01

Find the grams of each element in 100g compound

Assume you have a 100g sample of the compound. Given the mass percentages of Na, S, and O, we can determine the grams of each element in the 100g sample. For Na: \(26.4\% \times 100g = 26.4g\) For S: \(36.8\% \times 100g = 36.8g\) For O: The remaining mass percentage is for O, so \(100\% - 26.4\% - 36.8\% = 36.8\%\). Therefore, the mass of O in the 100g sample is \(36.8\% \times 100g = 36.8g\).
02

Convert grams to moles

Next, we will convert the mass of each element in grams to moles. To do this, we will use the molar masses of each element: Na (22.99 g/mol), S (32.07 g/mol), and O (16.00 g/mol). Moles of Na: \(\frac{26.4 g}{22.99 g/mol} = 1.15\) moles Moles of S: \(\frac{36.8 g}{32.07 g/mol} = 1.15\) moles Moles of O: \(\frac{36.8 g}{16.00 g/mol} = 2.30\) moles
03

Find the simplest whole-number ratio

Divide the moles of each element by the smallest number of moles to find the simplest whole-number ratio: For Na: \(\frac{1.15}{1.15} = 1\) For S: \(\frac{1.15}{1.15} = 1\) For O: \(\frac{2.30}{1.15} = 2\) The empirical formula is NaSO₂.

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