Calculate the values of (a) \(\langle x\rangle\) (b) \(\left\langle x^{2}\right\rangle\) \(,(\mathrm{c})\left\langle p_{x}\right\rangle,(\mathrm{d})\left\langle p_{x}^{2}\right\rangle\) for a harmonic oscillator in its ground state by evaluation of the appropriate integrals (as in Problems \(2.13-2.15\) ). Examine the value of \(\Delta x \Delta p_{x}\) in the light of the uncertainty principle. Hint. Use the integrals \\[ \begin{array}{l} \int_{-\infty}^{\infty} \mathrm{e}^{-\alpha x^{2}} \mathrm{d} x=\left(\frac{\pi}{\alpha}\right)^{1 / 2} \\ \int_{0}^{\infty} x \mathrm{e}^{-\alpha x^{2}} \mathrm{d} x=\frac{1}{2 \alpha} \\\ \int_{-\infty}^{\infty} x^{2} \mathrm{e}^{-\alpha x^{2}} \mathrm{d} x=\frac{1}{2}\left(\frac{\pi}{\alpha^{3}}\right)^{1 / 2} \end{array} \\]

Short Answer

Expert verified
The calculated averages and uncertainties are \(\langle x\rangle=0\), \(\langle x^{2}\rangle=\frac{\hslash}{2m \omega}\), \(\langle p_{x}\rangle=0\), \(\langle p_{x}^{2}\rangle=\frac{\hslash^{2}\omega}{2}\), \( \Delta x =\sqrt{\frac{\hslash}{2m \omega}}\) and \( \Delta p_{x} =\sqrt{\frac{\hslash^{2}\omega^2}{4}}\). The computed values satisfy the uncertainty principle as \( \Delta x \Delta p_{x} =\frac{\hslash}{2}\).

Step by step solution

01

Calculation of \(\langle x\rangle\)

The wave function for a harmonic oscillator in its ground state is \(\Psi_{0}(x)=\left(\frac{\omega}{\pi \hslash}\right)^{1/4} \exp\left(-\frac{m \omega x^{2}}{2 \hslash}\right)\). Thus \(\langle x\rangle= \int_{-\infty}^{\infty}\Psi^{*}_{0}(x) x \Psi_{0}(x) dx = \left(\frac{\omega}{\pi \hslash}\right)^{1/2} \int_{-\infty}^{\infty} x \exp\left(-\frac{m \omega x^{2}}{\hslash}\right) dx\). Using the second integral provided, this simplifies to 0.
02

Calculation of \(\langle x^{2}\rangle\)

For \(\langle x^{2}\rangle= \int_{-\infty}^{\infty}\Psi^{*}_{0}(x) x^{2} \Psi_{0}(x) dx = \left(\frac{\omega}{\pi \hslash}\right)^{1/2} \int_{-\infty}^{\infty} x^{2} \exp\left(-\frac{m \omega x^{2}}{\hslash}\right) dx\). Utilizing the third integral in the hint, we find \(\langle x^{2}\rangle =\frac{\hslash}{2m \omega}\).
03

Calculation of \(\langle p_{x}\rangle\)

Since the wave function is real, we know that \(\langle p_{x}\rangle= \int_{-\infty}^{\infty}\Psi^{*}_{0}(x)\left(-i\hslash\frac{d}{dx}\right)\Psi_{0}(x) dx =0\).
04

Calculation of \(\langle p_{x}^{2}\rangle\)

To solve \(\langle p_{x}^{2}\rangle=\int_{-\infty}^{\infty}\Psi^{*}_{0}(x)\left(-\hslash^{2}\frac{d^{2}}{dx^{2}}\right)\Psi_{0}(x) dx \), we can derive the second derivative of the wave function \(\Psi_0'(x)\) followed by applying the integration of \(\Psi^*_0(x) \Psi'_0(x)\). This leads to \(\langle p_{x}^{2}\rangle = \frac{\hslash^{2}\omega}{2}\).
05

Uncertainty Principle Check

The uncertainty principle states that \( \Delta x \Delta p_{x} \geq \frac{\hslash}{2}\). From Heisenberg's uncertainty principle, we calculate the uncertainties as \( \Delta x = \sqrt{ \langle x^{2}\rangle - \langle x\rangle^2} =\sqrt{\frac{\hslash}{2m \omega}}\) and \( \Delta p_{x} = \sqrt{ \langle p_{x}^{2}\rangle - \langle p_{x}\rangle^2} =\sqrt{\frac{\hslash^{2}\omega^2}{4}}\). Therefore, \( \Delta x \Delta p_{x} =\frac{\hslash}{2}\), which satisfies the uncertainty principle.

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Most popular questions from this chapter

The oscillation of the atoms around their equilibrium positions in the molecule HI can be modelled as a harmonic oscillator of mass \(m \approx m_{\mathrm{H}}\) (the iodine atom is almost stationary \()\) and force constant \(k_{\mathrm{f}}=313.8 \mathrm{N} \mathrm{m}^{-1} .\) Evaluate the separation of the energy levels and predict the wavelength of the light needed to induce a transition between neighbouring levels.

Calculate the energies and wavefunctions for a particle in a one-dimensional square well in which the potential energy rises to a finite value \(V\) at each end, and is zero inside the well; that is \\[ \begin{array}{ll} V(x)=V & x \leq 0 \text { and } x \geq L \\ V(x)=0 & 0

Energy is required to compress the box when a particle is inside: this suggests that the particle exerts a force on the walls. (a) On the basis that when the length of the box changes by dL the energy changes by \(\mathrm{d} E=-F \mathrm{d} L,\) find an expression for the force. (b) At what length does \(F=1 \mathrm{N}\) when an electron is in the state \(n=1 ?\)

For a particle in a box, the mean value and mean square value of the linear momentum are given by \(\int_{0}^{L} \psi^{*} p \psi \mathrm{d} x\) and \(\int_{0}^{L} \psi^{*} p^{2} \psi \mathrm{d} x,\) respectively. Evaluate these quantities. Form the root mean square deviation \(\Delta p=\left\\{\left\langle p^{2}\right\rangle-\langle p\rangle^{2}\right\\}^{1 / 2}\) and investigate the consistency of the outcome with the uncertainty principle. Hint. Use \(p=(\hbar / \mathrm{i}) \mathrm{d} / \mathrm{d} x .\) For \(\left\langle p^{2}\right\rangle\) notice that \(E=p^{2} / 2 m\) and we already know \(E\) for each \(n\). For the last part, form \(\Delta x \Delta p\) and show that \(\Delta x \Delta p \geq \frac{1}{2} \hbar,\) the precise form of the principle, for all \(n\) evaluate \(\Delta x \Delta p\) for \(n=1.\)

Determine the probability of finding the ground-state harmonic oscillator stretched to a displacement beyond the classical turning point. Hint. Relate the expression for the probability to the error function, erf \(z,\) defined as \\[ \operatorname{erf} z=1-\frac{2}{\pi^{1 / 2}} \int_{z}^{\infty} \mathrm{e}^{-y^{2}} \mathrm{d} y \\] and evaluate it using erf \(1=0.8427 .\) The error function is incorporated into most mathematical software packages.

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