Chapter 4: Problem 10
Suppose that in place of the actual angular momentum commutation rules, the operators obeyed \(\left[l_{x}, l_{y}\right]=-\mathrm{i} \hbar l_{z^{*}}\) What would be the roles of \(l_{2}=l_{x} \pm l_{y} ?\)
Chapter 4: Problem 10
Suppose that in place of the actual angular momentum commutation rules, the operators obeyed \(\left[l_{x}, l_{y}\right]=-\mathrm{i} \hbar l_{z^{*}}\) What would be the roles of \(l_{2}=l_{x} \pm l_{y} ?\)
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Get started for freeWhat are the possible outcomes of a single measurement of the \(z\) -component of spin angular momentum of an electron in the spin state \((1 / 4)^{1 / 2} \alpha-(3 / 4)^{1 / 2} \beta ?\)
(a) Confirm that the Pauli matrices \\[ \sigma_{x}=\left(\begin{array}{ll} 0 & 1 \\ 1 & 0 \end{array}\right) \quad \sigma_{y}=\left(\begin{array}{rr} 0 & -\mathrm{i} \\ \mathrm{i} & 0 \end{array}\right) \quad \boldsymbol{\sigma}_{z}=\left(\begin{array}{rr} 1 & 0 \\ 0 & -1 \end{array}\right) \\] satisfy the angular momentum commutation relations when we write \(s_{q}=\frac{1}{2} \hbar \sigma_{q},\) and hence provide a matrix representation of angular momentum. (b) Why does the representation correspond to \(s=1 / 2\) ? Hint. For the second part, form the matrix representing \(s^{2}\) and establish its eigenvalues.
Using the Pauli matrix representation, reduce each of the operators (a) \(s_{x} s_{y}\) (b) \(s_{x} s_{y}^{2} s_{z}^{2},\) and (c) \(s_{x}^{2} s_{y}^{2} s_{z}^{2},\) to a single spin operator.
Determine what total angular momenta may arise in the following composite systems: (a) \(j_{1}=3, j_{2}=4 ;\) (b) the orbital momenta of two electrons (i) both in p-orbitals, (ii) both in d-orbitals, (iii) the configuration \(\mathrm{p}^{1} \mathrm{d}^{1} ;\) (c) the spin angular momenta of four electrons. Hint. Use the ClebschGordan series, eqn \(4.42 ;\) apply it successively in (c).
Calculate the matrix elements (a) \(\left\langle 0,0\left|l_{z}\right| 0,0\right\rangle\) (b) \(\left\langle 2,1\left|l_{+}\right| 2,0\right\rangle\) (c) \(\left\langle 2,2\left|l_{+}^{2}\right| 2,0\right\rangle,\) (d) \(\left\langle 2,0\left|l_{+} l_{-}\right| 2,0\right\rangle\) (e) \(\left\langle 2,0\left|l \downarrow_{+}\right| 2,0\right\rangle,\) and (f) \(\left\langle 2,0\left|l^{2} l_{z} l^{2}+\right| 2,0\right\rangle\)
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