Chapter 16: Problem 13
The substance used in the preparation of malachite green is: (a) Benzaldehyde (b) Acetone (c) Formaldehyde (d) Acetaldehyde
Short Answer
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The substance used in the preparation of malachite green is (a) Benzaldehyde.
Step by step solution
01
Identify the chemical used in malachite green synthesis
Malachite green is a triphenylmethane dye. Its synthesis involves the condensation of benzaldehyde and dimethylaniline in the presence of an acid. The correct substance used is benzaldehyde.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Benzaldehyde
Benzaldehyde is an organic compound that plays a crucial role in the synthesis of various chemicals, including dyes, perfumes, and pharmaceuticals. It's known for its distinctive almond-like odor and is the primary component of bitter almond oil. In the context of producing malachite green, benzaldehyde acts as one of the starting materials. To understand its role, one should be aware that benzaldehyde has a benzene ring linked to an aldehyde group. This structure makes it highly reactive in condensation reactions, which are fundamental to synthesizing triphenylmethane dyes.
For instance, in the condensation reaction to make malachite green, benzaldehyde provides the necessary carbon framework that will form part of the dye's structure. It reacts with dimethylaniline, with the aldehyde group playing a key role in facilitating the formation of new bonds during the synthesis. It's this very chemical behavior that underscores the importance of benzaldehyde not only in the creation of malachite green but also in a vast array of organic reactions.
For instance, in the condensation reaction to make malachite green, benzaldehyde provides the necessary carbon framework that will form part of the dye's structure. It reacts with dimethylaniline, with the aldehyde group playing a key role in facilitating the formation of new bonds during the synthesis. It's this very chemical behavior that underscores the importance of benzaldehyde not only in the creation of malachite green but also in a vast array of organic reactions.
Importance in Dye Synthesis
In dye production, the reactivity of the aldehyde group allows for the formation of complex molecules that exhibit the vibrant colors needed. In teaching the concept, emphasizing the role of functional groups in organic chemistry is beneficial, as students can better understand how different compounds interact based on their structural features.Triphenylmethane Dye
Triphenylmethane dyes are a class of organic compounds known for their brilliant colors and their application in diverse fields ranging from textile manufacturing to biological staining. Malachite green is one of the prominent members of this family. To study these dyes, one must be familiar with their general structure—an aromatic central carbon atom bonded to three phenyl groups.
The synthesis of triphenylmethane dyes typically involves the formation of carbon-carbon bonds between aromatic compounds, such as benzaldehyde, and amine compounds like dimethylaniline. The reaction often requires an acidic catalyst, which helps stabilize intermediates and facilitate the reaction's progress. Malachite green synthesis can be seen as a prime example of how triphenylmethane dyes are created using such chemical processes.
The synthesis of triphenylmethane dyes typically involves the formation of carbon-carbon bonds between aromatic compounds, such as benzaldehyde, and amine compounds like dimethylaniline. The reaction often requires an acidic catalyst, which helps stabilize intermediates and facilitate the reaction's progress. Malachite green synthesis can be seen as a prime example of how triphenylmethane dyes are created using such chemical processes.
Color Formation Mechanism
The intense color of triphenylmethane dyes is due to the extensive conjugated system of double bonds within their chemical structure. When light interacts with these molecules, certain wavelengths are absorbed, and the remaining light reflected is what we perceive as the dye's color. Understanding the electronic structure and how it relates to color is essential in chemistry education, as it bridges the gap between the molecular level and the observed properties.Organic Chemistry
Organic chemistry is the area of chemistry that focuses on the study of carbon-containing compounds and their reactions. It is the foundation upon which the synthesis of malachite green, as well as myriad other synthetic processes, is built. Organic molecules can be complex, with a variety of functional groups that dictate how they react with other substances. In the synthesis of dyes, pharmaceuticals, plastics, and more, understanding organic reactions and mechanisms is crucial.
Take the malachite green synthesis as an example; it involves concepts such as nucleophilic addition, catalysis, and electrophilic aromatic substitution. These reactions are bread and butter for organic chemists, as they explain how molecules come together to form new compounds with new properties. The synthesis serves as a practical application of these reactions—showcasing the importance of knowing not only what functional groups are present in a molecule but also how they behave under reaction conditions.
Take the malachite green synthesis as an example; it involves concepts such as nucleophilic addition, catalysis, and electrophilic aromatic substitution. These reactions are bread and butter for organic chemists, as they explain how molecules come together to form new compounds with new properties. The synthesis serves as a practical application of these reactions—showcasing the importance of knowing not only what functional groups are present in a molecule but also how they behave under reaction conditions.