\begin{aligned} &\text { How many } \alpha-\text { and } \beta \text { -particles will be emitted when }{ }_{90} \mathrm{Th}^{232} \text { changes }\\\ &\text { into }{ }_{82} \mathrm{~Pb}^{208} \text { ? } \end{aligned}

Short Answer

Expert verified
Th-232 will emit 6 \( \alpha \) particles and 4 \( \beta \) particles to become Pb-208.

Step by step solution

01

Understand the nuclear reaction

Recognize that the transformation of an element into another through radioactive decay can involve the emission of \( \alpha \) particles (which are helium nuclei, equivalent to the loss of 2 protons and 2 neutrons, or a decrease in atomic mass by 4 units and atomic number by 2 units) and \( \beta \) particles (which are electrons, resulting in the conversion of a neutron into a proton, thus increasing the atomic number by 1 unit without changing the atomic mass).
02

Determine the change in atomic number

Calculate the change in atomic number from Thorium (Th) to Lead (Pb) to determine the number of \( \alpha \) particles emitted. The original atomic number of Th is 90, and it changes to Pb with an atomic number of 82, thus \( 90 - 82 = 8 \) \( \alpha \) particles must have been emitted, as each \( \alpha \) emission decreases the atomic number by 2.
03

Determine the change in atomic mass

Calculate the change in atomic mass to determine the number of \( \alpha \) and \( \beta \) particles emitted. The original mass number of Th is 232, and it turns into Pb with a mass number of 208, thus \( 232 - 208 = 24 \) units of mass have been lost. Since each \( \alpha \) particle emission decreases the mass number by 4 units, the 8 \( \alpha \) particles account for a decrease of \( 8 \times 4 = 32 \) units. This discrepancy suggests a mistake in the calculation because we can only lose 24 units of mass, not 32. Therefore, no additional \( \beta \) particles can account for a decrease in the mass number; instead, they can only alter the atomic number without affecting it.
04

Correct the number of alpha particles emitted

To resolve the discrepancy from Step 3, we subtract the change in mass (24 units) from the loss incorrectly attributed to \( \alpha \) particles (32 units) to find the number of \( \alpha \) particles actually emitted. \( 32 - 24 = 8 \) units of mass are 'extra', meaning 2 \( \alpha \) particles were counted that should not have been. Each \( \alpha \) particle accounts for 4 units of mass, so \( 8 / 4 = 2 \) \( \alpha \) particles must be subtracted from the previously calculated number. 8 (initially calculated) - 2 (correction) = 6 \( \alpha \) particles actually emitted.
05

Determine the number of beta particles emitted

Since \( \alpha \) particles have accounted for the atomic mass change, \( \beta \) particles will only affect the atomic number. For every \( \alpha \) particle emitted, the atomic number is reduced by 2. With 6 \( \alpha \) particles emitted, the atomic number is effectively reduced by \( 6 \times 2 = 12 \) units. But the difference between the atomic numbers of Th and Pb is only 8 units. This means 4 excess protons have been created, which must have been a result of \( \beta^- \) decay (a neutron turning into a proton and emitting a \( \beta \) particle), indicating the emission of 4 \( \beta \) particles.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Alpha Particle Emission
The concept of alpha particle emission is pivotal in understanding many nuclear reactions, including radioactive decay processes. An alpha particle is essentially a helium nucleus composed of two protons and two neutrons, which makes it a hefty particle with a substantial impact on the atomic mass and atomic number of the decaying nucleus.

When an unstable nucleus emits an alpha particle, there is a significant change in its composition: the atomic mass decreases by four units since the emitted alpha particle carries away two protons and two neutrons, and the atomic number decreases by two because it is defined by the number of protons in the nucleus. These changes transform the original element into a new one.

In our exercise example, each emission of an alpha particle by Thorium-232 results in a stepwise approach towards becoming the more stable Lead-208. It's a balancing act between mass and charge that leads to the eventual stabilization of the nucleus.
Beta Particle Emission
Beta particle emission is another form of radioactive decay, where the emitted particle is an electron in the case of beta-minus decay, or a positron in beta-plus decay. Specifically, in beta-minus decay, a neutron is transformed into a proton with the accompanying release of an electron, which is the beta particle, and an antineutrino. Conversely, in beta-plus decay, a proton is converted into a neutron with the emission of a positron and a neutrino.

The key characteristic of beta decay is that it alters the atomic number of the nucleus—the count of protons—without affecting the atomic mass, since the mass of an electron or positron is negligible compared to the nucleus. This means that beta emission can change one chemical element into another by changing the number of protons while maintaining the same mass number.

Incorporating this into our exercise, it's clear that beta emissions are necessary to account for changes in atomic number without the reduction of atomic mass, as occurs in the latter stages of the Thorium to Lead transformation.
Nuclear Reaction Analysis
Nuclear reaction analysis is a sophisticated method used to ascertain the sequence of events in a nuclear transformation. By meticulously calculating the changes in atomic mass and atomic number during decay processes, scientists can deduce the types and quantities of particles emitted. This deduction follows strict rules of conservation; both the total mass and charge must be conserved in the process.

To approach a nuclear reaction analytically, you must first become knowledgeable about different types of decay and understand the significance of the atomic mass and atomic number in describing the characteristics of an element. The analysis often involves a step-by-step sequence of logical calculations, highlighting the importance of accurate bookkeeping in terms of mass and proton count.

In educational settings, such as the IIT-JEE problem solving, this analysis is critical. It necessitates a comprehensive understanding and careful calculation, especially when numbers seem not to tally. The ability to identify and rectify discrepancies, such as in our exercise example, is a quintessential skill developed through practice.
IIT-JEE Chemistry Problems
Preparing for competitive exams like the Indian Institutes of Technology Joint Entrance Examination (IIT-JEE) involves tackling complex chemistry problems, including those on nuclear chemistry and radioactive decay. Highly challenging, these problems require a deep comprehension of underlying principles, the ability to apply concepts to novel situations, and high accuracy in numerical calculations.

Students are expected to navigate through intricate problems such as the calculation of alpha and beta particle emissions during nuclear decay, which not only test their understanding of the subject matter but also their problem-solving skills and attention to detail. Missteps in calculation can undermine the entire solution, stressing the importance of each step in the process.

Illustrating this, the textbook solution we’ve expounded upon serves as an essence of these complexities. It demonstrates the calibration required between theory and application, the precision demanded in numerical analysis, and the systematic troubleshooting needed when discrepancies arise—skills that are paramount for success in the IIT-JEE Chemistry examination.

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