Show how the successive use of cation- and anionexchange resins could be used to remove sodium chloride from water.

Short Answer

Expert verified
To remove sodium chloride from water using cation- and anion-exchange resins, pass the solution through a cation-exchange resin first. The resin attracts and holds sodium ions (Na+), releasing an equivalent amount of hydrogen ions (H+) in exchange. Reaction: \(Na^+_{(aq)} + Resin^-H^+ \rightarrow Resin^-Na^+ + H^+_{(aq)}\) Then, pass the solution through an anion-exchange resin, which attracts and holds chloride ions (Cl-) and releases an equivalent amount of hydroxide ions (OH-) in exchange. Reaction: \(Cl^-_{(aq)} + Resin^+OH^- \rightarrow Resin^+Cl^- + OH^-_{(aq)}\) Finally, the hydrogen ions (H+) and hydroxide ions (OH-) present in the solution combine to form water (H2O), effectively removing sodium chloride and leaving purified water. Reaction: \(H^+_{(aq)} + OH^-_{(aq)} \rightarrow H_2O_{(l)}\)

Step by step solution

01

Understand Ion Exchange Resins

Ion exchange is a process where ions are exchanged between a solution and a solid (usually a resin). There are two types of ion exchange resins: cation-exchange resins which exchange positively charged ions (cations) and anion-exchange resins which exchange negatively charged ions (anions). In this case, we will be using both cation- and anion-exchange resins to remove sodium (Na+) and chloride (Cl-) ions, respectively, from a sodium chloride dissolved in water.
02

Cation-Exchange Resin

Cation exchange resins have negatively charged functional groups that can attract and hold positively charged ions. In our case, sodium ions (Na+) present in the sodium chloride solution will be attracted to the cation-exchange resin. The resin has a fixed negative charge and will release an equivalent amount of hydrogen ions (H+) in exchange for the sodium ions. This will result in the removal of sodium ions from the water and their replacement by hydrogen ions. Reaction: \(Na^+_{(aq)} + Resin^-H^+ \rightarrow Resin^-Na^+ + H^+_{(aq)}\)
03

Anion-Exchange Resin

Anion exchange resins have positively charged functional groups that can attract and hold negatively charged ions. In our case, chloride ions (Cl-) present in the sodium chloride solution will be attracted to the anion-exchange resin. The resin has a fixed positive charge and will release an equivalent amount of hydroxide ions (OH-) in exchange for the chloride ions. This will result in the removal of chloride ions from the water and their replacement by hydroxide ions. Reaction: \(Cl^-_{(aq)} + Resin^+OH^- \rightarrow Resin^+Cl^- + OH^-_{(aq)}\)
04

Formation of Water

After passing the solution through both the cation- and anion-exchange resins, the hydrogen ions (H+) and hydroxide ions (OH-) present in the solution will combine to form water (H2O), a neutral molecule. Reaction: \(H^+_{(aq)} + OH^-_{(aq)} \rightarrow H_2O_{(l)}\)
05

Removal of Sodium Chloride from Water

By using successive cation- and anion-exchange resins, the sodium chloride dissolved in the water is effectively removed. The sodium ions are replaced by hydrogen ions, and the chloride ions are replaced by hydroxide ions. As a result, the hydrogen and hydroxide ions combine to form neutral water molecules, leaving us with purified water free from sodium chloride.

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