Zinc and hydrochloric acid react according to the reaction : $$ \mathrm{Zn}(\mathrm{s})+2 \mathrm{HCl}(\mathrm{aq} .) \longrightarrow \mathrm{ZnCl}_{2}(\mathrm{aq} .)+\mathrm{H}_{2}(\mathrm{~g}) $$ If \(0.30\) mole of \(\mathrm{Zn}\) are added to hydrochloric acid containing \(0.52\) mole HCl, how many moles of \(\mathrm{H}_{2}\) are produced?

Short Answer

Expert verified
0.26 moles of H2 are produced.

Step by step solution

01

Understanding the Chemical Reaction

Evaluate the stoichiometry of the given reaction by understanding the molar ratio of the reactants to the products. In the reaction \[\mathrm{Zn(s)} + 2\mathrm{HCl(aq)} \longrightarrow \mathrm{ZnCl}_2(\mathrm{aq}) + \mathrm{H}_2(\mathrm{g})\],1 mole of Zn reacts with 2 moles of HCl to produce 1 mole of ZnCl2 and 1 mole of H2. The molar ratio of Zn to H2 is therefore 1:1.
02

Determining the Limiting Reactant

Identify the limiting reactant, which is the reactant that will be completely consumed first and hence limit the extent of the reaction. We have 0.30 moles of Zn and 0.52 moles of HCl, therefore: For Zn: 0.30 moles Zn (1 mole H2/1 mole Zn) = 0.30 moles H2 (theoretical), For HCl: 0.52 moles HCl (1 mole H2/2 moles HCl) = 0.26 moles H2. Since the amount of HCl only produces 0.26 moles of H2 and Zn could produce 0.30 moles of H2, HCl is the limiting reactant.
03

Calculating Moles of H2 Produced

Since HCl is the limiting reactant, use its moles to calculate the moles of H2 produced. From the balanced equation, 2 moles of HCl produce 1 mole of H2. Thus, 0.52 moles of HCl will produce: \[0.52 \text{ moles HCl} \times \frac{1 \text{ mole H}_2}{2 \text{ moles HCl}} = 0.26 \text{ moles H}_2.\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Limiting Reactant
Understanding the concept of the limiting reactant is crucial in predicting the amount of products formed in a chemical reaction. It's the substance that is totally consumed when the chemical reaction is complete, determining the maximum amount of product that can be produced. In practical terms, imagine baking cookies: if your recipe calls for one egg per batch and you have five eggs but enough flour for ten batches, you can only make five batches of cookies because eggs are the limiting reactant.
In our zinc and hydrochloric acid reaction, by comparing the moles of each reactant and the stoichiometry, we can identify the limiting reactant. Since hydrochloric acid (HCl) is available in fewer moles than required according to the reaction's stoichiometric ratio, HCl is the limiting reactant. Knowing the limiting reactant is vital for accurate stoichiometry calculations since it allows us to calculate the exact number of moles of products produced in the reaction.
Stoichiometry Calculations
Stoichiometry calculations are mathematical techniques used to determine the amounts of reactants required or products formed in a chemical reaction. These calculations are based on the balanced chemical equation, which provides the mole ratios of reactants and products. In essence, stoichiometry is like a recipe for chemistry. Just as you would use a recipe to find out how much flour and sugar you need for a cake, you use stoichiometry to find out how much of each reactant you need to get your products.
In our exercise, we used the mole ratios from the balanced equation for zinc and hydrochloric acid to calculate the theoretical yield of hydrogen gas (H2) from Zn and HCl. Such calculations require a clear understanding of the mole concept and the ability to apply the mole ratios to determine the amount of product from a given amount of reactant, which brings us to the mole concept.
Mole Concept
The mole concept is one of the central ideas in chemistry and serves as a bridge between the microscopic world of atoms and molecules and the macroscopic world of grams and kilograms that we can measure. One mole is defined as Avogadro's number (\(6.022 \times 10^{23}\)) of particles, whether they are atoms, molecules, ions, or others. It's similar to a dozen eggs being 12 eggs; one mole of any substance is always the same number of particles.
The importance of the mole lies in its ability to relate mass to a count of atoms or molecules. In the context of chemical reactions, being able to convert from moles to grams and vice versa is essential for stoichiometry calculations. Our exercise demonstrated this by converting moles of reactants to moles of products using the balanced equation as the guide.
Chemical Reactions
Chemical reactions involve the transformation of one or more substances into new substances. These changes occur during the breaking and forming of chemical bonds, leading to products that have different properties from the reactants. Every chemical reaction is governed by conservation of mass and follows a balanced equation where the number of atoms of each element in the reactants equals the number of atoms in the products.
In our zinc and hydrochloric acid reaction, the solid zinc reacts with aqueous hydrochloric acid to form aqueous zinc chloride and gaseous hydrogen. This reaction is a type of single displacement reaction, where an element displaces another element in a compound, producing a new compound and an element. Understanding the types of reactions and their mechanisms enables us to predict the products and to carry out appropriate stoichiometry calculations.

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