Chapter 11: Problem 54
Ethylene reacts with \(1 \%\) cold alkaline \(\mathrm{KMnO}_{4}\) to form (a) Ethylene glycol (b) Oxalic acid (c) HCHO (d) Ethyl alcohol
Short Answer
Expert verified
Ethylene reacts with dilute, cold alkaline (KMnO4) to form ethylene glycol (a).
Step by step solution
01
Understand the reaction condition
Ethylene is reacting with a dilute, cold solution of potassium permanganate (KMnO4) in an alkaline medium. This reaction condition suggests an oxidation reaction that is mild and does not lead to complete oxidation.
02
Identify the product from the given options
In a dilute, cold, alkaline (KMnO4) environment, ethylene (a double-bonded carbon compound) will undergo dioxygenation, adding two hydroxyl (-OH) groups across the double bond. This results in the formation of ethylene glycol, a glycol with two -OH groups on adjacent carbon atoms.
03
Eliminate other options
The other options can be eliminated because oxalic acid and HCHO (formaldehyde) represent further oxidation products that would require harsher conditions, and ethyl alcohol is not a product of direct oxidation of a double bond by (KMnO4).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
KMnO4 Characteristics
Potassium permanganate, commonly denoted as (KMnO4), is a powerful oxidizing agent used widely in chemistry, both in the laboratory and industrially. Its vivid purple crystals are highly recognizable and soluble in water, producing a purple, pink, or faintly magenta solution, depending on the concentration. One hallmark of (KMnO4) is its ability to oxidize a variety of organic compounds in different conditions. It can be used in acidic, neutral, or alkaline media, and the reaction outcomes vary accordingly. In acidic conditions, it can produce (Mn^{2+}) while in neutral or slightly alkaline solutions, it often yields (MnO2).
In the context of the ethylene oxidation reaction, a cold and dilute solution of (KMnO4) in an alkaline medium is known for causing gentle oxidation. This is crucial for selectively forming desired products without degrading them through overoxidation. Students can observe a color change from purple to brown or colorless, indicating the consumption of (KMnO4) during the reaction -- a visual cue that's helpful during titrations or when monitoring the progress of an experiment.
In the context of the ethylene oxidation reaction, a cold and dilute solution of (KMnO4) in an alkaline medium is known for causing gentle oxidation. This is crucial for selectively forming desired products without degrading them through overoxidation. Students can observe a color change from purple to brown or colorless, indicating the consumption of (KMnO4) during the reaction -- a visual cue that's helpful during titrations or when monitoring the progress of an experiment.
Oxidation Reactions in Organic Chemistry
Oxidation in organic chemistry involves the increase in the oxygen content or decrease in the hydrogen content of a molecule. These reactions are pivotal in creating various functional groups that define the chemical properties of organic compounds. Alkenes, like ethylene, are particularly prone to oxidation due to the presence of a double bond, which is a reactive site for adding oxygen atoms or removing hydrogen atoms.
The ethylene oxidation reaction with (KMnO4) showcases a typical organic oxidation process where the alkene is transformed into a glycol. The term 'gentle' or 'mild' oxidation is used when the conditions (typically temperature and concentration) are controlled to limit the reaction to a specific stage. This is crucial in synthetic chemistry where the goal is to obtain a desired intermediate without proceeding to complete oxidation, which in the case of ethylene could result in compounds like oxalic acid or carbon dioxide under harsh conditions.
The ethylene oxidation reaction with (KMnO4) showcases a typical organic oxidation process where the alkene is transformed into a glycol. The term 'gentle' or 'mild' oxidation is used when the conditions (typically temperature and concentration) are controlled to limit the reaction to a specific stage. This is crucial in synthetic chemistry where the goal is to obtain a desired intermediate without proceeding to complete oxidation, which in the case of ethylene could result in compounds like oxalic acid or carbon dioxide under harsh conditions.
Chemistry for NEET
The National Eligibility cum Entrance Test (NEET) is a significant pre-medical exam in India for students who wish to enter medical fields. The chemistry section of NEET tests a student's understanding of chemical concepts that are foundational to the health sciences. It includes a broad range of topics from inorganic, organic, and physical chemistry.
Understanding the characteristics of (KMnO4) and its role in oxidation reactions is key for NEET aspirants, as these principles are often tested. Recognizing reaction conditions, predicting products, and identifying reaction types are skills that directly apply to NEET chemistry problems. Practicing with reactions like the mild oxidation of ethylene can provide NEET students with insight into how reactants are transformed into different molecular structures and the role of specific reagents, such as (KMnO4), in driving these chemical changes. Moreover, a grasp of oxidation mechanisms and the outcomes of varying reaction conditions will bolster a student's problem-solving abilities, directly contributing to their performance on the exam.
Understanding the characteristics of (KMnO4) and its role in oxidation reactions is key for NEET aspirants, as these principles are often tested. Recognizing reaction conditions, predicting products, and identifying reaction types are skills that directly apply to NEET chemistry problems. Practicing with reactions like the mild oxidation of ethylene can provide NEET students with insight into how reactants are transformed into different molecular structures and the role of specific reagents, such as (KMnO4), in driving these chemical changes. Moreover, a grasp of oxidation mechanisms and the outcomes of varying reaction conditions will bolster a student's problem-solving abilities, directly contributing to their performance on the exam.