Chapter 9: Problem 21
In a reaction; \(2 A \longrightarrow\) Products, the concentration of \(A\) decreases from \(0.5\) mol litre \(^{-1}\) to \(0.4\) mol litre \(^{-1}\) in 10 minutes. Calculate rate during this interval.
Short Answer
Expert verified
The average rate of reaction is \( -1.67 \times 10^{-4} \) mol litre^{-1} s^{-1}.
Step by step solution
01
Identify the Change in Concentration
Determine the initial and final concentrations of reactant A. The initial concentration is given as 0.5 mol litre^{-1}, and the final concentration after 10 minutes is 0.4 mol litre^{-1}. The change in concentration, \(\Delta[A]\), is the final concentration subtracted from the initial concentration.
02
Calculate the Change in Concentration
Subtract the final concentration of A from the initial concentration to get the change in concentration: \(\Delta[A] = [A]_{initial} - [A]_{final} = 0.5 - 0.4 = 0.1\) mol litre^{-1}.
03
Identify the Change in Time
The time interval during which the concentration changes is given as 10 minutes. We can denote this as \(\Delta t = 10\) minutes. To use consistent units, we can convert the time to seconds, knowing that 1 minute equals 60 seconds. Therefore, \(\Delta t = 10 \times 60 = 600\) seconds.
04
Calculate the Average Rate of Reaction
Use the formula for rate of reaction, which is the change in concentration over the change in time, rate = \(\frac{\Delta[A]}{\Delta t}\). Plug in the values calculated in steps 2 and 3 to find the average rate of reaction during the 10-minute interval.
05
Express the Rate with Proper Sign
Since this is a reaction involving the consumption of A, the rate will be negative, indicating a decrease in concentration over time. \(rate = -\frac{0.1}{600}\) mol litre^{-1} s^{-1}.
06
Simplify the Rate Expression
Calculate the numerical value of the rate: \(rate = -\frac{0.1}{600} = -\frac{1}{6000}\) or approximately \(rate = -1.67 \times 10^{-4}\) mol litre^{-1} s^{-1}.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Understanding Chemical Kinetics
Chemical kinetics is the study of the rates of chemical processes and the factors affecting those rates. It's central to predicting how reactions occur and can tell us not just the speed of a chemical reaction, but also how various conditions can influence this speed. This field of chemistry plays a critical role in everything from creating new medicines to understanding environmental processes.
In the calculation example, we witness chemical kinetics in action. We start by identifying the change in concentration of reactant A. A foundational concept here is that the rate of reaction is proportional to the concentration of the reactants, as per the law of mass action. The change in concentration over time gives us insight into the reaction speed. By knowing this, one can design experiments and analyze the effects of concentration, temperature, or catalysts on the rate of a reaction.
In the calculation example, we witness chemical kinetics in action. We start by identifying the change in concentration of reactant A. A foundational concept here is that the rate of reaction is proportional to the concentration of the reactants, as per the law of mass action. The change in concentration over time gives us insight into the reaction speed. By knowing this, one can design experiments and analyze the effects of concentration, temperature, or catalysts on the rate of a reaction.
Analyzing Concentration Change Over Time
The concentration change over time is key to understanding reaction dynamics. In our example, we see the concentration of A decrease from 0.5 to 0.4 mol litre-1 over a span of 10 minutes. This change is crucial to calculate the rate of reaction.
Considering reaction rates are determined by the changes in concentration of reactants (or products), knowing how to measure this change accurately is imperative. A proper calculation involves accurate measurements and unit consistency.
Considering reaction rates are determined by the changes in concentration of reactants (or products), knowing how to measure this change accurately is imperative. A proper calculation involves accurate measurements and unit consistency.
Relative Change and Reaction Progress
It's also important to appreciate the relative change; in the given problem, a 20% decrease in concentration signifies a significant step toward the reaction completion. Understanding the quantitative dynamics assists in grasping the 'bigger picture' of chemical reactions.Determining the Reactant Consumption Rate
The reactant consumption rate is a measure that tells us how quickly a reactant is being used up in a reaction. It's generally expressed with a negative sign, which indicates a decrease in the reactant's concentration over time.
From our calculation example, the rate was determined to be -1.67 x 10-4 mol litre-1 s-1, which quantitatively describes the speed at which reactant A is consumed. This rate is critical for designing chemical processes, predicting the duration of reactions, and scaling up laboratory reactions to industrial production.
From our calculation example, the rate was determined to be -1.67 x 10-4 mol litre-1 s-1, which quantitatively describes the speed at which reactant A is consumed. This rate is critical for designing chemical processes, predicting the duration of reactions, and scaling up laboratory reactions to industrial production.