Chapter 3: Problem 85
There are many elements in the periodic table which exhibit variable valency. This is a particular characteristic of (a) representative elements (b) transition elements (c) noble gases (d) non-metals.
Short Answer
Expert verified
Elements exhibiting variable valency are characteristic of (b) transition elements.
Step by step solution
01
Understanding Variable Valency
Variable valency refers to the ability of an element to exhibit more than one valency or oxidation state. This is due to the availability of d-orbitals that can participate in bonding apart from the s-orbital in the outermost energy level of the atom.
02
Identifying the Elements with Variable Valency
The transition elements, which are found in the d-block of the periodic table, are known for exhibiting variable valency as they have incomplete d-orbitals that can be involved in chemical bonding.
03
Eliminating Incorrect Options
Representative elements (main group elements), noble gases, and non-metals generally do not exhibit variable valency to the extent seen in transition elements. Noble gases have a complete valence shell and typically do not form compounds. Non-metals usually have more fixed valencies, and representative elements do not have the same access to d-orbitals for bonding as transition elements do.
04
Choosing the Correct Option
Based on the given options and the characteristic of having variable valency due to the availability of d-orbitals, the correct answer is (b) transition elements.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Transition Elements
When exploring the fascinating world of chemistry, one often encounters the term transition elements. These are a group of elements situated in the d-block of the periodic table. One of the most interesting aspects of transition elements is their variable valency, which means they can exhibit more than one valency or oxidation state. This flexibility in valency is primarily due to the presence of d-orbitals that are energetically accessible and capable of participation in the formation of chemical bonds.
The unique property of variable valency allows transition elements to form a myriad of compounds with diverse chemical and physical properties. This is particularly important for industrial applications, such as catalysts in chemical reactions, and the manufacturing of materials with specific characteristics. In addition, the ability of transition elements to form colorful compounds is due to the different oxidation states they can adopt, making them visually appealing in both practical uses and educational demonstrations.
As an improvement to understand these elements better, it's vital to delve into specific examples, such as iron, copper, and cobalt, which exhibit variable valencies in their compounds. For instance, iron can exist in oxidation states +2 and +3, copper in +1 and +2, while cobalt can be found in +2 and +3 states among others. Observing these elements in laboratory experiments can enhance the understanding of the concept for students.
The unique property of variable valency allows transition elements to form a myriad of compounds with diverse chemical and physical properties. This is particularly important for industrial applications, such as catalysts in chemical reactions, and the manufacturing of materials with specific characteristics. In addition, the ability of transition elements to form colorful compounds is due to the different oxidation states they can adopt, making them visually appealing in both practical uses and educational demonstrations.
As an improvement to understand these elements better, it's vital to delve into specific examples, such as iron, copper, and cobalt, which exhibit variable valencies in their compounds. For instance, iron can exist in oxidation states +2 and +3, copper in +1 and +2, while cobalt can be found in +2 and +3 states among others. Observing these elements in laboratory experiments can enhance the understanding of the concept for students.
Oxidation States
Diving deeper into the realm of chemistry, the oxidation states or oxidation numbers represent the degree of oxidation of an atom within a compound. Understanding oxidation states is not just about counting electrons; it's about recognizing the potential a chemical species has to engage in reactions, donate or accept electrons, and consequently undergo redox processes.
Transition elements are infamous for their variability in oxidation states, which stems from their ability to use the electrons in their d-orbitals for bonding. This results in numerous possible combinations, as electrons can be added to or removed from these orbitals during chemical reactions. In educational settings, it's often helpful to clarify this concept with visual aids, such as electron configuration diagrams, which can illustrate how different oxidation states are achieved.
For example, manganese, a transition element, can exhibit oxidation states ranging from +2 to +7, each having distinctive chemical reactivity and color when forming compounds. Educators should emphasize examples where variable oxidation states play a crucial role, such as in biological systems where transition metals often serve as enzymatic cofactors with specific oxidation states.
Transition elements are infamous for their variability in oxidation states, which stems from their ability to use the electrons in their d-orbitals for bonding. This results in numerous possible combinations, as electrons can be added to or removed from these orbitals during chemical reactions. In educational settings, it's often helpful to clarify this concept with visual aids, such as electron configuration diagrams, which can illustrate how different oxidation states are achieved.
For example, manganese, a transition element, can exhibit oxidation states ranging from +2 to +7, each having distinctive chemical reactivity and color when forming compounds. Educators should emphasize examples where variable oxidation states play a crucial role, such as in biological systems where transition metals often serve as enzymatic cofactors with specific oxidation states.
D-Block of the Periodic Table
The d-block of the periodic table is a central location for transition elements. It comprises groups 3 to 12 and is characterized by the progressive filling of d-orbital electrons across the period. A key point to remember is that the chemical properties of elements within the d-block are directly influenced by the configuration of these d-electrons.
Within the periodic table, the d-block can be seen as a bridge or a transition between the highly reactive s-block elements and the p-block elements, which have more variation in properties. The d-block is where the metallic characteristics of elements tend to become more pronounced along with an increase in densities and melting points. Educators can use periodic trends in the d-block such as these to help students plot and visualize how the properties change across the period and why.
For effective teaching, demonstrating the d-block's trends with practical experiments or interactive simulations can enhance comprehension. For instance, showing the varied magnetic properties or the catalytic behaviors of d-block elements in reactions could elucidate the textbook concepts and offer a real-world context to the theoretical knowledge.
Within the periodic table, the d-block can be seen as a bridge or a transition between the highly reactive s-block elements and the p-block elements, which have more variation in properties. The d-block is where the metallic characteristics of elements tend to become more pronounced along with an increase in densities and melting points. Educators can use periodic trends in the d-block such as these to help students plot and visualize how the properties change across the period and why.
For effective teaching, demonstrating the d-block's trends with practical experiments or interactive simulations can enhance comprehension. For instance, showing the varied magnetic properties or the catalytic behaviors of d-block elements in reactions could elucidate the textbook concepts and offer a real-world context to the theoretical knowledge.