Commercially available concentrated hydrochloric acid contains \(38 \%\) \(\mathrm{HCl}\) by mass. (a) What is the molarity of this solution? The density is \(1.19 \mathrm{~g} \mathrm{~mL}^{-1}\). (b) What volume of concentrated \(\mathrm{HCl}\) is required to make \(1.00\) litre of \(0.10 \mathrm{M} \mathrm{HCl} ?\)

Short Answer

Expert verified
The molarity of the concentrated HCl solution is 12.40 M. To make 1.00 litre of 0.10 M HCl, 8.06 mL of the concentrated HCl is required.

Step by step solution

01

Calculate the mass of HCl per liter

First, we calculate the mass of the hydrochloric acid in one liter of the solution by multiplying the density of the solution by the volume. Since the density is given as 1.19 g/mL, for 1000 mL (which is one liter), the total mass of the solution is 1.19 g/mL * 1000 mL = 1190 g.
02

Calculate the mass of HCl

Given that the hydrochloric acid is 38% by mass, we calculate the mass of the actual HCl in that one liter of the solution. This is 38% of 1190 g, which gives (38/100) * 1190 g = 452.2 g of HCl.
03

Calculate the number of moles of HCl

The molar mass of HCl is approximately 36.46 g/mol. To find the moles of HCl, we divide the mass of HCl by its molar mass. So, the moles of HCl are 452.2 g / 36.46 g/mol = 12.40 mol.
04

Calculate the molarity of the HCl solution

Molarity is defined as the number of moles of solute divided by the volume of solution in liters. In one liter, there are 12.40 moles of HCl, so the molarity of the concentrated solution is 12.40 M.
05

Calculate the volume needed to make a 0.10 M solution

Using the dilution equation M1V1 = M2V2, where M1 is the molarity of the concentrated solution, V1 is the volume of the concentrated solution needed, M2 is the molarity of the diluted solution, and V2 is the volume of the diluted solution. We plug in the values (12.40 M)(V1) = (0.10 M)(1.00 L). Solving for V1 gives V1 = (0.10 M)(1.00 L) / 12.40 M = 0.00806 L or 8.06 mL.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Concentration of Solutions
When talking about the concentration of solutions, we refer to the amount of substance, known as the solute, dissolved in a specific volume of solvent. It is essential for students to comprehend how to express concentration since it is a foundation of stoichiometry in chemistry.

There are various ways to quantify concentration, but a common one is molarity. Molarity, denoted as M, is defined as the number of moles of solute per liter of solution. It's calculated by dividing the number of moles of solute by the volume of the solution in liters.

To apply this in our exercise, we first find the mass of HCl in one liter of solution from its density, then calculate the moles of HCl using its molar mass, and finally divide by the solution's volume to determine the molarity. It's like a recipe, where you measure the ingredients (moles of HCl) and then figure out how much soup (solution) you can make with them. This understanding is critical not only for academic purposes but also for practical applications in laboratories and industries.
Stoichiometry in Chemistry
Stoichiometry in chemistry is like the mathematics of molecules. It involves calculations that relate the quantities of reactants and products in a chemical reaction. Students need to grasp this concept to handle reactions and understand the relationships within. A fundamental stoichiometric principle is the conservation of mass, which states that matter is neither created nor destroyed in a chemical reaction.

For stoichiometry, molar relationships are key; knowing the number of moles of each reactant and product involved. The balanced chemical equation provides the molar ratio needed to perform calculations. In the context of our exercise, we used the stoichiometry of the HCl solution to calculate the mass, moles, and then molarity, showcasing how stoichiometry is applied beyond just reactions but also to solution preparation.
Dilution Equation
The dilution equation is a vital concept in chemistry for decreasing the concentration of a solution without altering the amount of solute present. This concept helps in preparing solutions of desired concentrations and is based on the principle that the amount of solute remains the same before and after dilution.

The dilution equation is represented as M1V1 = M2V2, where M1 is the initial molarity, V1 is the volume of the starting solution, M2 is the final molarity, and V2 is the final volume. For our exercise, we used this equation to find the volume of concentrated HCl needed to make a more diluted solution. Remember to think of it as watering down paint; you're spreading the color (solute) thinner over a larger volume but the total amount of color remains the same.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free