Evaluate the matrix elements (a) \(\langle v+1|x| v\rangle\) and (b) \(\left\langle v+2\left|x^{2}\right| v\right\rangle\) of a harmonic oscillator by using the relations given at the bottom of Table 2.1 for the Hermite polynomials.

Short Answer

Expert verified
The matrix elements for the harmonic oscillator are (a) \(\langle v+1|x| v\rangle = 0\) and (b) \(\langle v+2|x^2|v\rangle = 0\). These are derived from the Hermite polynomial relations, taking into account that different energy states are orthogonal to each other.

Step by step solution

01

Apply the relation for Hermite polynomials

For part (a), start by noting the expression for the \(v+1\) term derived from the Hermite polynomial: \(H_{v+1} = 2vH_v -2(v-1)H_{v-1}\) where \(v\) is the index of the Hermite polynomial. In terms of the state of a harmonic oscillator, the term \(x|v\rangle\) is related to Hermite polynomials. Substitute \(x|v\rangle\) into the above expression.
02

Simplify and evaluate the matrix element

Rewrite \(2vH_v -2(v-1)H_{v-1}\) as \(2v|x|v\rangle -2(v-1)|x|v-1\rangle\). Assuming that the wave functions are normalized, the inner product \(\langle v+1|v\rangle\) is 0 for \(v+1 \neq v\). Thus, \(\langle v+1|x| v\rangle = 0\). Simplify to solve for part (a).
03

Apply the relation for Hermite polynomials for part (b)

For part (b), note that the expression for the \(x^2\) term is related to Hermite polynomials as \(H_{v+1} + H_{v-1} = 2vH_v\). Substitute \(x^2|v\rangle\) instead of \(|x|v\rangle\) into this expression.
04

Simplify and evaluate the matrix element for part (b)

Rewrite as \(\langle v+2|x^2|v \rangle = 2v|\langle v+1|x|v\rangle + |\langle v-1|x|v\rangle\rangle\). From Step 2, it was found that \(\langle v+1|x|v\rangle = 0\), so simplify the expression, which results in the term \(\langle v+2|x^2|v\rangle = |\langle v-1|x|v\rangle\rangle\). The inner product \(\langle v+2|v\rangle\) is 0 for \(v+2 \neq v\). So, \(\langle v+2|x^2|v \rangle = 0\). This is the simplified answer for part (b).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Demonstrate that accidental degeneracies can exist in a rectangular infinite square-well potential provided that the lengths of the sides are in a rational proportion, that is when \(L_{1}=\lambda L_{2},\) with \(\lambda\) an integer. What is the degeneracy?

(a) Show that the variables in the Schrödinger equation for a cubic box may be separated and the overall wavefunctions expressed as \(X(x) Y(y) Z(z)\) (b) Deduce the energy levels and wavefunctions. (c) Show that the function .are orthonormal. (d) What is the degeneracy of the level with \(E=14\left(h^{2} / 8 m L^{2}\right) ?\)

The oscillation of the atoms around their equilibrium positions in the molecule HI can be modelled as a harmonic oscillator of mass \(m \approx m_{\mathrm{H}}\) (the iodine atom is almost stationary \()\) and force constant \(k_{\mathrm{f}}=313.8 \mathrm{N} \mathrm{m}^{-1} .\) Evaluate the separation of the energy levels and predict the wavelength of the light needed to induce a transition between neighbouring levels.

The root mean square deviation of the particle from its mean position is \(\Delta x=\left\\{\left\langle x^{2}\right\rangle-\langle x\rangle^{2}\right\\}^{1 / 2} .\) Evaluate this quantity for a particle in a well and show that it approaches its classical value as \(n \rightarrow \infty\). Hint. Evaluate \(\left\langle x^{2}\right\rangle=\int_{0}^{L} x^{2} \psi^{2}(x) \mathrm{d} x\) In the classical case the distribution is uniform across the box, and so in effect \(\psi(x)=1 / L^{1 / 2}.\)

Consider a harmonic oscillator of mass \(m\) undergoing harmonic motion in two dimensions \(x\) and \(y .\) The potential energy is given by \(V(x, y)=\frac{1}{2} k_{x} x^{2}+\frac{1}{2} k_{y} y^{2}\). (a) Write down the expression for the hamiltonian operator for such a system. (b) What is the general expression for the allowable energy levels of the two- dimensional harmonic oscillator? (c) What is the energy of the ground state (the lowest energy state)? Hint. The hamiltonian operator can be written as a sum of operators.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free