In the following reaction: \(\mathrm{Cr}(\mathrm{OH})_{3}+\mathrm{OH}^{-}+\mathrm{IO}_{3} \longrightarrow \mathrm{CrO}_{4}^{2-}+\mathrm{H}_{2} \mathrm{O}+\mathrm{I}^{-}\) (a) \(\mathrm{IO}_{3}^{-}\) is oxidizing agent (b) \(\mathrm{Cr}(\mathrm{OH})_{3}\) is oxidized (c) \(6 \mathrm{e}^{-}\) are being taken per \(\mathrm{l}\) atom (d) All are true

Short Answer

Expert verified
(d) All are true.

Step by step solution

01

Identify the Oxidizing and Reducing Agents

An oxidizing agent is a substance that gains electrons in a chemical reaction and is reduced. A reducing agent is a substance that loses electrons and is oxidized. To find the oxidizing and reducing agents, write down the half-reactions for oxidation and reduction.
02

Determine Oxidation States

Determine the oxidation states of iodine in \(\mathrm{IO}_{3}^{-}\) and chromium in \(\mathrm{Cr}(\text{OH})_{3}\) before and after the reaction to infer the changes in oxidation states that indicate oxidation and reduction.
03

Verify Transfer of Electrons

Use the change in oxidation states to identify how many electrons are lost by one substance and gained by another to confirm the total number of electrons transferred.
04

Assess Statements for Accuracy

Review each statement given in the exercise. For (a), confirm if \(\mathrm{IO}_{3}^{-}\) gains electrons, for (b), check if \(\mathrm{Cr}(\text{OH})_{3}\) loses electrons, and for (c), determine the exact number of electrons exchanged per iodine atom. If these corroborate with the determined half-reactions, validate whether (d) is true.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation and Reduction
Understanding oxidation and reduction is crucial when studying redox reactions in chemistry. Oxidation is the process where an atom, ion, or molecule loses electrons, resulting in an increase in its oxidation state. Conversely, reduction involves the gain of electrons, leading to a decrease in the oxidation state.

These processes always occur together; when one species is oxidized, another is reduced. This pairing is also referred to as a redox reaction, which stands for reduction-oxidation. To easily remember this concept, think of the mnemonic 'OIL RIG': Oxidation Is Loss, Reduction Is Gain of electrons.
Identifying Oxidizing and Reducing Agents
In a redox reaction, oxidizing and reducing agents are key players in the transfer of electrons. An oxidizing agent, or oxidant, accepts electrons and is reduced in the process. On the flip side, a reducing agent, or reductant, donates electrons and is oxidized. How do you spot them? Look for the substance that undergoes reduction (gain of electrons) to identify the oxidizing agent, and find the one that is oxidized (loss of electrons) to pinpoint the reducing agent.

In our exercise, \(\mathrm{IO}_{3}^{-}\) is acting as the oxidizing agent because it is being reduced, while \(\mathrm{Cr}(\mathrm{OH})_{3}\) is the reducing agent as it is being oxidized.
Determining Oxidation States
To accurately determine what is being oxidized or reduced in a redox reaction, you must first find the oxidation states of the atoms involved. Oxidation state, sometimes called oxidation number, is a value assigned to an atom in a compound representing the atom's degree of electron possession or deficiency, compared to the pure element.

For example, in the given reaction, chromium goes from an oxidation state in \(\mathrm{Cr}(\mathrm{OH})_{3}\) to a different state in \(\mathrm{CrO}_{4}^{2-}\). Similarly, the oxidation state of iodine changes from \(\mathrm{IO}_{3}^{-}\) to \(\mathrm{I}^{-}\), indicating the transfer of electrons and helping us assess which atoms are oxidized and reduced.
Electron Transfer in Chemical Reactions
Electron transfer is the backbone of redox chemistry. It's the literal movement of electrons from one atom or molecule (reducing agent) to another (oxidizing agent). The number of electrons transferred must be the same for both the oxidation and reduction to maintain electrical neutrality.

In the case of our exercise, each iodine atom in \(\mathrm{IO}_{3}^{-}\) receives a certain number of electrons to become \(\mathrm{I}^{-}\). The reaction shows that one chromium atom donates six electrons, confirming the answer in (c) of the exercise. These kinds of insights are fundamental for understanding the specifics of chemical reactions and for solving problems related to redox events.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Saturated solution of \(\mathrm{KNO}_{3}\) is used to make 'salt bridge' because: (a) Velocity of \(\mathrm{K}^{+}\) is greater than that of \(\mathrm{NO}_{3}^{-}\) (b) Velocity of \(\mathrm{NO}_{3}\) is greater than that of \(\mathrm{K}^{+}\) (c) Velocities of both \(\mathrm{K}^{+}\) and \(\mathrm{NO}_{3}^{-}\) are nearly the same (d) \(\mathrm{KNO}_{3}\) is highly soluble in water

The standard reduction potentials of \(\mathrm{Ag}, \mathrm{Cu}, \mathrm{Co}\) and \(\mathrm{Zn}\) are \(0.799,0.337,-0.277\) and \(-0.762 \mathrm{~V}\) respectively. Which of the following cells will have maximum cell emf? (a) \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{IM})\right|\left|\mathrm{Cu}^{2+}(1 \mathrm{M})\right| \mathrm{Cu}\) (b) \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{lM}) \| \mathrm{Ag}^{+}(\mathrm{lM})\right| \mathrm{Ag}\) (c) \(\mathrm{Cu}\left|\mathrm{Cu}^{2+}(\mathrm{lM}) \| \mathrm{Ag}^{+}(\mathrm{lM})\right| \mathrm{Ag}\) (d) \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{IM})\right| \mathrm{Co}^{2+}(\mathrm{IM}) \mid \mathrm{Co}\)

A solution of sodium sulphate in water is electrolyzed using inert electrodes. The products at the cathode and anode are respectively: (a) \(\mathrm{O}_{2}, \mathrm{H}_{2}\) (b) \(\mathrm{O}_{2}, \mathrm{Na}\) (c) \(\mathrm{O}_{2}, \mathrm{SO}_{2}\) (d) \(\mathrm{H}_{2}, \mathrm{O}_{2}\)

A certain current liberates \(0.504 \mathrm{~g}\) of hydrogen in 2 hour. The amount (or mass) of copper deposited at the cathode during the electrolysis of \(\mathrm{CuSO}_{4}\) (aq) solution by the same current flowing for the same time is (atomic masses \(\mathrm{H}=1.0, \mathrm{Cu}=63.5\) ): (a) \(16.0 \mathrm{~g}\) (b) \(32.0 \mathrm{~g}\) (c) \(8.6 \mathrm{~g}\) (d) \(1.60 \mathrm{~g}\)

When white phosphorus reacts with caustic soda, the products are \(\mathrm{PH}_{3}\) and \(\mathrm{NaH}_{2} \mathrm{PO}_{2} .\) This reaction is an example of: (a) Oxidation (b) Reduction (c) Disproportionation (d) Neutralization

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free