What is an alkene?

Short Answer

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An alkene is an unsaturated hydrocarbon containing a carbon-carbon double bond (C=C) in its structure. They have the general molecular formula CnH2n and are more reactive than alkanes due to the presence of the double bond. Examples of alkenes include ethene (\( CH_2=CH_2 \)), propene (\( CH_2=CH-CH_3 \)), and butene (\( CH_2=CH-CH_2-CH_3 \)).

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01

Definition of Alkene

An alkene is an unsaturated hydrocarbon, which means it contains a carbon-carbon double bond (C=C) in its structure. They are a family of organic compounds and have the general molecular formula CnH2n, where n represents the number of carbon atoms.
02

Characteristic of Alkenes

The presence of the carbon-carbon double bond in alkenes makes them more reactive compared to alkanes, which have only single bonds between carbon atoms. The double bond consists of one sigma bond and one pi bond. Apart from the double bond, the remaining carbon atoms are bonded to hydrogen atoms or other carbon atoms.
03

Nomenclature

The IUPAC nomenclature for alkenes consists of adding the suffix "-ene" to the base name of the corresponding alkane. The carbon atom count is used to determine the base name, and the position of the double bond is specified by a number. For example, in the case of CH2=CH2, it is called ethene, as it has two carbon atoms in the molecule.
04

Examples of Alkenes

Here are a few examples of alkenes: 1. Ethene: \( CH_2=CH_2 \). It has two carbon atoms and a double bond between them. 2. Propene: \( CH_2=CH-CH_3 \). It has three carbon atoms with a double bond between the first and second carbon atoms. 3. Butene: \( CH_2=CH-CH_2-CH_3 \). It has four carbon atoms with a double bond between the first and second carbon atoms. Remember that the position of the double bond may vary, so there can be isomers of alkenes with the same molecular formula but different structures, such as: 1. 1-Butene: \( CH_2=CH-CH_2-CH_3 \). The double bond is between the first and second carbon atoms. 2. 2-Butene: \( CH_3-CH=CH-CH_3 \). The double bond is between the second and third carbon atoms.

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Most popular questions from this chapter

(a) Indicate the direction of the net dipole moment for each of the dihaloethenes. (b) Would cis-2,3-dichloro-2-butane have a larger or smaller dipole moment than cis-1,2-dichloroethene? (c) Indicate the direction of the net dipolemoment of cis-1,2 dibromo-1,2-dichloroethene. Will it be larger or smaller than the dipole moment of cis-1,2-dichloroethene? Why?

Indicate how you would synthesize each of the following compounds from any one of the given organic starting materials and inorganic reagents. Specify reagents and the reaction conditions. Starting materials: propylene, isobutylene.

Describe the catalytic hydrogenation reaction of alkenes.

In the presence of a trace of peroxide or under the influence of ultraviolet light, 1-octene reacts: (a) with \(\mathrm{CHCI}_{3}\) to form \(1,1,1\) -trichlorononane; (b) with \(\mathrm{CHBr}_{3}\) to form \(1,1,3\) -tribromononane; (c) with \(\mathrm{CBrCl}_{3}\) to form \(1,1,1\) -trichloro-3-bromononane; (d) with \(\mathrm{H}-\mathrm{S}-\mathrm{CH}_{2} \mathrm{COOH}\) (thioglycolic acid) to yield \(\mathrm{n}-\mathrm{C}_{8} \mathrm{H}_{17}-\mathrm{S}-\mathrm{CH}_{2} \mathrm{COOH}\)

When isopropyl bromide is treated with sodium ethoxide in ethanol, propylene and ethyl isopropyl ether are formed in a \(3: 1\) ratio. If the hexadeuteroisopropy1 bromide, \(\mathrm{CD}_{3} \mathrm{CHBrCD}_{3}\) is used, \(\mathrm{CD}_{3} \mathrm{CH}=\mathrm{CD}_{2}\) and \(\left(\mathrm{CD}_{3}\right)_{2} \mathrm{CHOC}_{2} \mathrm{H}_{5}\) are formed in a ratio of \(1: 2\). Explain.

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