What volume of water is required to make \(0.20 \mathrm{~N}\) solution from \(1600 \mathrm{~mL}\) of \(0.2050 \mathrm{~N}\) solution?

Short Answer

Expert verified
40 mL of water is required.

Step by step solution

01

Understand the Concept of Normality

Normality (N) is a measure of concentration that is equivalent to the molarity times the equivalent factor, which depends on the type of reaction the solute participates in. When diluting a solution, the amount of substance in equivalents remains constant. We use the dilution formula: initial volume times initial normality equals final volume times final normality (ViNi = VfNf).
02

Identify Given Information

We are given the initial volume (Vi = 1600 mL) and initial normality (Ni = 0.2050 N) of the solution, and we want to find the final volume (Vf) for a desired normality (Nf = 0.20 N).
03

Use the Dilution Formula to Solve for Final Volume

Using the formula ViNi = VfNf, we can rearrange it to solve for the final volume: Vf = (Vi * Ni) / Nf. Plug in the known values: Vf = (1600 mL * 0.2050 N) / 0.20 N.
04

Calculate the Final Volume

Vf = (1600 mL * 0.2050) / 0.20 = 328 mL / 0.20 = 1640 mL. So, the final volume of the diluted solution is 1640 mL.
05

Determine the Volume of Water Required

To find the volume of water required for dilution, subtract the initial volume from the final volume: Volume of water = Vf - Vi = 1640 mL - 1600 mL = 40 mL.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Normality Concept
Let's begin by demystifying the concept of normality, a term often encountered in chemistry when dealing with solutions. Normality (N) is a metric used to express the concentration of a solution. It is specifically defined as the number of gram equivalents of solute per liter of solution. This can change based on the reaction involved because it's dependent on the equivalence factor, which is the amount of solute that can react with or supply one mole of hydrogen ions (H+), hydroxide ions (OH-), electrons, or other pivotal reactants in a given chemical reaction.

To grasp this concept fully, consider a common acid-base reaction where normality is crucial: vinegar (acetic acid) neutralizing baking soda (sodium bicarbonate). If the vinegar is 1 N, this tells us there's one gram equivalent of acetic acid per liter, capable of neutralizing one gram equivalent of sodium bicarbonate. In different reaction scenarios, the equivalence factor might change, impacting the normality. For instance, in redox reactions, it's the number of electrons transferred that influences normality. By understanding these nuances, we can see how normality becomes a versatile tool for chemists, enabling precise formulation and reaction predictions.
Dilution Formula
With the context of normality in place, let's pivot to the heart of the dilution process: the dilution formula. This formula is delightfully straightforward yet incredibly powerful. It states that the initial volume of the solution multiplied by the initial normality is equal to the final volume of the solution multiplied by the final normality, or mathematically represented as ViNi = VfNf.

To put this into action, let's consider you're working to weaken a sauce in cooking by adding water. Similar principles apply here as in chemistry. If you start with a certain concentration (normality) of sauce, and you add some water, the 'strength' of the sauce's flavor dilutes. Concurrently, in our chemical scenario, adding water to a solution lowers the normality. Our formula ensures that despite the dilution, the amount of solute, in terms of equivalents, remains constant. This guarantees fidelity and allows for predictable scaling of volume without upsetting the ratio of reactants.
Dilution Problem Solving
Solving dilution problems typically involves a strategic approach where you identify critical information and apply the dilution formula effectively. In the example provided, we were presented with a clear task: dilute a given solution to achieve a desired normality. We first pinpointed the initial conditions - volume and normality - of our solution. Afterward, we introduced the final condition we aimed for, the target normality.

From there, it's a matter of algebraic manipulation, as we rearrange the dilution equation to solve for the unknown - in this case, the final volume. With the equation rearranged as Vf = (Vi * Ni) / Nf, we simply substitute our known values to find the answer. It's critical to pay attention to the units, ensuring that they align and if not, converting them accordingly to avoid any mishaps in the calculation. This step-by-step methodology is a reliable route to solving dilution problems, ingraining a systematic mindset for tackling various chemistry problems.
Concentration Calculation
Mastering the skill of concentration calculation is crucial for accurate scientific work. Concentration not only pertains to normality but also to other measures like molarity, molality, and mass percent. The ability to switch between these different types of concentration calculations allows for versatility in the lab setting. For instance, sometimes you might be required to calculate the volume of solvent needed to achieve a certain molarity from a stock solution.

In our educational exercise, the determination of the volume of water necessary to dilute our solution was the goal. Once we computed the final volume required for our desired concentration, it was a straightforward subtraction to find the needed volume of water. Skills in concentration calculation form the bedrock of experimental design, titration analysis, and even in industrial processes where chemical solutions must be manipulated carefully. Grasping the relationship between solute, solvent, and overall solution concentration is essential for any budding chemist.

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