Chapter 7: Problem 85
The number of \(\mathrm{P}-\mathrm{O}-\mathrm{P}\) and \(\mathrm{P}-\mathrm{O}-\mathrm{H}\) bonds present respectively in pyrophosphoric acid molecule are (a) 2,2 (b) 1,8 (c) 1,2 (d) 1,4
Short Answer
Expert verified
The number of \(P-O-P\) and \(P-O-H\) bonds in a pyrophosphoric acid molecule are 1 and 4, respectively, so the correct answer is (d) 1,4.
Step by step solution
01
Understanding the Structure of Pyrophosphoric Acid
Pyrophosphoric acid, also known as diphosphoric acid, has the chemical formula \(H_4P_2O_7\). It is composed of two phosphorus atoms, each bonded to four oxygen atoms, and four hydrogens are present as \(OH\) groups. One oxygen is shared between the two phosphorus atoms, forming a \(P-O-P\) linkage.
02
Counting the \(P-O-P\) Bonds
In the structure of pyrophosphoric acid, there is only one \(P-O-P\) bond, this is the bond that connects the two phosphorus atoms.
03
Counting the \(P-O-H\) Bonds
Since there are four hydroxyl groups (\(OH\)) in the molecule, each phosphorus atom will be bonded to two \(OH\) groups. This results in a total of four \(P-O-H\) bonds in the molecule.
04
Determining the Correct Option
By analyzing the structure and counting the specific bonds, we conclude that there is one \(P-O-P\) bond and four \(P-O-H\) bonds. Therefore, the correct answer is (d) 1,4.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
P-O-P Bonds in Pyrophosphoric Acid
In chemistry, understanding bond structures is quintessential for grasping how molecules behave and interact. For pyrophosphoric acid, the P-O-P bond plays a critical role in its structure. The molecule is composed of two phosphorus (P) atoms connected by a bridge - an oxygen (O) atom - forming a pivotal P-O-P bond. This bond is a linkage between the central atoms of the molecule. This structure is significant as it imparts stability and influences the acid's chemical reactivity and properties.
When visualizing the P-O-P bond, imagine two clusters, each containing a phosphorus atom at the center surrounded by oxygen atoms. One oxygen serves as the link by sharing one electron with each phosphorus atom, forming a bond that holds the entire structure together in a stable formation. Despite the complexity of pyrophosphoric acid's overall structure, there's only one P-O-P bond present. This understanding is crucial for students attempting to comprehend the molecule and its reactions with other substances.
When visualizing the P-O-P bond, imagine two clusters, each containing a phosphorus atom at the center surrounded by oxygen atoms. One oxygen serves as the link by sharing one electron with each phosphorus atom, forming a bond that holds the entire structure together in a stable formation. Despite the complexity of pyrophosphoric acid's overall structure, there's only one P-O-P bond present. This understanding is crucial for students attempting to comprehend the molecule and its reactions with other substances.
P-O-H Bonds in Pyrophosphoric Acid
Moving beyond the central P-O-P bond, pyrophosphoric acid also features P-O-H bonds—specifically, four of them. Each P-O-H bond comprises a phosphorus atom single-bonded to an oxygen atom, which is in turn bonded to a hydrogen atom, denoted as the hydroxyl group (OH). In pyrophosphoric acid, each phosphorus atom is attached to two of these hydroxyl groups, resulting in a total of four P-O-H bonds.
Recognizing these bonds is vital for understanding the behavior of pyrophosphoric acid in different chemical contexts, including its role as a condensing agent in organic synthesis and its contribution to the biochemistry of life.
- The presence of the hydroxyl groups directly influences the acid's solubility and its ability to donate protons (H+ ions), which is essential for classifying it as an acid.
- It is the P-O-H bonds that allow the molecule to exhibit its acidic properties when dissolved in water.
- Furthermore, these bonds are important for intermolecular interactions and the formation of hydrogen bonds, which affect the compound’s physical properties such as boiling point and viscosity.
Recognizing these bonds is vital for understanding the behavior of pyrophosphoric acid in different chemical contexts, including its role as a condensing agent in organic synthesis and its contribution to the biochemistry of life.
Chemical Formula of Pyrophosphoric Acid
One of the most fundamental pieces of information in chemistry is the chemical formula, which provides a compact representation of the components and structure of a compound. Pyrophosphoric acid has the chemical formula of \( H_4P_2O_7 \). This formula indicates that each molecule contains four hydrogen atoms, two phosphorus atoms, and seven oxygen atoms.
The chemical formula serves as a gateway to understanding the substance’s molecular geometry and the interactions between atoms. When deciphered, it shows us that:
For students delving into the world of inorganic chemistry, mastering the interpretation of chemical formulas like \( H_4P_2O_7 \) is fundamental for understanding not just pyrophosphoric acid, but a wide range of chemical compounds and their respective properties and applications.
The chemical formula serves as a gateway to understanding the substance’s molecular geometry and the interactions between atoms. When deciphered, it shows us that:
- There are two phosphorus atoms at the heart of pyrophosphoric acid's structure, around which the rest of the molecule is arranged.
- The quantity of oxygen atoms compared to hydrogen and phosphorus implies a dense, rich-in-oxygen environment within the molecule, leading to its acidic character.
- The subscript numbers help us perceive the proportion of atoms, which in turn allows us to predict the molecule's mass and how it might combine with other elements in chemical reactions.
For students delving into the world of inorganic chemistry, mastering the interpretation of chemical formulas like \( H_4P_2O_7 \) is fundamental for understanding not just pyrophosphoric acid, but a wide range of chemical compounds and their respective properties and applications.