Chapter 10: Problem 18
1,1 -dibromoethane when heated with zinc dust produces (a) Ethyl bromide (b) Ethene (c) Vinyl bromide (d) 2 -butene
Short Answer
Expert verified
When 1,1-dibromoethane is heated with zinc dust, it produces ethene (option b).
Step by step solution
01
Understanding the Reaction
1,1-dibromoethane is an alkyl dihalide where both bromine atoms are attached to the same carbon atom. When heated with zinc dust, a chemical reaction known as dehalogenation occurs, where both bromine atoms are removed from the alkyl dihalide.
02
Predicting the Product
Through the dehalogenation process, zinc removes both halogen atoms as ZnBr2, which leads to the formation of a carbon-carbon double bond between the carbon atoms that were originally bonded to the bromine atoms.
03
Determining the Structure of the Product
After the elimination of the bromine atoms, the remaining carbon atoms form a double bond to create ethene (also known as ethylene), which is the simplest alkene.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
1,1-Dibromoethane
1,1-Dibromoethane is an organic compound categorized as a vicinal dihalide, consisting of two bromine atoms attached to the same carbon atom in an ethane molecule. In organic chemistry, such compounds are common substrates in elimination reactions. An elimination reaction involves the removal of two substituents from a molecule, leading to the formation of a multiple bond. In the context of a dehalogenation reaction, the removal of the two bromine atoms from 1,1-dibromoethane introduces a double bond, converting the saturated hydrocarbon into an unsaturated one - specifically, an alkene.
This transformation is particularly relevant for students, as understanding the reactivity and properties of halogenated hydrocarbons like 1,1-dibromoethane forms a fundamental part of organic chemistry curricula, and it often serves as a practical example of a chemical transformation principle.
This transformation is particularly relevant for students, as understanding the reactivity and properties of halogenated hydrocarbons like 1,1-dibromoethane forms a fundamental part of organic chemistry curricula, and it often serves as a practical example of a chemical transformation principle.
Zinc Dust
Zinc dust is a finely powdered form of zinc metal that is commonly used in various chemical reactions as a reducing agent. In the dehalogenation of 1,1-dibromoethane, zinc dust plays a pivotal role by inducing the elimination of bromine atoms. The zinc effectively 'pairs up' with the bromine atoms, forming zinc bromide (ZnBr2), and simultaneously facilitating the formation of a new bond between the carbons.
When discussing reduction and oxidation reactions in organic chemistry, it's essential to note that these reactions can change the oxidation state of different atoms within a molecule. Zinc, being more electropositive, persuades halogens like bromine to sever connections with their carbon hosts, thus driving the reaction towards alkene formation.
When discussing reduction and oxidation reactions in organic chemistry, it's essential to note that these reactions can change the oxidation state of different atoms within a molecule. Zinc, being more electropositive, persuades halogens like bromine to sever connections with their carbon hosts, thus driving the reaction towards alkene formation.
Alkene Formation
Alkene formation is central to a multitude of reactions in organic chemistry. Alkenes are hydrocarbons characterized by at least one carbon-carbon double bond and are typically formed through elimination reactions. In the scenario with 1,1-dibromoethane and zinc dust, the reaction is a dehalogenation because it eliminates halogen atoms from the molecule.
Consequently, the direct outcome of the reaction is ethene, the simplest alkene with the molecular formula C2H4. This illustrates an important characteristic of alkenes: their ability to be synthesized from saturated hydrocarbons by removing specific atoms or groups, leading to unsaturation. Studying these transformation processes helps students comprehend how to synthesize different organic compounds through various reaction pathways.
Consequently, the direct outcome of the reaction is ethene, the simplest alkene with the molecular formula C2H4. This illustrates an important characteristic of alkenes: their ability to be synthesized from saturated hydrocarbons by removing specific atoms or groups, leading to unsaturation. Studying these transformation processes helps students comprehend how to synthesize different organic compounds through various reaction pathways.
Organic Chemistry Reactions
Dehalogenation is just one example of the myriad reactions studied in organic chemistry, a branch focused on carbon-containing compounds. Organic reactions are typically categorized by the changes occurring to the skeleton of the compound and the functional groups involved. For example, addition reactions include new groups joining a molecule, substitution reactions involve exchanging parts of the molecule, and elimination reactions such as dehalogenation result in the removal of elements from the molecule.
The reactions feature mechanisms that detail the step-by-step process by which reactants convert to products. Understanding these underlying principles is crucial for students, as it not only aids in prediction of the outcomes of organic reactions but also underpins the synthesis and manipulation of organic molecules in practical applications, ranging from medicinal chemistry to material sciences.
The reactions feature mechanisms that detail the step-by-step process by which reactants convert to products. Understanding these underlying principles is crucial for students, as it not only aids in prediction of the outcomes of organic reactions but also underpins the synthesis and manipulation of organic molecules in practical applications, ranging from medicinal chemistry to material sciences.
NEET Chemistry Preparation
When preparing for competitive exams like NEET, which serve as entry points to professions in fields like medicine, mastering the core concepts of chemistry is crucial. Organic chemistry, including reactions like dehalogenation, is often heavily tested in these exams. Aspiring students need to be familiar with various organic compounds, reaction mechanisms, and the conditions under which different reactions proceed.
Effective NEET chemistry preparation typically includes a thorough review of textbook solutions, practice problems, and conceptual clarity. Grasping the intricacies of reactions such as the one involving 1,1-dibromoethane and zinc dust ensures a strong understanding of the fundamental principles of organic chemistry, which is necessary for success in examinations like the NEET.
Effective NEET chemistry preparation typically includes a thorough review of textbook solutions, practice problems, and conceptual clarity. Grasping the intricacies of reactions such as the one involving 1,1-dibromoethane and zinc dust ensures a strong understanding of the fundamental principles of organic chemistry, which is necessary for success in examinations like the NEET.