Chapter 5: Problem 3
$$ \begin{aligned} &\text { Point out the oxidation number of } \mathrm{C} \text { in the following : }\\\ &\mathrm{CH}_{4}, \mathrm{C}_{3} \mathrm{H}_{8}, \mathrm{C}_{2} \mathrm{H}_{6}, \mathrm{C}_{4} \mathrm{H}_{10}, \mathrm{CO}, \mathrm{CO}_{2} \text { and } \mathrm{HCO}_{3}^{-}, \mathrm{CO}_{3}^{2-} \end{aligned} $$
Short Answer
Step by step solution
Understanding Oxidation Numbers
Assigning Oxidation Numbers for Hydrogen and Oxygen
Determining the Oxidation Number of Carbon in CH4
Determining the Oxidation Number of Carbon in C3H8
Determining the Oxidation Number of Carbon in C2H6
Determining the Oxidation Number of Carbon in C4H10
Determining the Oxidation Number of Carbon in CO
Determining the Oxidation Number of Carbon in CO2
Determining the Oxidation Number of Carbon in HCO3-
Determining the Oxidation Number of Carbon in CO32-
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation States
When determining the oxidation state of an atom, certain rules are applied consistently. For instance, the oxidation number of a pure element is always 0, and for monoatomic ions, it is equal to the ion's charge. In compounds, hydrogen typically has an oxidation number of +1, and oxygen normally has an oxidation number of -2, with some exceptions, such as in peroxides. The sum of oxidation states for all atoms in a molecule or ion must equal the overall charge of that species.
Compound Nomenclature
Naming ions involves similar methods: anions typically end in '-ide', while polyatomic ions have unique names, such as the bicarbonate (HCO3-) and carbonate (CO32-) ions mentioned in the provided exercise. The prefixes and suffixes are essential clues to the composition and structure of the compounds, an essential aspect of effective chemical communication.
Balancing Charges
For instance, in the bicarbonate ion (HCO3-), the positive and negative charges must add up to -1. Similarly, in methane (CH4), carbon has a -4 oxidation state to neutralize the +1 oxidation states of the four hydrogen atoms. Understanding how to balance charges enables chemists to predict the formulas of compounds formed and to balance chemical equations for reactions.
Redox Chemistry
Redox reactions consist of two complementary processes: reduction (gain of electrons, leading to a decrease in oxidation state) and oxidation (loss of electrons, leading to an increase in oxidation state). For a redox process to occur, there must be a transfer of electrons from the reducing agent to the oxidizing agent. The action of assigning oxidation numbers, as demonstrated in the provided exercise, is a preliminary step to identifying redox reactions and understanding the electron transfer that occurs during these chemical processes.