Chapter 6: Problem 105
What is an alkene?
Chapter 6: Problem 105
What is an alkene?
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Get started for free(a) Indicate the direction of the net dipole moment for each of the dihaloethenes. (b) Would cis-2,3-dichloro-2-butane have a larger or smaller dipole moment than cis-1,2-dichloroethene? (c) Indicate the direction of the net dipolemoment of cis-1,2 dibromo-1,2-dichloroethene. Will it be larger or smaller than the dipole moment of cis-1,2-dichloroethene? Why?
Indicate how you would synthesize each of the following compounds from any one of the given organic starting materials and inorganic reagents. Specify reagents and the reaction conditions. Starting materials: propylene, isobutylene.
Describe the catalytic hydrogenation reaction of alkenes.
In the presence of a trace of peroxide or under the influence of ultraviolet light, 1-octene reacts: (a) with \(\mathrm{CHCI}_{3}\) to form \(1,1,1\) -trichlorononane; (b) with \(\mathrm{CHBr}_{3}\) to form \(1,1,3\) -tribromononane; (c) with \(\mathrm{CBrCl}_{3}\) to form \(1,1,1\) -trichloro-3-bromononane; (d) with \(\mathrm{H}-\mathrm{S}-\mathrm{CH}_{2} \mathrm{COOH}\) (thioglycolic acid) to yield \(\mathrm{n}-\mathrm{C}_{8} \mathrm{H}_{17}-\mathrm{S}-\mathrm{CH}_{2} \mathrm{COOH}\)
When isopropyl bromide is treated with sodium ethoxide in ethanol, propylene and ethyl isopropyl ether are formed in a \(3: 1\) ratio. If the hexadeuteroisopropy1 bromide, \(\mathrm{CD}_{3} \mathrm{CHBrCD}_{3}\) is used, \(\mathrm{CD}_{3} \mathrm{CH}=\mathrm{CD}_{2}\) and \(\left(\mathrm{CD}_{3}\right)_{2} \mathrm{CHOC}_{2} \mathrm{H}_{5}\) are formed in a ratio of \(1: 2\). Explain.
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