Chapter 16: Problem 326
Explain how the following alcohols are named using the IUPAC system of nomenclature:
Chapter 16: Problem 326
Explain how the following alcohols are named using the IUPAC system of nomenclature:
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Get started for freePredict the products of hydroboration-oxidation of: (a) cis-2-phenyl-2-butene; (b) trans \(-2\) -phenyl-2-butene; (c) 1 -methylcyclohexene.
A naive graduate student attempted the preparation of \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CDBrCH}_{3}\) from \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CDOHCH}_{3}\) by heating the deuterio-alcohol with \(\mathrm{HBr}\) and \(\mathrm{H}_{2} \mathrm{SO}_{4}\). He obtained a product having the correct boiling point, but a careful examination of the spectral properties by his research director showed that the product was a mixture of \(\mathrm{CH}_{3} \mathrm{CHDCHBrCH}_{3}\) and \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CDBrCH}_{3}\). What happened?
Indicate how you would synthesize each of the following substances from the given organic starting materials and other necessary organic or inorganic reagents. Specify reagents and conditions. (b) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH}-\mathrm{CH}_{2} \mathrm{Br}\) from \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{COH}\) (c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C}\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHO}\) from \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{C}(\mathrm{OH}) \mathrm{CH}_{2} \mathrm{CH}_{3}\) (d) \(\mathrm{CH}_{3} \mathrm{OCH}_{2} \mathrm{CH}_{2} \mathrm{OCH}_{3}\) from ethylene
Predict the products of each precursor by the hydration of olefins method. (a) \(\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CH}_{2}\) (b) \(\mathrm{CH}_{2}=\mathrm{CH}_{2}\) Propylene Ethene
What are the various methods of preparing alcohols?
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