Evaluate the commutators (a) \([x, y]\) (b) \(\left[p_{x}, p_{y}\right]\) (c) \(\left[x, p_{x}\right]\) (d) \(\left[x^{2}, p_{x}\right]\) (e) \(\left[x^{n}, p_{x}\right]\)

Short Answer

Expert verified
The results of the commutators are: (a) 0, (b) 0, (c) \(i\hbar\), (d) \(2xi\hbar\), and (e) \(inx^{n-1}i\hbar = in\hbar x^{n-1}\)

Step by step solution

01

Evaluation of the first commutator

Since \(x\) and \(y\) are two different variables and thus independent, their commutator is simply zero. Hence, \([x, y] = 0\)
02

Evaluation of the second commutator

Again, since \(p_{x}\) and \(p_{y}\) are the momenta in two different, and thus independent, directions, their commutator is zero. Hence, \([p_{x}, p_{y}] = 0\)
03

Evaluation of the third commutator

It's a fundamental result in quantum mechanics that the commutator of the position and momentum in the same direction is equal to \(i\hbar\). Hence, \([x, p_{x}] = i\hbar\)
04

Evaluation of the fourth commutator

The operator \(x^{2}\) can be rewritten as \(xx\), which results in \([x^{2}, p_{x}] = [xx, p_{x}] = x[x, p_{x}] + [x, p_{x}]x = xi\hbar + i\hbar x = 2xi\hbar\)
05

Evaluation of the fifth commutator

To evaluate the commutator \([x^{n}, p_{x}]\), you need to iteratively apply the operator to \([x,x^{n-1}]\), using the relation worked out in step 4. After doing this, you will find \([x^{n}, p_{x}] = inx^{n-1}i\hbar = in\hbar x^{n-1}\)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Find the operator for position \(x\) if the operator for momentum \(p\) is taken to be \((\hbar / 2 m)^{1 / 2}(A+B),\) with \([A, B]=1\) and all other commutators zero. Hint. Write \(x=a A+b B\) and find one set of solutions for \(a\) and \(b\)

Are the linear combinations \(2 x-y-z, 2 y-x-z\) \(2 z-x-y\) linearly independent?

Confirm that the operators (a) \(T=-\left(\hbar^{2} / 2 m\right)\left(d^{2} / d x^{2}\right)\) and (b) \(l_{z}=(\hbar / \mathrm{i})(\mathrm{d} / \mathrm{d} \varphi)\) are Hermitian. Hint. Consider the integrals \(\int_{0}^{L} \psi_{a}^{*} T \psi_{b} \mathrm{d} x\) and \(\int_{0}^{2 \pi} \psi_{a}^{*} l_{z} \psi_{b} \mathrm{d} \varphi\) and integrate by parts.

Evaluate the commutators (a) \(\left[H, p_{x}\right]\) and (b) \([H, x]\) where \(H=p_{x}^{2} / 2 m+V(x) .\) Choose (i) \(V(x)=V,\) a constant, (ii) \(V(x)=\frac{1}{2} k_{t} x^{2},\) (iii) \(V(x) \rightarrow V(r)=e^{2} / 4 \pi \varepsilon_{0} r .\) Hint. For part (b), case (iii), use \(\left(\partial r^{-1} / \partial x\right)=-x / r^{3}\)

The ground-state wavefunction of a hydrogen atom has the form \(\psi(r)=N \mathrm{e}^{-b r}, b\) being a collection of fundamental constants with the magnitude \(1 / a_{0},\) with \(a_{0}=53 \mathrm{pm}\) Normalize this spherically symmetrical function. Hint. The volume element is \(\mathrm{d} \tau=\sin \theta \mathrm{d} \theta \mathrm{d} \varphi r^{2} \mathrm{d} r,\) with \(0 \leq \theta \leq \pi\) \(0 \leq \varphi \leq 2 \pi,\) and \(0 \leq r<\infty,\) 'Normalize' always means 'normalize to 1 ' in this text.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free